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The Sheahan Diamond Literature Reference Compilation - Technical Articles based on Major Region - Angola
The Sheahan Diamond Literature Reference Compilation is compiled by Patricia Sheahan who publishes on a monthly basis a list of new scientific articles related to diamonds as well as media coverage and corporate announcements called the Sheahan Diamond Literature Service that is distributed as a free pdf to a list of followers. Pat has kindly agreed to allow her work to be made available as an online digital resource at Kaiser Research Online so that a broader community interested in diamonds and related geology can benefit. The references are for personal use information purposes only; when available a link is provided to an online location where the full article can be accessed or purchased directly. Reproduction of this compilation in part or in whole without permission from the Sheahan Diamond Literature Service is strictly prohibited. Return to Diamond Region Index
Sheahan Diamond Literature Reference Compilation - Scientific Articles by Author for all years
Each article reference in the SDLRC is tagged with one or more key words assigned by Pat Sheahan to highlight the main topics of the article. In addition most references have been tagged with one or more region words. In an effort to make it easier for users to track down articles related to a specific region, KRO has extracted these region words and developed a list of major region words presented in the Major Region Index to which individual region words used in the article reference have been assigned. Each individual Region Report contains in chronological order all the references with a region word associated with the Major Region word. Depending on the total for each reference type - technical, media and corporate - the references will be either in their own technical, media or corporate Region Report, or combined in a single report. Where there is a significant number of technical references there will be a technical report dedicated to the technical articles while the media and corporate references are combined in a separate region report. References that were added in the most recent monthly update are highlighted in yellow within the Region Report. The Major Region words have been defined by a scale system of "general", "continent", "country", "state or province" and "regional". Major Region words at the smaller scales have been created only when there are enough references to make isolating them worthwhile. References not tagged with a Region are excluded, and articles with a region word not matched with a Major Region show up in the "Unknown" report.
Kimberlite - diamondiferous
Lamproite - diamondiferous
Lamprophyre - diamondiferous
Other - diamondiferous
Kimberlite - non diamondiferous
Lamproite - non diamondiferous
Lamprophyre - non diamondiferous
Other - non diamondiferous
Kimberlite - unknown
Lamproite - unknown
Lamprophyre - unknown
Other - unknown
Future Mine
Current Mine
Former Mine
Click on icon for details about each occurrence. Works best with Google Chrome.
CITATION: Faure, S, 2010, World Kimberlites CONSOREM Database (Version 3), Consortium de Recherche en Exploration Minérale CONSOREM, Université du Québec à Montréal, Numerical Database on consorem.ca. NOTE: This publicly available database results of a compilation of other public databases, scientific and governmental publications and maps, and various data from exploration companies reports or Web sites, If you notice errors, have additional kimberlite localizations that should be included in this database, or have any comments and suggestions, please contact the author specifying the ID of the kimberlite: [email protected]
Review of 1989 international mineral industry activities.Brief mention Of diamonds in several countries. ie. South Africa, Zaire, Namibia, Angola, Guinea
Mining Engineering, Vol. 42, No. 7, July, pp. 665-675
South Africa, Democratic Republic of Congo, Namibia, Angola, Guinea
The discreet tycoon. by R. Weldon. reviewed in Professional Jeweler, Vol. 5, 1, 2002, pp. 20,21, 22, 26. Lev Leviev's Angolan connection. 5, 2, pp.19-21.
Gems and Gemology, Vol. 38, Fall, p. 290 ( 1p. abstract)
28th. De Beers Alex du Toit memorial lecture, 2004. On cryogenian (Neoproterozoic) ice sheet dynamics and the limitations of the glacial sedimentary record.
South African Journal of Geology, Vol. 108, pp. 557-577.
Jelsma, H.,Krishnan, S.U., Perritt, S.,Kumar, M., Preston, R., Winter, F., Lemotlo, L., Costa, J., Van der Linde, G., Facatino, M., Posser, A., Wallace, C., Henning, A., Joy, S., Chinn, I., Armstrong, R., Phillips, D.
Kimberlites from central Angola: a case stidy of exploration findings.
10th. International Kimberlite Conference Feb. 6-11, Bangalore India, Abstract
Monie, P., Bosch, D., Bruguier, O., Vauchez, A., Rolland, Y., Nsungani, P., Buta Nto, A.
The Late Neoproterozoic/Early Palezoic evolution of the West Congo belt of NW Angola: geochronological (U-Pb and Ar-Ar) and petrostructural constraints.
Ernst, R.E., Pereira, E., Hamilton, M.A., Pisarevsky, S.A., Rodriques, J., Tasinari, C.C.G., Teixeira, W., Van-Dunem, V.
Mesoproterozoic intraplate magmatic 'barcode' record of the Angola portion of the Congo craton: newly dated magmatic events at 1505 and 1110 Ma and implications for Nuna ( Columbia) supercontinent reconstructions.
Kimberlites from central Angola: a case study of exploration findings.
Proceedings of the 10th. International Kimberlite Conference, Vol. 2, Special Issue of the Journal of the Geological Society of India,, Vol. 2, pp. 173-190.
New U-Pb SHRIMP ages from the Lubango region, sw Angola: insights into the Paleoproterozoic evolution of the Angolan shield, southern Congo craton, Africa.
Journal of the Geological Society, Vol. 170, pp. 353-363.
In situ trace element geochemistry and U-Pb dating on perovskite from kimberlites of the Lunda Norte province ( NE Angola): petrogenetic and tectonic implications.
Insights into the mantle structure beneath the Lunda Norte kimberlitic province (NE Angola): petrography and paleothermobarometry of fresh mantle xenoliths.
Garzanti, E., Resentini, A., Ando, S., Vezzoli, G., Pereira, A., Vermeesch, P.
Physical controls on sand and composition and relative durability of detrital minerals during ultra-long distance littoral and aeolian transport ( Namibia and southern Angola).
Jelsma, H., Krishnan, U., Perritt, S., Preston, R., Winter, F., Lemotlo, L., van der Linde, G., Armstrong, R., Phillips, D., Joy, S., Costa, J., Facatino, M., Posser, A., Kumar, M., Wallace, C., Chinn, I., Henning, A.
Kimberlites from central Angola: a case study of exploration findings.
Proceedings of the 10th. International Kimberlite Conference, Vol. 2, pp. 173-190.
Mantle conditions and geochemical environment as controls of diamond survival and grade variation in kimberlitic diamond deposits: Lunda Province NE Angola.
30th. International Conference on Ore Potential of alkaline, kimberlite and carbonatite magmatism. Sept. 29-, http://alkaline2014.com
Abstract: A set of small volcanic edifices with tuff ring and maar morphologies occur in the Catanda area, which is the only locality with extrusive carbonatites reported in Angola. Four outcrops of carbonatite lavas have been identified in this region and considering the mineralogical, textural and compositional features, we classify them as: silicocarbonatites (1), calciocarbonatites (2) and secondary calciocarbonatites produced by the alteration of primary natrocarbonatites (3). Even with their differences, we interpret these lava types as having been a single carbonatite suite related to the same parental magma. We have also estimated the composition of the parental magma from a study of melt inclusions hosted in magnetite microphenocrysts from all of these lavas. Melt inclusions revealed the presence of 13 different alkali-rich phases (e.g., nyerereite, shortite, halite and sylvite) that argues for an alkaline composition of the Catanda parental melts. Mineralogical, textural, compositional and isotopic features of some Catanda lavas are also similar to those described in altered natrocarbonatite localities worldwide such as Tinderet or Kerimasi, leading to our conclusion that the formation of some Catanda calciocarbonatite lavas was related to the occurrence of natrocarbonatite volcanism in this area. On the other hand, silicocarbonatite lavas, which are enriched in periclase, present very different mineralogical, compositional and isotopic features in comparison to the rest of Catanda lavas. We conclude that its formation was probably related to the decarbonation of primary dolomite bearing carbonatites.
Abstract: This paper provides a review of the Geological exploration of the Angola Coast (from Sumbe to Namibe) from pioneer's first geological descriptions and mining inventory to the most recent publications supported by the oil industry. We focus our attention on the following periods: 1875-1890 (Paul Choffat's work, mainly), 1910-1949 (first maps at country scale), 1949-1974 (detailed mapping of the Kwanza-Namibe coastal series), 1975-2000, with the editing of the last version of the Angola geological map at 1:1 million scale and the progressive completion of previous works. Since 2000, there is a renewal in geological fieldwork publications on the area mainly due to the work of university teams. This review paper thus stands at the frontier between geology, natural resources and the history of geology. It shows how geological knowledge has progressed in time, fueled by economic and scientific reasons.
Abstract: Perovskite (CaTiO3) has become a very useful mineral for dating kimberlite eruptions, as well as for constraining the compositional evolution of a kimberlitic magma and its source. Despite the undeniable potential of such an approach, no similar study had been done in Angola, the fourth largest diamond producer in Africa. Here we present the first work of in situ U-Pb geochronology and Sr-Nd isotope analyses of perovskite in six Angolan kimberlites, supported by a detailed petrographic and geochemical study of their perovskite populations. Four types of perovskite were identified, differing in texture, major- and trace-element composition, zoning patterns, type of alteration and the presence or absence of inclusions. Primary groundmass perovskite is classified either as anhedral, Na-, Nb- and LREE-poor perovskite (Ia); or euhedral, strongly zoned, Na-, Nb- and LREE-rich perovskite (Ib). Secondary perovskite occurs as reaction rims on ilmenite (IIa) or as high Nb (up to 10.6 wt% Nb2O5) perovskite rims on primary perovskite (IIb). The occurrence of these four types within the Mulepe kimberlites is interpreted as an evidence of a complex, multi-stage process that involved mingling of compositionally different melts. U-Pb dating of these perovskites yielded Lower Cretaceous ages for four of the studied kimberlites: Mulepe 1 (116.2 ± 6.5 Ma), Mulepe 2 (123.0 ± 3.6 Ma), Calonda (119.5 ± 4.3 Ma) and Cat115 (133 ± 10 Ma). Kimberlite magmatism occurred in NE Angola likely due to reactivation of deep-seated translithospheric faults (> 300 km) during the break-up of Gondwana. Sr-Nd isotope analyses of four of these kimberlites indicate that they are Group I kimberlites, which is consistent with the petrological observations.
Abstract: Perovskite (CaTiO3) has become a very usefulmineral for dating kimberlite eruptions, aswell as for constraining the compositional evolution of a kimberlitic magma and its source. Despite the undeniable potential of such an approach, no similar study had been done in Angola, the fourth largest diamond producer in Africa. Here we present the firstwork of in situ U-Pb geochronology and Sr-Ndisotope analyses of perovskite in six Angolan kimberlites, supported by a detailed petrographic and geochemical study of their perovskite populations. Four types of perovskitewere identified, differing in texture,major- and trace-element composition, zoning patterns, type of alteration and the presence or absence of inclusions. Primary groundmass perovskite is classified either as anhedral, Na-, Nb- and LREE-poor perovskite (Ia); or euhedral, strongly zoned, Na-, Nb- and LREE-rich perovskite (Ib). Secondary perovskite occurs as reaction rims on ilmenite (IIa) or as high Nb (up to 10.6 wt% Nb2O5) perovskite rims on primary perovskite (IIb). The occurrence of these four types within the Mulepe kimberlites is interpreted as an evidence of a complex, multi-stage process that involved mingling of compositionally different melts. U-Pb dating of these perovskites yielded Lower Cretaceous ages for four of the studied kimberlites: Mulepe 1 (116.2±6.5Ma),Mulepe 2 (123.0±3.6Ma), Calonda (119.5±4.3 Ma) and Cat115 (133±10Ma). Kimberlite magmatism occurred in NE Angola likely due to reactivation of deep-seated translithospheric faults (N300 km) during the break-up of Gondwana. Sr-Nd isotope analyses of four of these kimberlites indicate that they are Group I kimberlites, which is consistent with the petrological observations.
Thesis, University of Pretoria, Ms Metallurgical Engineering 279p. Pdf
Africa, Angola, South Africa
Deposit - AC 56-5-1, Venetia Red
Abstract: Kimberlite is the host rock from which diamonds are mined. The mineralogical features for kimberlites vary greatly with country, origin, depth and type of kimberlite. Kimberlites can contain various clay species with some kimberlites containing predominantly clay minerals. The presence of these clay minerals in the ore can cause difficulty in dewatering due to high flocculant demand, poor supernatant clarity and low settling rates. Identifying critical parameters that can predict the settling behaviour of African kimberlite slurries will assist the process engineer to predict the settling behaviour of different kimberlite slurries. Especially identifying the kimberlites that will most likely not settle with normal flocculant dosage rates is useful. From first principles the settling of a particle is described by Stoke’s law which incorporates the density of the particle and size of the particle as the inherent particle variables. In this case density is assumed constant and therefore the size of particles influence the settling rate of particles to a great extent. This study therefore investigated the influence of particle size on settling rate and whether the particle size distribution showed correlation with settling rate when regression modelling was fitted on the data. Other variables that were tested for correlation with settling were pH when the kimberlite is mixed in water as well as various mineralogical features of the ore. Fitting a simple model to any of these properties or combinations of these properties was attempted which would allow for prediction of settling behaviour. The mineralogical features were classified by evaluating the mineral composition, fractional elemental analysis, cation exchange capacity and the exchangeable sodium percentage of the different kimberlites. These variables were tested as well as their settling behaviour with 18 different African kimberlite samples. The settling rate and slurry bed compaction during natural settling as well coagulant and flocculant assisted settling were measured for the kimberlite slurries. The best performing coagulant and flocculant for each kimberlite were combined to evaluate potential improvements in the settling rates and slurry bed compaction compared to current settling practices that only utilise flocculant additions. Especially the use of coagulant for kimberlites that did not show settling with only flocculants was evaluated. For these 18 kimberlites only 2 kimberlites did not settle with the use of flocculants with settling rates varying between 10.7m/h and 25m/h. Both these kimberlites also did not settle with the combination of coagulant and flocculant, but could only settle with only coagulant additions at settling rates of 1.9 m/h and 2.2 m/h. Regression analysis fitted to the settling rate investigated the influence of particle size, pH and mineralogical features on settling. For representation of the particle size two data points from the Particle Size Distribution (PSD) was utilised which represented the fine material and the coarser material. These two data points were taken at percentage passing 7.5 ?m and 75 ?m. Regression data for kimberlite with flocculant additions showed that particle size and the pH of the slurry were identified as significant parameters in predicting settling. The regression data showed a R2 of 0.78 for the settling rate and an adjusted R2 of 0.79 for the slurry bed depth.
Geochimica et Cosmochimica Acta, Vol. 196, pp. 36-57.
Africa, Namibia, Angola
Paran-Etendeka, Karoo
Abstract: We present major and trace element compositions of 154 re-homogenised olivine-hosted melt inclusions found in primitive rocks (picrites and ferropicrites) from the Mesozoic Parana ´-Etendeka and Karoo Continental Flood Basalt (CFB) provinces. The major element compositions of the melt inclusions, especially their Fe/Mg ratios, are variable and erratic, and attributed to the re-homogenisation process during sample preparation. In contrast, the trace element compositions of both the picrite and ferropicrite olivine-hosted melt inclusions are remarkably uniform and closely re?ect those of the host whole-rocks, except in a small subset a?ected by hydrothermal alteration. The Parana ´-Etendeka picrites and ferropicrites are petrogenet- ically related to the more evolved and voluminous ?ood basalts, and so we propose that compositional homogeneity at the melt inclusion scale implies that the CFB parental mantle melts were well mixed prior to extensive crystallisation. The incompatible trace element homogeneity of olivine-hosted melt inclusions in Parana ´-Etendeka and Karoo primitive magmatic rocks has also been identi?ed in other CFB provinces and contrasts with ?ndings from studies of basalts from mid- ocean ridges (e.g. Iceland and FAMOUS on the Mid Atlantic Ridge), where heterogeneity of incompatible trace elements in olivine-hosted melt inclusions is more pronounced. We suggest that the low variability in incompatible trace element contents of olivine-hosted melt inclusions in near-primitive CFB rocks, and also ocean island basalts associated with moderately thick lithosphere (e.g. Hawaii, Gala ´pagos, Samoa), may re?ect mixing along their longer transport pathways during ascent and/or a temperature contrast between the liquidus and the liquid when it arrives in the crust. These thermal paths promote mixing of mantle melts prior to their entrapment by growing olivine crystals in crustal magma chambers. Olivine-hosted melt inclusions of ferropicrites from the Parana ´-Etendeka and Karoo CFB have the least variable compositions of all global melt inclusion suites, which may be a function of their unusually deep origin and low viscosity.
Abstract: Mantle flow can cause the Earth’s surface to uplift and subside, but the rates and durations of these motions are, in general, poorly resolved due to the difficulties in making measurements of relatively small vertical movements (hundreds of metres) over sufficiently large distances (about 1,000?km). Here we examine the effect of mantle upwelling through a study of Quaternary uplift along the coast of Angola. Using both optically stimulated luminescence on sediment grains, and radiocarbon dating of fossil shells, we date a 25?m coastal terrace at about 45 thousand years old, when sea level was about 75?m lower than today, indicating a rapid uplift rate of 1.8-2.6?mm?yr?1 that is an order of magnitude higher than previously obtained rates averaged over longer time periods. Automated extraction and correlation of coastal terrace remnants from digital topography uncovers a symmetrical uplift with diameter of more than 1,000?km. The wavelength and relatively short timescale of the uplift suggest that it is associated with a mantle process, possibly convective upwelling, and that the topography may be modulated by rapid short-lived pulses of mantle-derived uplift. Our study shows that stable continental regions far from the effects of glacial rebound may experience rapid vertical displacements of several millimetres per year.
Abstract: Tectonic plate interiors are often regarded as relatively inactive. Yet, reconstructions of marine terrace uplift in Angola suggest that underlying mantle flow can rapidly warp Earth's surface far from obviously active plate boundaries.
Abstract: The origin of intraplate carbonatitic to alkaline volcanism in Africa is controversial. A tectonic control, i.e., decompression melting associated with far-field stress, is suggested by correlation with lithospheric sutures, repeated magmatic cycles in the same areas over several million years, synchronicity across the plate, and lack of clear age progression patterns. Conversely, a dominant role for mantle convection is supported by the coincidence of Cenozoic volcanism with regions of lithospheric uplift, positive free-air gravity anomalies, and slow seismic velocities. To improve constraints on the genesis of African volcanism, here we report the first radiometric and isotopic results for the Catanda complex, which hosts the only extrusive carbonatites in Angola. Apatite (U-Th-Sm)/He and phlogopite 40Ar/39Ar ages of Catanda aillikite lavas indicate eruption at ca. 500–800 ka, more than 100 m.y. after emplacement of abundant kimberlites and carbonatites in this region. The lavas share similar high-? (HIMU)–like Sr-Nd-Pb-Hf isotope compositions with other young mantle-derived volcanics from Africa (e.g., Northern Kenya Rift; Cameroon Line). The position of the Catanda complex in the Lucapa corridor, a long-lived extensional structure, suggests a possible tectonic control for the volcanism. The complex is also located on the Bié Dome, a broad region of fast Pleistocene uplift attributed to mantle upwelling. Seismic tomography models indicate convection of deep hot material beneath regions of active volcanism in Africa, including a large area encompassing Angola and northern Namibia. This is strong evidence that intraplate late Cenozoic volcanism, including the Catanda complex, resulted from the interplay between mantle convection and preexisting lithospheric heterogeneities.
deposits - Tchiuzo, Anomaly 116, Catoca, Alt Cuilo-4, Cuilo-63, Cucumbi-79.
Abstract: In this study, we compare the major- and trace-element compositions of olivine, garnet, and clinopyroxene that occur as single crystals (142 grains), with those derived from xenoliths (51 samples) from six kimberlites in the Lucapa area, northeastern Angola: Tchiuzo, Anomaly 116, Catoca, Alto Cuilo-4, Alto Cuilo-63 and Cucumbi-79. The samples were analyzed using electron probe microanalysis (EPMA) and laser-ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS). The results suggest different paragenetic associations for these kimberlites in the Lucapa area. Compositional overlap in some of the macrocryst and mantle xenolith samples indicates a xenocrystic origin for some of those macrocrysts. The presence of mantle xenocrysts suggests the possibility of finding diamond. Geothermobarometric calculations were carried out using EPMA data from xenoliths by applying the program PTEXL.XLT. Additional well calibrated single-clinopyroxene thermobarometric calculations were also applied. Results indicate the underlying mantle experienced different equilibration conditions. Subsequent metasomatic enrichment events also support a hypothesis of different sources for the kimberlites. These findings contribute to a better understanding of the petrogenetic evolution of the kimberlites in northeastern Angola and have important implications for diamond exploration.
Abstract: Magnesian ilmenite is a common kimberlite indicator mineral, although its use in diamond exploration is still controversial. Complex crystallisation and replacement processes have been invoked to explain the wide compositional and textural ranges of ilmenite found in kimberlites. This work aims to shed light on these processes, as well as their implications for diamond exploration. Petrographic studies were combined for the first time with both major- and trace-element analyses to characterise the ilmenite populations found in xenoliths and xenocrysts in two Angolan kimberlites (Congo-Kasai craton). A multi-stage model describes the evolution of ilmenite in these pipes involving: i) crystallisation of ferric and Mg-rich ilmenite either as metasomatic phases or as megacrysts, both in crustal and in metasomatised mantle domains; ii) kimberlite entrainment and xenolith disaggregation producing at least two populations of ilmenite nodules differing in composition; iii) interaction of both types with the kimberlitic magma during eruption, leading to widespread replacement by Mg-rich ilmenite along grain boundaries and fractures. This process produced similar major-element compositions in ilmenites regardless of their primary (i.e., pre-kimberlitic) origin, although the original enrichment in HFSE (Zr, Hf, Ta, Nb) observed in Fe3 +-rich xenocrysts is preserved. Finally (iv) formation of secondary Mn-ilmenite by interaction with a fluid of carbonatitic affinity or by infiltration of a late hydrothermal fluid, followed in some cases by subsolidus alteration in an oxidising environment. The complexities of ilmenite genesis may lead to misinterpretation of the diamond potential of a kimberlite during the exploration stage if textural and trace-element information is disregarded. Secondary Mg-enrichment of ilmenite xenocrysts is common and is unrelated to reducing conditions that could favour diamond formation/preservation in the mantle. Similarly, Mn-rich ilmenite should be disregarded as a diamond indicator mineral, unless textural studies can prove its primary origin.
Journal of Volcanology and Geothermal Research, in press available, 19p.
Africa, Angola, Democratic Republic of Congo
carbonatites
Abstract: The South Atlantic Igneous Province comprises the Paraná Basalts, Rio Grande Rise, Tristan archipelago and surrounding guyot province,Walvis Ridge, Etendeka basalts and, in somemodels, the alkaline igneous lineament in the Lucapa corridor, Angola. Although these volcanics are often considered to have a single generic origin, complexities that suggest otherwise are observed. The Paraná Basalts erupted ~5 Ma before sea-floor spreading started in the neighborhood, and far more voluminous volcanic margins were emplaced later. A continental microcontinent likely forms much of the Rio Grande Rise, and variable styles of volcanism built the Walvis Ridge and the Tristan da Cunha archipelago and guyot province. Such complexities, coupled with the northward-propagating mid-ocean ridge crossing amajor transverse transtensional intracontinental structure, suggest that fragmentation of Pangaea was complex at this latitude and that the volcanism may have occurred in response to distributed extension. The alternative model, a deep mantle plume, is less able to account for many observations and no model variant can account for all the primary features that include eruption of the Paraná Basalts in a subsiding basin, continental breakup by rift propagation that originated far to the south, the absence of a time-progressive volcanic chain between the Paraná Basalts and the Rio Grande Rise, derivation of the lavas from different sources, and the lack of evidence for a plume conduit in seismic-tomography- and magnetotelluric images. The region shares many common features with the North Atlantic Igneous Province which also features persistent, widespread volcanismwhere a propagating mid-ocean ridge crossed a transverse structural discontinuity in the disintegrating supercontinent.
Abstract: The origin of intraplate carbonatitic to alkaline volcanism in Africa is controversial. A tectonic control, i.e., decompression melting associated with far-field stress, is suggested by correlation with lithospheric sutures, repeated magmatic cycles in the same areas over several million years, synchronicity across the plate, and lack of clear age progression patterns. Conversely, a dominant role for mantle convection is supported by the coincidence of Cenozoic volcanism with regions of lithospheric uplift, positive free-air gravity anomalies, and slow seismic velocities. To improve constraints on the genesis of African volcanism, here we report the first radiometric and isotopic results for the Catanda complex, which hosts the only extrusive carbonatites in Angola. Apatite (U-Th-Sm)/He and phlogopite 40Ar/39Ar ages of Catanda aillikite lavas indicate eruption at ca. 500-800 ka, more than 100 m.y. after emplacement of abundant kimberlites and carbonatites in this region. The lavas share similar high-? (HIMU)-like Sr-Nd-Pb-Hf isotope compositions with other young mantle-derived volcanics from Africa (e.g., Northern Kenya Rift; Cameroon Line). The position of the Catanda complex in the Lucapa corridor, a long-lived extensional structure, suggests a possible tectonic control for the volcanism. The complex is also located on the Bié Dome, a broad region of fast Pleistocene uplift attributed to mantle upwelling. Seismic tomography models indicate convection of deep hot material beneath regions of active volcanism in Africa, including a large area encompassing Angola and northern Namibia. This is strong evidence that intraplate late Cenozoic volcanism, including the Catanda complex, resulted from the interplay between mantle convection and preexisting lithospheric heterogeneities.
Abstract: This study focuses on the causes, modalities and obstacles of sediment transfer in the longest cell of littoral sand drift documented on Earth so far. Sand derived from the Orange River is dragged by swell waves and persistent southerly winds to accumulate in four successive dunefields in coastal Namibia to Angola. All four dunefields are terminated by river valleys, where aeolian sand is flushed back to the ocean; and yet sediment transport continues at sea, tracing an 1800 km long submarine sand highway. Sand drift would extend northward to beyond the Congo if the shelf did not become progressively narrower in southern Angola, where drifting sand is funnelled towards oceanic depths via canyon heads connected to river mouths. Garnet-magnetite placers are widespread along this coastal stretch, indicating systematic loss of the low-density feldspatho-quartzose fraction to the deep ocean. More than half of Moçamedes Desert sand is derived from the Orange River, and the rest in similar proportions from the Cunene River and from the Swakop and other rivers draining the Damara Orogen in Namibia. The Orange fingerprint, characterized by basaltic rock fragments, clinopyroxene grains and bimodal zircon-age spectra with peaks at ca 0•5 Ga and ca 1•0 Ga, is lost abruptly at Namibe, and beach sands further north have abundant feldspar, amphibole-epidote suites and unimodal zircon-age spectra with a peak at ca 2•0 Ga, documenting local provenance from Palaeoproterozoic basement. Along with this oblique-rifted continental margin, beach placers are dominated by Fe-Ti-Cr oxides with more monazite than garnet and thus have a geochemical signature sharply different from beach placers found all the way along the Orange littoral cell. High-resolution mineralogical studies allow us to trace sediment dispersal over distances of thousands of kilometres, providing essential information for the correct reconstruction of ‘source to sink’ relationships in hydrocarbon exploration and to predict the long-term impact of man-made infrastructures on coastal sediment budgets.
Russian Geology and Geophysics, Vol. 58, pp. 1305-1316.
Africa, Angola
eclogites
Abstract: We studied the Sm-Nd, Rb-Sr, and Re-Os isotope compositions of mantle xenoliths (eclogites and peridotites) from diamondiferous kimberlites of the Catoca cluster of the Kasai Craton. In the eclogites, the primary strontium isotope composition 87Sr/86Sr varies from 0.7056 to 0.7071, and the neodymium isotope composition eNd, from 1.8 to 2.6. The 187Re/188Os and 187Os/188Os ratios range from 135 to 80 and from 1.3110 to 1.9709, respectively, which indicates a significant portion of radiogenic Os: yOs = 129-147. These isotope values exceed the values assumed for model reservoirs (primitive upper mantle (PUM) and bulk silicate Earth (BSE)) and those of chondrites. The isotope composition of the studied systems indicates the formation of eclogites from a rhenium-enriched source, namely, the subducted oceanic crust transformed as a result of metasomatism and/or melting under upper-mantle conditions.
Anais da Academia Brasileira de Ciencas, Vol. 78, 2, pp. 309-315.
Africa, Angola
deposit - Camafuca
Abstract: This work presents a geochemical study of a set of garnets, selected by their colors, from the Camafuca-Camazambo kimberlite, located on northeast Angola. Mantle-derived garnets were classified according to the scheme proposed by Grütter et al. (2004) and belong to the G1, G4, G9 and G10 groups. Both sub-calcic (G10) and Ca-saturated (G9) garnets, typical, respectively, of harzburgites and lherzolites, were identified. The solubility limit of knorringite molecule in G10D garnets suggests they have crystallized at a minimum pressure of about 40 to 45 kbar (4-4.5 GPa). The occurrence of diamond stability field garnets (G10D) is a clear indicator of the potential of this kimberlite for diamond. The chemistry of the garnets suggests that the source for the kimberlite was a lherzolite that has suffered a partial melting that formed basaltic magma, leaving a harzburgite as a residue.
Abstract: In this study, we compare the major- and trace-element compositions of olivine, garnet, and clinopyroxene that occur as single crystals (142 grains), with those derived from xenoliths (51 samples) from six kimberlites in the Lucapa area, northeastern Angola: Tchiuzo, Anomaly 116, Catoca, Alto Cuilo-4, Alto Cuilo-63 and Cucumbi-79. The samples were analyzed using electron probe microanalysis (EPMA) and laser-ablation inductively coupled plasma-mass spectrometry (LA-ICP-MS). The results suggest different paragenetic associations for these kimberlites in the Lucapa area. Compositional overlap in some of the macrocryst and mantle xenolith samples indicates a xenocrystic origin for some of those macrocrysts. The presence of mantle xenocrysts suggests the possibility of finding diamond. Geothermobarometric calculations were carried out using EPMA data from xenoliths by applying the program PTEXL.XLT. Additional well calibrated single-clinopyroxene thermobarometric calculations were also applied. Results indicate the underlying mantle experienced different equilibration conditions. Subsequent metasomatic enrichment events also support a hypothesis of different sources for the kimberlites. These findings contribute to a better understanding of the petrogenetic evolution of the kimberlites in northeastern Angola and have important implications for diamond exploration.
Mineral Processing and Extractive Metallurgy Review, Vol. 39, pp. 136-144.
Africa, Angola
mineral processing
Abstract: Kimberlite is the host rock of diamonds and varies widely in geological and mineralogical features as well as color, processing capability, and dewatering characteristics. This study investigated the dewatering behavior of problematic Angolan kimberlites. The presence of clay minerals in kimberlite causes difficulties in dewatering due to high flocculant demand, poor supernatant clarity, and low settling rates. Identifying critical parameters governing the settling behavior will assist in managing the settling behavior of different kimberlite slurries. The influence of particle size, pH of the kimberlite slurry, cation exchange capacity, exchangeable sodium percentage, and smectite content of the kimberlite on the settling rate were investigated for 18 different African kimberlite samples. The settling rate and slurry bed compaction during natural settling were also measured for the kimberlite slurries. Seventeen different Angolan clay-rich kimberlites and one South African clay-rich kimberlite were tested, and, except for two kimberlites, colloidal stability was experienced during natural settling. The pH values of the kimberlite slurries ranged between 9 and 11, which is similar to the pH band where colloidal stability was found during earlier research. The results indicate that colloidal stable slurries were experienced with kimberlites that had exchangeable sodium percentages as low as 0.7%. The cation exchange capacity of the various kimberlites differentiated more distinctly between colloidal stability and instability. A new model is proposed whereby clay-rich kimberlites with a cation exchange capacity of more than 10cmol/kg will experience colloidal stability if the pH of the solvent solution is within the prescribed pH range of 9-11.
The Southern African Institute of Mining and Metallurgy Diamonds - from source to use 2013, 9p. Pdf researchgate
Africa, Angola, South Africa
deposit - Mulepe, Voorspoed
Abstract: Construction of geological models for kimberlites has historically largely been based on visual volcanic textures and features, with chemical data only produced on an ad-hoc basis depending on the level of perceived complexity observed in the geological data. The focus of this manuscript is a high-level mineral resource management view of the impact which the initial absence of proper chemical data had on two kimberlite resource models as well as the increasing magnitude of the problem caused by the lack of chemical data once the resource estimation process commenced. The impact of the absence of chemical data on projects where micro-diamond estimation techniques are employed is also discussed. Metallurgical parameters have historically not been incorporated into kimberlite resource models, but recent work at De Beers Group Services has shown that geostatistical quantification of the DMS (Dense Media Separator) yield is useful for mine planning purposes, and will add value in the understanding of the kimberlite emplacement process. A case study is presented where a geostatistical analysis and conditional simulation was performed on the DMS yield in a kimberlite at a local block scale. These data were used to identify mining blocks where the DMS yield would exceed the capability of the treatment plant.
Mineralogy and Petrology, doi.org/10.1007/ s00710-018-0628-1 14p.
Africa, Angola
kimberlites
Abstract: Based on a comprehensive analysis of kimberlite pipes of Angola, including the near surface structural setting, deep lithospheric structure, pipe morphology and emplacement, mineralogical and petrographic features, diamond characteristics and locations of secondary deposits four geographical regions have been outlined within Angola representing four types of diamond bearing potential. These areas include high diamond bearing potential pipes, possible potential, no potential, and unclear potential areas. It was found that the depth of magmatism and diamond potential of kimberlites increases from the Atlantic coast in southwestern Angola into the continent in the north-easterly direction. Areas prospective for the discovery of new primary diamond deposits have been identified.
Abstract: The breakup of Africa from South America is associated with the emplacement of the Paraná-Etendeka flood basalt province from around 134 Ma and the Tristan da Cunha plume. Yet many additional volcanic events occur that are younger than the main pulse of the Paraná-Etendeka and straddle the rift to drift phases of the main breakup. This contribution reports on new geochronological constraints from the Angolan part of the African Margin. Three coastal and one inland section have been sampled stretching across some 400 Km, with 39Ar/40Ar, U-Pb and Palaeontology used to provide age constraints. Ages from the new data range from ~100 to 81 Ma, with three main events (cr. 100, 91 and 82-81 Ma). Volcanic events are occurring within the Early to Late Cretaceous, along this part of the margin with a general younging towards Namibia. With the constraints of additional age information both onshore and offshore Angola, a clear younging trend at the early stages of rift to drift is recorded in the volcanic events that unzip from North to South. Similar age volcanic events are reported from the Brazilian side of the conjugate margin, and highlight the need to fully incorporate these relatively low volume volcanic pulses into the plate tectonic breakup models of the South Atlantic Margin.
Geodynamics and Tectonphysics in RUS, Vol. 9, 3, pp. 827-854. only 1 p. english abstract
Africa, Angola
deposit - Catoca
Abstract: This paper presents the first results of the geostructural and tectonophysical studies of the crustal stress state in the Catoca kimberlite pipe area at the southwestern flank of the Kasai Shield in the northeasternAngola. In the evolution of the crustal stress state, six main stages are distinguished by analyzing the displacements of markers, fold hinges, long axes of boudins, granite dikes of various intrusion phases and kimberlites, as well as fractures with striations. For each of these stages, a dominating horizontal tectonic stress and its orientation is identified. During stage 1 (NW extension and shearing) and at the beginning of stage 2 (NW compression), structures formed in the host rocks in brittle-plastic conditions. The replacement of plastic deformation by faulting could occur about 530-510 Ma ago, when the continental crust ofAfricahad completely formed. Stage 3 (radial, mainly NW extension) and stage 4 (shearing, NW extension, and NE compression) were the most important for kimberlite occurrence: in the Early Cretaceous, radial extension was replaced by shearing. Both stages are related to opening of the central segment of theSouth Atlantic. The main kimberlite magmas occurred during the break-up of the Angola-Brazilian segment of Gondwana. In the course of all the four stages, stress was mainly released by the NE- and E-NE-striking faults and, to a lesser extent, by the NW-striking and latitudinal faults. The initial stage of kimberlite magmatism is associated with the NE- and E-NE-striking faults due to the presence of the Precambrian zones of flow and schistosity, which facilitated the NW-trending subhorizontal extension. Stage 5 (NE compression) began in the second half of the Cretaceous and possibly lasted until the end of the Paleogene, and compression occurred mainly along the NW-striking faults. Regionally, it corresponds to two stages of inversion movements in the southern regions of Africa, during which theAngoladome-shaped uplift emerged and the shoulders of the East African rifts began to take shape. Stage 6 (horizontal extension, mainly in the N-NE direction) is related to the processes that took place in the southern segment of theTanganyikarift and the eastern coast of theAtlantic. Based on the results of our studies, it became for the first time possible to get an idea of the main stages in the evolution of the studied region. Further geostructural measurements and dating of the host rocks will provide for a more precise definition of the proposed stages.
Gems & Gemology, Sixth International Gemological Symposium Vol. 54, 3, 1p. Abstract p. 274.
Africa, South Africa, Angola
deposit - Cullinan, Lulo
Abstract: Many of the world’s largest and most valuable gem diamonds exhibit an unusual set of physical characteristics. For example, in addition to their conspicuously low nitrogen concentrations, diamonds such as the 3,106 ct Cullinan (type IIa) and the Hope (type IIb, boron bearing) tend to have very few or no inclusions, and in their rough state they are found as irregular shapes rather than as sharp octahedral crystals. It has long been suspected that type IIa and IIb diamonds form in a different way than most other diamonds. Over the past two years, systematic investigation of both type IIa and IIb diamonds at GIA has revealed that they sometimes contain rare inclusions from unique geological origins. Examination of more than 130 inclusion-bearing samples has established recurring sets of inclusions that clearly show many of these diamonds originate in the sublithospheric mantle, much deeper in the earth than more common diamonds from the cratonic lithosphere. We now recognize that type IIa diamonds, or more specifically, diamonds with characteristics akin to the historic Cullinan diamond (dubbed CLIPPIR diamonds), are distinguished by the occurrence of ironrich metallic inclusions. Less frequently, CLIPPIR diamonds also contain inclusions of majoritic garnet and former CaSiO3perovskite that constrain the depth of formation to within 360–750 km. The inclusions suggest that CLIPPIR diamonds belong to a unique paragenesis with an intimate link to metallic iron in the deep mantle (Smith et al., 2016, 2017). Similarly, findings from type IIb diamonds also place them in a “superdeep” sublithospheric mantle setting, with inclusions of former CaSiO3 perovskite and other high-pressure minerals, although the iron-rich metallic inclusions are generally absent (Smith et al., 2018). Altogether, these findings show that high-quality type II gem diamonds are predominantly sourced from the sublithospheric mantle, a surprising result that has refuted the notion that all superdeep diamonds are small and nongem quality. Valuable information about the composition and behavior of the deep mantle is cryptically recorded in these diamonds. CLIPPIR diamonds (figure 1) confirm that the deep mantle contains metallic iron, while type IIb diamonds suggest that boron and perhaps water can be carried from the earth’s surface down into the lower mantle by plate tectonic processes. In addition to being gemstones of great beauty, diamonds carry tremendous scientific value in their unique ability to convey information about the interior of our planet.
Abstract: Mobilistic plate-tectonic interpretation of Precambrian orogens requires that two conjoined crustal blocks may derive from distant portions of the globe. Nonetheless, many proposed Precambrian cratonic juxtapositions are broadly similar to those of younger times (so-called “strange attractors”), raising the specter of bias in their construction. We evaluated the possibility that the Congo and Kalahari cratons (Africa) were joined together prior to their amalgamation along the Damara-Lufilian-Zambezi orogen in Cambrian time by studying diabase dikes of the Huila-Epembe swarm and sills in the southern part of the Congo craton in Angola and in Namibia. We present geologic, U-Pb geochronologic, and paleomagnetic evidence showing that these two cratons were directly juxtaposed at ca. 1.1 Ga, but in a slightly modified relative orientation compared to today. Recurring persistence in cratonic connections, with slight variations from one supercontinent to the next, may signify a style of supercontinental transition similar to the northward motion of Gondwana fragments across the Tethys-Indian oceanic tract, reuniting in Eurasia.
International Journal of Earth Sciences, Vol. 108, pp. 89-113.
Africa, Angola
thermochronology
Abstract: There are two main points of view regarding how continental margins evolve. The first one argues that the present-day margins have been developed by long-term denudation since a major exhumation episode, probably driven by rifting or another relevant tectonic event. The second one argues that continental margins underwent alternating burial and exhumation episodes related to crustal tectonic and surface uplift and subsidence. To demonstrate that the proximal domain of the southwestern Angolan margin has evolved in a polycyclic pattern, we present a review of geological and thermochronological information and integrate it with new combined apatite fission-track and (U-Th)/He data from Early Cretaceous volcanic and Precambrian basement samples. We also provide hypotheses on the possible mechanisms able to support the vertical crustal movements of this margin segment, which are also discussed based on some modern rifting models proposed for Central South Atlantic. The central apatite fission-track ages range from 120.6?±?8.9 to 272.9?±?21.6 Ma, with the mean track lengths of approximately 12 µm. The single-grain apatite (U-Th)/He ages vary between 52.2?±?1 and 177.2?±?2.6 Ma. The integration of the thermochronological data set with published geological constraints supports the following time-temperature evolution: (1) heating since the Carboniferous-Permian, (2) cooling onset in the Early Jurassic, (3) heating onset in the Early Cretaceous, (4) cooling onset in the Mid- to Late Cretaceous, (5) heating onset in the Late Cretaceous, and (6) cooling onset in the Oligocene-Miocene. The thermochronological data and the geological constraints, support that the proximal domain of the southwestern Angolan margin was covered in the past by pre-, syn-, and post-rift sediments, which were eroded during succeeding exhumation events. For this margin segment, we show that a development based on long-term denudation is less realistic than one based on burial and exhumation episodes during the last 130 Myr.
Abstract: The breakup of Africa from South America is associated with the emplacement of the Paraná-Etendeka flood basalt province from around 134?Ma and the Tristan da Cunha plume. Yet many additional volcanic events occur that are younger than the main pulse of the Paraná-Etendeka and straddle the rift to drift phases of the main breakup. This contribution reports on new geochronological constraints from the Angolan part of the African Margin. Three coastal and one inland section have been sampled stretching across some 400?Km, with 39Ar/40Ar, U-Pb and Palaeontology used to provide age constraints. Ages from the new data range from ~100 to 81?Ma, with three main events (cr. 100, 91 and 82-81?Ma). Volcanic events are occurring within the Early to Late Cretaceous, along this part of the margin with a general younging towards Namibia. With the constraints of additional age information both onshore and offshore Angola, a clear younging trend at the early stages of rift to drift is recorded in the volcanic events that unzip from North to South. Similar age volcanic events are reported from the Brazilian side of the conjugate margin, and highlight the need to fully incorporate these relatively low volume volcanic pulses into the plate tectonic breakup models of the South Atlantic Margin.
Abstract: The tectonic setting of northeastern Angola was influenced by the opening of the South Atlantic Ocean, which reactivated deep NE-SW-trending faults during the early Cretaceous. The new interpretation of a kimberlitic pulse during the middle of the Aptian and the Albian, which provides precise data on the age of a significant diamond-bearing kimberlite pulse in Angola, will be an important guide in future diamond exploration. These findings contribute to a better understanding of the petrogenetic evolution of the kimberlites in northeastern Angola and have important implications for diamond exploration. Six kimberlite pipes within the Lucapa structure in northeastern Angola have been investigated using major and trace element geochemistry of mantle xenoliths, macro- and megacrysts. Geothermobarometric calculations were carried out using xenoliths and well-calibrated single crystals of clinopyroxene. Geochronological and isotopic studies were also performed where there were samples available of sufficient quality. Results indicate that the underlying mantle experienced variable conditions of equilibration among the six sites. Subsequent metasomatic enrichment events also support a hypothesis of different sources for these kimberlites. The U/Th values suggest at least two different sources of zircon crystals from the Catoca suite. These different populations may reflect different sources of kimberlitic magma, with some of the grains produced in U- and Th-enriched metasomatized mantle units, an idea consistent with the two populations of zircon identified on the basis of their trace element compositions. This research shows the absence of fresh Mg-rich ilmenite in the Catoca kimberlite (one of the largest bodies of kimberlite in the world), as well as the occurrence of Fe3+-rich ilmenite, do not exclude the presence of diamond in the kimberlite. This is a new insight into the concept of ilmenite and diamond exploration and leads to the conclusion that compositional attributes must be evaluated in light of textural attributes.
Africa, Sierra Leone, Democratic Republic of Congo, Angola
legal
Abstract: This article investigates the impact of the world price of a “lootable,” labor-intensive natural resource on intensity of violent conflict. Results suggest that a price increase can have opposite effects at different geographical levels of analysis: a decrease in conflict intensity overall in resource-rich countries, but an increase in conflict intensity in resource-rich subnational regions. The article argues that intensity of violence decreases overall due to rising opportunity costs of rebellion but that violence concentrates in resource-rich areas as returns to looting rise. The article introduces a new measure of diamond propensity based on geological characteristics, which is arguably exogenous to conflict and can capture small-scale labor-intensive production better than existing measures. The stated effects are found for secondary diamonds, which are lootable and related to opportunity costs of fighting, but not for primary diamonds, which are neither.
2019 Twelth International Conference Oct 1-3. Moscow, IEEE DOI 11.09/MLSD .2019.8911014
Africa, Angola, Russia, Yakutia
geophysics
Abstract: We show how to increase the effectiveness of the prognoses of kimberlite bodies by using airborne geophysical technologies. We show the advantages of electromagnetic and magnetic methods for predicting kimberlite pipes. You will see examples of a regional diamond survey in Angola and Siberia.
The Journal of the Southern African Insitute of Mining and Metallurgy, Vol. 119, Feb, 9p. Pdf
Africa, South Africa, Zimbabwe, Namibia, Angola, DRC, Lesotho, Botswana, eSwatini
production
Abstract: Southern Africa is generally thought to be well explored, with only limited potential for major new diamond discoveries. However, Chiadzwa in Zimbabwe and reports of a significant new kimberlite find in Angola are testimony to the dangers attached to an attitude that 'there is nothing left to find'.
Since the major discoveries in the central interior of South Africa in the 1870s, diamond exploration in the region has been led by market and political factors that influence the key exploration drivers of opportunity and value proposition. Unexpected new discoveries by new players always impact on existing producers and, from time to time, denial of opportunity through political or protectionist policies has inhibited investment in exploration. Entrepreneurial exploration appetite in southern Africa will be tempered by the potential value equation and security of investment. Overlaid on this, developments in diamond recovery technologies provide opportunity to reinvigorate current mines and old prospects previously considered too difficult or costly to exploit. Position on the cost curve will remain a key factor for survival in an increasingly competitive environment.
Communicacoes Geologicas *** in PORT, researchgate 7p. Pdf
Africa, Angola
deposit - Bailundo
Abstract: Pyrochlore group minerals are common accessory phases in alkaline-carbonatitic complexes, and the most important Nb ore worldwide. Its capacity to embody a wide range of compositions can often provide useful insights in Nb occurrence and concentration processes. In the Bailundo Carbonatitic Complex (BCC, Angola), two major sets of pyrochlore can be distinguished: (1) magmatic/metasomatic pyrochlore in deep carbonatitic rocks, often displaying diffuse textures obliterating primary zoning, with slightly low contents in Nb2O5 (average 50 wt%), and in other chemical components (Ta, U, Na); and (2) supergene pyrochlore in the weathering profile, displaying corroded and bleached patches along microfractures (in some cases, with relics of magmatic pyrochlore), that show higher contents in Nb2O5 (up to 73 wt%), Ba and Pb. Compositional and textural variations recorded in pyrochlore crystals illustrate the geodynamic events that took place in the BCC and contributed to high Nb concentration in the weathering profile, thus being quite useful to distinguish different mineralization types and as Nb-exploration tools.
South African Historical Journal, Vol. 72, 3, pp. 431-460.
Africa, Angola
history
Abstract: In the wake of the Anthropocene there is a growing body of literature questioning the colonial and imperialistic underpinnings of geology, mineralogy and mining sciences. When focused on the African continent, these critiques echo and complement previous analyses of the role that anthropology has played as the ‘handmaiden of colonialism’. This article proposes to liken the two debates by focusing on the ethnographic practices promoted by the Angolan diamond mining company Diamang (1917-1988) during the interwar period. It argues that mineral desire, the greed for mineral resources such as diamonds, copper or gold, was the drive behind the introduction of ethnographic collecting and field-working to the Portuguese colony. The implications of this shift in perspective will be explored regarding the ongoing restitution debate. First, the article demonstrates that the history of the objects collected by Diamang disrupts ‘classic’ readings of the history of Portuguese anthropology focused on ‘disciplinary big men’ and their agendas. Second, it shows how the gathering and interpretation of ethnographic and archaeological data were totally integrated into the extractive apparatus of Diamang. The article then concludes by suggesting that the decolonisation of ethnographic collections must consider their entanglements with mining, geology and mineralogy.
Abstract: Very few zircon-bearing, kimberlite-hosted mantle eclogite xenoliths have been identified to date; however, the zircon they contain is crucial for our understanding of subcratonic lithospheric mantle evolution and eclogite genesis. In this study, we constrain the characteristics of zircon from mantle eclogite xenoliths based on existing mineralogical and geochemical data from zircons from different geological settings, and on the inferred origin of mantle eclogites. Given the likely origin and subsequent evolution of mantle eclogites, we infer that the xenoliths can contain zircons with magmatic, metamorphic and xenogenic (i.e. kimberlitic zircon) origins. Magmatic zircon can be inherited from low-pressure mafic oceanic crust precursors, or might form during direct crystallization of eclogites from primary mantle-derived melts at mantle pressures. Metamorphic zircon within mantle eclogites has a number of possible origins, ranging from low-pressure hydrothermal alteration of oceanic crustal protoliths to metasomatism related to kimberlite magmatism. This study outlines a possible approach for the identification of inherited magmatic zircon within subduction-related mantle eclogites as well as xenogenic kimberlitic zircon within all types of mantle eclogites. We demonstrate this approach using zircon grains from kimberlite-hosted eclogite xenoliths from the Kasai Craton, which reveals that most, if not all, of these zircons were most likely incorporated as a result of laboratory-based contamination.
Journal of African Earth Sciences, Vol. 177, 104154, 16p. Pdf
Africa, Angola
deposit - Bailundo
Abstract: Pyrochlore is a common accessory in carbonatite rocks and its composition can provide useful insights on petrogenetic and post-magmatic metal-enrichment processes, especially those which favour its occurrence and concentration. Comprehensive compositional and textural characterization of a large set of pyrochlores from the Bailundo Carbonatite Complex (SW Angola) and associated surface rocks was the basis to (i) evaluate the main effects of metasomatism and weathering as causes of metal leaching or concentration; and (ii) assess pyrochlore compositions as potential petrogenetic or metallogenetic tools, with particular emphasis on pyrochlore enrichment in economic components, such as Ta, REE, U, Th and Pb, during weathering processes. Unweathered fluor- and hydroxyl-calciopyrochlores from deep-seated carbonatitic rocks (provided by a 600 m-deep drill-core) often present high Ta/Nb ratios, as well as high U and Th contents, and comparatively low overall REE concentrations. Metasomatic effects are not easy to assess, given the extreme compositional variability of these pyrochlores. On the other hand, some systematic trends can be established in pyrochlores from weathered surface rocks: these pyrochlores usually show strong depletion in most A-site cations (e.g., Na, Ca, U), and clear enrichment in Nb and in large-ion metals (e.g., Ba, Sr, Pb) usually absent in unweathered pyrochlores. REE seem to be relatively immobile and to become concentrated during weathering. Along with some REE phosphates and oxides, pyrochlore is often present in several domains of the weathering profile, occurring in the outcropping weathered carbonatite as well as in the regolith immediately overlying the intrusion. Thus, both the Bailundo carbonatite intrusion and its weathering products, concentrated inside the ridge formed by differential erosion of the fenitic aureole, constitute good exploration targets for Nb (±Ta ± REE). However, future exploration work should also include a 3-D understanding of the chemical and geological processes at work in both geological environments.
Comminocacoes Geologicas ( Researchgate), July, 7p. Pdf
Africa, Angola
deposit - Bailundo
Abstract: Pyrochlore group minerals are common accessory phases in many rock types of the Bailundo Carbonatite Complex. These minerals record compositional and textural features that provide useful information regarding their genesis and accumulation, monitoring magmatic, metasomatic and weathering events. In drill core samples, primary compositions (significant Ta and U contents, and relatively low Nb and F values) are found in relict cores of strongly metasomatized pyrochlore grains; irregular patches in pyrochlore rims, typically enriched in F, Na and Nb, reflect fluid alteration fronts. At shallower levels, preserved pyrochlores show well-defined concentric zoning and substantially higher values of F and Nb. In the weathering profile, alteration processes include replacement of F, Na and Ca by Ba, Sr, Pb and H2O. These data suggest the possibility of Nb concentration in late-magmatic fluids as fluoride complexes, and its subsequent mobilization and crystallization in the form of pyrochlore at shallower levels of the Bailundo Carbonatite Complex.
Abstract: In the early 1990s several rebel groups turned to natural resource extraction to pay for war. A key form of this is rebel diamond production, commonly referred to as conflict diamonds, which is widely perceived as being highly beneficial to insurgent organisations. Yet in the Angolan Civil War (1992-2002), the use of conflict diamonds by the National Union for the Total Independence of Angola (UNITA) resulted in a decisive insurgent defeat. How can this outcome be explained? Offering a nuanced understanding of how conflict diamonds affect civil war, this article shows that although diamonds generated considerable revenue for UNITA, they were not an effective method for them to take on the Angolan government. This was for two reasons: internally, the rebels greatly struggled to convert their diamond proceeds into sufficient goods and services; and externally, it left the group highly vulnerable to international countermeasures in the form of United Nations Security Council sanctions. Natural resource extraction may therefore not be as useful to rebel groups as is frequently believed.
Journal of Petrology, 10.1093/petrology /egab070 98p. Pdf
Africa, Angola
deposit - Catoca
Abstract: Reconstructed whole-rock and mineral major- and trace-element compositions, as well as new oxygen isotope data, for 22 mantle eclogite xenoliths from the Catoca pipe (Kasai Craton) were used to constrain their genesis and evolution. On the basis of mineralogical and major-element compositions, the Catoca eclogites can be divided into three groups: high-alumina (high-Al) (kyanite-bearing), low-magnesian (low-Mg#), and high-magnesian (high-Mg#) eclogites. The high-Al Catoca eclogites contain kyanite and corundum; high Al2O3 contents in rock-forming minerals; rare earth element (REE) patterns in garnets showing depleted LREEs, positive Eu anomalies (1.03-1.66), and near-flat HREEs; and high Sr contents in garnets and whole-rock REE compositions. All of these features point to a plagioclase-rich protolith (probably gabbro). Reconstructed whole-rock compositions (major elements, MREEs, HREEs, Li, V, Hf, Y, Zr, and Pb) and ?18O of 5.5-7.4‰ of the low-Mg# Catoca eclogites are in good agreement with the compositions of picrite basalts and average mid-ocean ridge basalt (MORB). The depleted LREEs and NMORB-normalised Nd/Yb values of 0.07-0.41 indicate that the degree of partial melting for the majority of the low-Mg# eclogites protolith was ?30%. The narrow ?18O range of 5.5-7.4‰ near the ‘gabbro-basalt’ boundary (6‰) obtained for the high-Al and low-Mg# Catoca eclogites reflects the influence of subduction-related processes. This case shows that mantle eclogites represented by two different lithologies and originating from different protoliths — plagioclase-rich precursor, presumably gabbro (for high-Al eclogites), and basalt (low-Mg# eclogites) — can provide similar and overlapping ?18O signatures on account of the influence of subduction-related processes. Chemical compositions of the high-Mg# eclogites indicate a complicated petrogenesis, and textural signatures reveal recrystallisation. The presence of Nb-rich rutile (8-12 wt% of Nb2O5) enriched with HFSE (Zr/Hf of 72.6-75.6) and multiple trace-element signatures (including reconstructed whole-rock NMORB-normalised Ce/Yb of 3.9-10.6 and Sr/Y of 5.8-9.6, MgO contents of 15.7-17.9 wt%, and high Ba and Sr) provide strong evidence for deep metasomatic alteration. High Cr contents in clinopyroxene (800-3740 ppm), garnet (430-1400 ppm), and accessory rutile (700-2530 ppm), together with extremely low Li contents of 1.0-2.4 ppm in clinopyroxene, may indicate hybridisation of the eclogites with peridotite. Comparison of the chemical compositions (major and trace elements) of (1) unaltered fresh cores of coarse-grained garnets from the low-Mg# eclogites, (2) secondary garnet rims (ubiquitous in the low-Mg# eclogites), (3) proto-cores in the coarse-grained garnet (high-Mg# eclogites), and (4) homogeneous recrystallised fine-grained garnets (high-Mg# eclogites) suggests that the high-Mg# eclogites formed through recrystallisation of low-Mg# eclogite in the presence of an external fluid in the mantle. Four of the five high-Mg# samples show that mantle metasomatism inside the Kasai craton mantle beneath the Catoca pipe occurred at a depth range of 145-160 km (4.5-4.8 GPa).
Abstract: Reconstructed whole-rock (RWR) and mineral major- and trace-element compositions, as well as new oxygen isotope data, for 22 mantle eclogite xenoliths from the Catoca pipe (Kasai Craton) were used to constrain their genesis and evolution. On the basis of mineralogical and major-element compositions, the Catoca eclogites can be divided into three groups: high-alumina (high-Al) (kyanite-bearing), low-magnesian (low-Mg#), and high-magnesian (high-Mg#) eclogites. The high-Al Catoca eclogites contain kyanite and corundum; high Al2O3 contents in rock-forming minerals; rare earth element (REE) patterns in garnets showing depleted LREEs, positive Eu anomalies (1.03-1.66), and near-flat HREEs; and high Sr contents in garnets and whole-rock REE compositions. All of these features point to a plagioclase-rich protolith (probably gabbro). RWR compositions (major elements, MREEs, HREEs, Li, V, Hf, Y, Zr, and Pb) and ?18O of 5.5-7.4‰ of the low-Mg# Catoca eclogites are in good agreement with the compositions of picrite basalts and average mid-ocean ridge basalt (MORB). The depleted LREEs and NMORB-normalised Nd/Yb values of 0.07-0.41 indicate that the degree of partial melting for the majority of the low-Mg# eclogites protolith was ?30%. The narrow ?18O range of 5.5-7.4‰ near the ‘gabbro-basalt’ boundary (6‰) obtained for the high-Al and low-Mg# Catoca eclogites reflects the influence of subduction-related processes. This case shows that mantle eclogites represented by two different lithologies and originating from different protoliths—plagioclase-rich precursor, presumably gabbro (for high-Al eclogites), and basalt (low-Mg# eclogites)—can provide similar and overlapping ?18O signatures on account of the influence of subduction-related processes. Chemical compositions of the high-Mg# eclogites indicate a complicated petrogenesis, and textural signatures reveal recrystallisation. The presence of Nb-rich rutile (8-12 wt% of Nb2O5) enriched with high field strength elements (HFSE) (Zr/Hf of 72.6-75.6) and multiple trace-element signatures (including RWR, NMORB-normalised Ce/Yb of 3.9-10.6 and Sr/Y of 5.8-9.6, MgO contents of 15.7-17.9 wt%, and high Ba and Sr) provide strong evidence for deep metasomatic alteration. High Cr contents in clinopyroxene (800-3740 ppm), garnet (430-1400 ppm), and accessory rutile (700-2530 ppm), together with extremely low Li contents of 1.0-2.4 ppm in clinopyroxene, may indicate hybridisation of the eclogites with peridotite. Comparison of the chemical compositions (major and trace elements) of (1) unaltered fresh cores of coarse-grained garnets from the low-Mg# eclogites, (2) secondary garnet rims (ubiquitous in the low-Mg# eclogites), (3) proto-cores in the coarse-grained garnet (high-Mg# eclogites), and (4) homogeneous recrystallised fine-grained garnets (high-Mg# eclogites) suggests that the high-Mg# eclogites formed through recrystallisation of low-Mg# eclogite in the presence of an external fluid in the mantle. Four of the five high-Mg# samples show that mantle metasomatism inside the Kasai craton mantle beneath the Catoca pipe occurred at a depth range of 145-160 km (4.5-4.8 GPa).
Abstract: A database of microprobe EPMA and ICP MS analysis of the kimberlite indicator minerals > 20,000 of the Lunda and Kukumbi-Kwango kimberlite regions were used for construction of series PTCFO2 diagrams for mantle section beneath major kimberlite pipes the and profile through the subcontinental lithospheric mantle (SLM) beneath the NE Angolan Kasai craton within the Lucapa tectonic "corridor", which controls the kimber-lite volcanism in the North of Angola. The general construction of the mantle sections are similar for most pipes but details of the structure refer t the mineralogy and degree of the hydrous metasomatism. The vertical and lat-eral heterogeneity of the mantle in this region and the PTCFO2 parameters in mantle beneath diamond-bearing kimberlite pipes were calculated. There is the inclination of the general mantle structure toward the SW marked by the depleted layer of mantle peridotites. The local dome-like structures are found near the lithosphere base beneath Catoca, Luaxe field and other kimberlite regions. Mapping of the upper mantle beneath the Angolan Archaean cratons of is a relatively pioneer direction in the regional diamond forecasting, developed by the authors.
Abstract: The Zambezi rises with considerable modesty in north-west Zambia from a small spring on the gentle upland of the Southern Equatorial Divide - the watershed that separates the river from north-west-flowing tributaries of the Congo. The evolution of the Zambezi River has repeatedly modified the distribution of riverine plant and animal species. The hydrology of the Zambezi is further influenced by water exploitation by different users, along its main channel and tributaries. The dams have had severe ecological impacts on the major floodplains, as a result of the reduction of the supply of water and sediment. The major Early Cretaceous Zambezi-Limpopo River system entered the Mozambique coastal plain via a line of crustal weakness that was exploited by a major west-north-west trending dyke swarm. Drainage evolution of the Palaeo-Chambeshi system has been invoked as the primary cause of the recent evolution of the molerats.