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The Sheahan Diamond Literature Reference Compilation - Technical, Media and Corporate Articles based on Major Region - Spain
The Sheahan Diamond Literature Reference Compilation is compiled by Patricia Sheahan who publishes on a monthly basis a list of new scientific articles related to diamonds as well as media coverage and corporate announcements called the Sheahan Diamond Literature Service that is distributed as a free pdf to a list of followers. Pat has kindly agreed to allow her work to be made available as an online digital resource at Kaiser Research Online so that a broader community interested in diamonds and related geology can benefit. The references are for personal use information purposes only; when available a link is provided to an online location where the full article can be accessed or purchased directly. Reproduction of this compilation in part or in whole without permission from the Sheahan Diamond Literature Service is strictly prohibited. Return to Diamond Region Index
Sheahan Diamond Literature Reference Compilation - Scientific Articles by Author for all years
Each article reference in the SDLRC is tagged with one or more key words assigned by Pat Sheahan to highlight the main topics of the article. In addition most references have been tagged with one or more region words. In an effort to make it easier for users to track down articles related to a specific region, KRO has extracted these region words and developed a list of major region words presented in the Major Region Index to which individual region words used in the article reference have been assigned. Each individual Region Report contains in chronological order all the references with a region word associated with the Major Region word. Depending on the total for each reference type - technical, media and corporate - the references will be either in their own technical, media or corporate Region Report, or combined in a single report. Where there is a significant number of technical references there will be a technical report dedicated to the technical articles while the media and corporate references are combined in a separate region report. References that were added in the most recent monthly update are highlighted in yellow within the Region Report. The Major Region words have been defined by a scale system of "general", "continent", "country", "state or province" and "regional". Major Region words at the smaller scales have been created only when there are enough references to make isolating them worthwhile. References not tagged with a Region are excluded, and articles with a region word not matched with a Major Region show up in the "Unknown" report.
Kimberlite - diamondiferous
Lamproite - diamondiferous
Lamprophyre - diamondiferous
Other - diamondiferous
Kimberlite - non diamondiferous
Lamproite - non diamondiferous
Lamprophyre - non diamondiferous
Other - non diamondiferous
Kimberlite - unknown
Lamproite - unknown
Lamprophyre - unknown
Other - unknown
Future Mine
Current Mine
Former Mine
Click on icon for details about each occurrence. Works best with Google Chrome.
CITATION: Faure, S, 2010, World Kimberlites CONSOREM Database (Version 3), Consortium de Recherche en Exploration Minérale CONSOREM, Université du Québec à Montréal, Numerical Database on consorem.ca. NOTE: This publicly available database results of a compilation of other public databases, scientific and governmental publications and maps, and various data from exploration companies reports or Web sites, If you notice errors, have additional kimberlite localizations that should be included in this database, or have any comments and suggestions, please contact the author specifying the ID of the kimberlite: [email protected]
The Ronda peridotite and lamproites in Spain. Salmeron, Jumill, Cerro Canbezo Maria. Chemical analyses of lamproite/ Isotopic systematics of lamproites.
Mineral variations from Mediterranean lamproites: major element compositions and first indications from trace elements in phlogopites, olivines and clinopyroxenes.
Persistence of mantle lithospheric Re-Os signature during asthenospherization of the subcontinental lithospheric mantle: insights in situ sulphides....
Contributions to Mineralogy and Petrology, Vol. 159, 3, pp. 315-330.
Electron back scatter diffraction based identification and quantification of diamonds from the RIF gneisses ( Spain and Morocco): economic implications.
Gonzalez-Jimienez, J.M., Marchesi, C., Griffin, W.L., Gutierrez-Narbona, R., Lorand, J-P., O'Reilly, S.Y., Garrido, C.J., Gervilla, F., Pearson, N.J., Hidas, K.
Transfer of Os isotopic signatures from peridotite to chromitite in the subcontinental mantle: insights from in situ analysis of platinum-group and base metal minerals (Ojen peridotite massif, southern Spain.
Contributions to Mineralogy and Petrology, Vol. 169, pp. 52-
Europe, Spain
Deposit - Ronda
Abstract: Chemical weathering of dark-green massive peridotite, including partly serpentinized peridotite, produces a distinct and remarkable brown weathering rind when exposed to the atmosphere long enough. The structure and mineral composition of crusts on rocks from the Ronda peridotite, Spain, have been studied in some detail. The generic overall weathering reaction serpentinized peridotite + rainwater = weathering rind + runoff water describes the crust-forming process. This hydration reaction depends on water supply from the outcrop surface to the reaction front separating green peridotite from the brown crust. The reaction pauses after drying and resumes at the front after wetting. The overall net reaction transforms olivine to serpentine in a volume-conserving replacement reaction. The crust formation can be viewed as secondary serpentinization of peridotite that has been strongly altered by primary hydrothermal serpentinization. The reaction stoichiometry of the crust-related serpentinization is preserved and reflected by the composition of runoff waters in the peridotite massif. The brown color of the rind is caused by amorphous Fe(III) hydroxide, a side product from the oxidation of Fe(II) released by the dissolution of fayalite component in olivine.
Abstract: Detailed textural and mineral chemistry characterisation of lamproites from the Socovos fault zone, SE Spain Neogene Volcanic Province (NVP) combining X-ray element maps and LA-ICP-MS spot analyses has provided valuable information about mantle depth ultrapotassic magma mixing processes. Despite having similar whole-rock compositions, rocks emplaced in the Socovos fault are mineralogically varied: including type-A olivine-phlogopite lamproites; and type-B clinopyroxene-phlogopite lamproites. The Ol-lacking type-B predates Ol-bearing type-A by c. 2 million years. We propose that the mineralogical variations, which are representative of lamproites in the NVP as a whole, indicate mantle source heterogeneities. Major and trace element compositions of mineral phases suggest both metasomatised harzburgite and veined pyroxenite sources that were most likely closely spatially related. Thin section scale textural and compositional variations in mineral phases reveal heterogeneous mantle- and primitive magma-derived crystals. The variety of crystals points to interaction and mingling-mixing of ultrapotassic magma batches at mantle depths prior crustal emplacement. The mixing apparently occurred in a mantle melting zone with a channelised flow regime and localised magma chambers-reservoirs. Magma interaction was interrupted when the Socovos and other lithosphere-scale faults tore down to the mantle source region, triggering rapid ascent of the heterogeneous lamproite magma.
Abstract: It is now accepted that significant volumes of pyroxenites are generated in the subduction factory and remain trapped in the mantle. In ophiolites and orogenic massifs the geometry of pyroxenite layers and their relationships with the host peridotite can be observed directly. Since a large part of what is known about the upper mantle structure is derived from the analysis of seismic waves, it is crucial to integrate pyroxenites in the interpretations. We modeled the seismic properties of a peridotitic mantle rich in pyroxenite layers in order to determine the impact of layering on the seimsic properties. To do so, EBSD data on deformed and undeformed pyroxenites from the Cabo Ortegal complex (Spain) and the Trinity ophiolite (California, USA) respectively are combined with either A or B-type olivine fabrics in order to model a realistic pyroxenite-rich upper mantle. Consideration of pyroxeniterich domains within the host mantle wall rock is incorporated in the calculations using the Schoenberg and Muir group theory [1]. This quantification reveals the complex dependence of the seismic signal on the deformational state and relative abundance of each mineral phase. The incorporation of pyroxenites properties into geophysical interpretations in understanding the lithospheric structure of subduction zones will lead to more geologically realistic models.
Geochimica et Cosmochimica Acta, Vol. 232, pp. 303-328.
Africa, Morocco, Europe, Spain
UHP
Abstract: We present an integrated geochemical study of ultra-high pressure (UHP) garnet pyroxenites from the Ronda and Beni Bousera peridotite massifs (Betic-Rif Belt, westernmost Mediterranean). Based on their Sr-Nd-Pb-Hf isotopic systematics, we classify UHP garnet pyroxenites into three groups: Group A pyroxenites (Al 2 O 3 : 15-17.5 wt. %) have low initial 87 Sr/ 86 Sr, relatively high ? Nd , ? Hf and 206 Pb/ 204 Pb ratios, and variable 207 Pb/ 204 Pb and 208 Pb/ 204 Pb. Group B pyroxenites (Al 2 O 3 < 14 wt. %) are characterized by high initial 87 Sr/ 86 Sr and relatively low ? Nd , ? Hf and 206 Pb/ 204 Pb ratios. Group C pyroxenites (Al 2 O 3 ~ 15 wt. %) have depleted radiogenic signatures with relatively low initial 87 Sr/ 86 Sr and 206 Pb/ 204 Pb, high ? Nd and ? Hf , and their 207 Pb/ 204 Pb and 208 Pb/ 204 Pb ratios are similar to those of Group B pyroxenites. The major and trace element and isotopic compositions of UHP garnet pyroxenites support their derivation from ancient (1.5-3.5 Ga) oceanic crust recycled into the mantle and intimately stirred with peridotites by convection. However, the genesis of these pyroxenites requires also the involvement of recycled continental lower crust with an isotopic composition akin to the lower crustal section of the lithosphere where these UHP garnet pyroxenites now reside in. These oceanic and continental crustal components were stirred in different proportions in the convective mantle, originating pyroxenites with a more marked geochemical imprint of either oceanic (Group A) or continental lower crust (Group B), or hybrid compositions (Group C). The pyroxenite protoliths likely underwent several melting events, one of them related to the formation of the subcontinental lithospheric mantle and continental crust, generating restitic UHP garnet pyroxenites now preserved in the Ronda and Beni Bousera orogenic peridotites. The extent of melting was mostly 3 controlled by the bulk Mg-number (Mg#) of the pyroxenite protoliths, where protoliths with low Mg# experienced higher degrees of partial melting than sources with higher Mg#. Positive Eu and Sr anomalies in bulk rocks, indicative of their origin from cumulitic crustal gabbros, are preserved mostly in high Mg# pyroxenites due to their higher melting temperatures and consequent lower partial melting degrees. The results of this study show that the genesis of UHP garnet pyroxenites in orogenic peridotites requires a new recipe for the marble cake mantle hypothesis, combining significant recycling and stirring of both oceanic and continental lower crust in the Earth's mantle. Furthermore, this study establishes a firm connection between the isotopic signatures of UHP pyroxenite heterogeneities in the mantle and the continental lower crust.
Journal of Geochemical Exploration, Vol. 204, pp. 270-288.
Europe, Spain
REE
Abstract: Gran Canaria is a hotspot-derived, intraplate, oceanic island, comprising a variety of alkaline felsic magmatic rocks (i.e. phonolites, trachytes, rhyolites and syenites). These rocks are enriched in rare-earth elements (REE) in relation to the mean concentration in the Earth's crust and they are subsequently mobilised and redistributed in the soil profile. From a set of 57 samples of felsic rocks and 12 samples from three paleosol profiles, we assess the concentration and mobility of REE. In the saprolite that developed over the rhyolites, we identified REE-bearing minerals such as primary monazite-(Ce), as well as secondary phases associated with the edaphic weathering, such as rhabdophane-(Ce) and LREE oxides. The averaged concentration of REE in the alkaline bedrock varies from trachytes (449?mg?kg?1), to rhyolites (588?mg?kg?1) and to phonolites (1036?mg?kg?1). REE are slightly enriched in saprolites developed on trachyte (498?mg?kg?1), rhyolite (601?mg?kg?1) and phonolite (1171?mg?kg?1) bedrocks. However, B-horizons of paleosols from trachytes and phonolites showed REE depletion (436 and 994?mg?kg?1, respectively), whereas a marked enrichment was found in soils developed on rhyolites (1584?mg?kg?1). According to our results, REE resources on Gran Canaria are significant, especially in Miocene alkaline felsic magmatic rocks (declining stage) and their associated paleosols. We estimate a total material volume of approximately 1000?km3 with REE concentrations of 672?±?296?mg?kg?1, yttrium contents of 57?±?30?mg?kg?1, and light and heavy REE ratios (LREE/HREE) of 17?±?6. This mineralisation can be considered as bulk tonnage and low-grade ore REE deposits but it remains necessary to develop detailed mineral exploration on selected insular zones in the future, without undermining environmental and socioeconomic interests.
Lithos, doi 10.1016/j.lithos.2019.105215, 75p. Pdf
Europe, Spain
deposit - Ronda
Abstract: We present a detailed study of the water geochemistry, mineralogy and textures in serpentinization-related hyperalkaline springs in the Ronda peridotites. Ronda waters can be classified into hyperalkaline fluids and river waters that are broadly similar to Ca2+-OH- and Mg2+-HCO3- water types described in serpentinite-hosted alkaline springs elsewhere. At the discharge sites of the fluids (fractures or human made outlets) and ponds along the fluid flow paths, the fluids are hyperalkaline (10.9 < pH < 12) and characterized by low Mg and high Na, K, Ca, and Cl concentrations. River waters, occurring near the spring sites, are mildly alkaline (8.5 < pH < 8.9) and enriched in Mg and DIC compared to Na, K, Ca and Cl. The chemistry of Ronda Mg-HCO3 river waters is likely due to the hydrolysis of ferromagnesian peridotite minerals in equilibrium with the atmosphere by infiltrated meteoric water and shallow groundwater in the serpentinized peridotite. The Ronda Ca-OH hyperalkaline fluids are generated by the combination of low temperature serpentinization reactions from infiltrated surface Mg-HCO3 river waters —or Ca-HCO3 waters from near karst aquifers— and deep carbonate precipitation isolated from atmospheric CO2. Mass balance calculations indicate that the weathering of Ca-bearing peridotite silicates such as diopside is a feasible source of Ca in Ronda Ca-OH hyperalkaline fluids; however, it requires steady-state dissolution rates substantially greater than those determined experimentally. Travertine, crystalline crusts and sediment deposits are the main types of solid precipitates observed in Ronda hyperalkaline spring sites. Calcite and aragonite, minor dolomite and Mg-Al-rich clays are the main minerals in the spring sites. As illustrated in the Baños del Puerto spring site, (i) calcite-dominated precipitation is due to hyperalkaline fluid uptake of atmospheric CO2 during discharge, and (ii) aragonite-dominated precipitation is due to mixing of Ca-OH hyperalkaline fluids with Mg- HCO3 river waters. Aragonite and dolomite contents increase away from the springs and toward the river waters that uniquely reflects the effect of Mg ions on the precipitation of aragonite versus calcite. Other potential factors controlling the precipitation of these CaCO3 polymorphs are the Mg/Ca ratio, the CO2 content, and the temperature of the fluids. Dolomite forms during lithification of travertine due to periodic flooding of river water combined with subsequent evaporation.
Toscani, L., Salvioli-Mariani, E., Mattioli, M., Tellini, C., Boschetti, T., Iacumin, P., Selmo, E.
The pyroclastic breccia of the Cabezo Negro de Tallant ( SE Spain): the first finding of carbonatite volcanism in the internal domain of the Betic Cordillera.
Abstract: Mantle lithologies in orogenic massifs and xenoliths commonly display strikingly different Hf- and Nd-isotope compositions compared to oceanic basalts. While the presence of pyroxenites has long been suggested in the source region of mantle-derived magmas, very few studies have reported their combined HfNd isotope compositions. We here report the first LuHf data along with ReOs data and S concentrations on the Cabo Ortegal Complex, where the pyroxenite-rich Herbeira massif has been interpreted as remnants of a delaminated arc root. The pyroxenites, chromitites and their host harzburgites show a wide range of whole-rock 187Re/188Os and 187Os/188Os (0.16-1.44), indicating that Re was strongly mobilized, partly during hydrous retrograde metamorphism but mostly during supergene alteration that preferentially affected low-Mg#, low Cu/S pyroxenites. Samples that escaped this disturbance yield an isochron age of 838 ± 42 Ma, interpreted as the formation of Cabo Ortegal pyroxenites. Corresponding values of initial 187Os/188Os (0.111-0.117) are relatively unradiogenic, suggesting limited contributions of slab-derived Os to primitive arc melts such as those parental to these pyroxenites. This interpretation is consistent with radiogenic Os in arc lavas being mostly related to crustal assimilation. Paleoproterozoic to Archean Os model ages confirm that Cabo Ortegal pyroxenites record incipient volcanic arc magmatism on the continental margin of the Western African Craton, as notably documented by zircon UPb ages of 2.1 and 2.7 Ga. LuHf data collected on clinopyroxene and amphibole separates and whole-rock samples are characterized by uncorrelated 176Lu/177Hf and 176Hf/177Hf (0.2822-0.2855), decoupled from Nd-isotope compositions. This decoupling is ascribed to diffusional disequilibrium during melt-peridotite interaction, in good agreement with the results of percolation-diffusion models simulating the interaction of an arc melt with an ancient melt-depleted residue. These models notably show that HfNd isotopic decoupling such as recorded by Cabo Ortegal pyroxenites and peridotites (??Hf(i) up to +97) is enhanced during melt-peridotite interaction by slow diffusional re-equilibration and can be relatively insensitive to chromatographic fractionation. Finally, we discuss the hypothesis that arc-continent interaction may provide preferential conditions for such isotopic decoupling and propose that its ubiquitous recognition in peridotites reflects the recycling of sub-arc mantle domains derived from ancient, reworked SCLM.
Neues Jahbuch fur Mineralogie, Vol. 196, 3, pp. 193-196.
Europe, Spain
lamproite
Abstract: Al analogue of chayesite (with Al > Fe3+) was found in a lamproite from Cancarix, SE Spain. The mineral forms green thick-tabular crystals up to 0.4 mm across in cavities. The empirical formula derived from EMP measurements and calculated on the basis of 17 Mg + Fe + Al + Si apfu is (K0.75 Na0.20 Ca0.11)Mg3.04 Fe0.99 Al1.18 Si11.80 O30. The crystal structure was determined from single crystal X-ray diffraction data ( R = 2.38%). The mineral is hexagonal, space group P 6/ mcc, a = 10.09199(12), c = 14.35079(19) Å, V = 1265.78(3) Å3, Z = 2. Fe is predominantly divalent. Al is mainly distributed between the octahedral A site and the tetrahedral T 2 site. The crystal chemical formula derived from the structure refinement is C (K0.73 Na0.16 Ca0.11) B (Na0.02)4 A (Mg0.42 Al0.29 Fe0.29)2 T 2(Mg0.71 Fe0.16 Al0.13)3 T 1(Si0.985 Al0.015)12 O30.
Geological Society, London Special Publication, doi.org/10.1144/SP513-2021-36 49p. Pdf
Europe, Italy, France, Spain, Serbia, Macedonia, Turkey
lamproites
Abstract: High-MgO lamproite and lamproite-like (i.e., lamprophyric) ultrapotassic rocks are recurrent in the Mediterranean and surrounding regions. They are associated in space and time with ultrapotassic shoshonites and high-K calc-alkaline rocks. This magmatism is linked with the geodynamic evolution of the westernmost sector of the Alpine-Himalaya collisional margin, which followed the closure of the Tethys ocean. Subduction-related lamproites, lamprophyres, shoshonites and high-K calc-alkaline suites were emplaced in the Mediterranean region in the form of shallow level intrusions (e.g., plugs, dykes, and laccoliths), and small volume lava flows, with very subordinate pyroclastic rocks, starting from the Oligocene, in the Western Alps (Northern Italy), through the Late Miocene in Corsica (Southern France) and in Murcia-Almeria (South-Eastern Spain), to the Plio-Pleistocene in Southern Tuscany and Northern Latium (Central Italy), in the Balkan peninsula (Serbia and Macedonia), and in the Western Anatolia (Turkey). The ultrapotassic rocks are mostly lamprophyric, but olivine latitic lavas with a clear lamproitic affinity are also found, as well as dacitic to trachytic differentiated products. Lamproite-like rocks range from slightly silica under-saturated to silica over-saturated composition, have relatively low Al2O3, CaO, and Na2O contents, resulting in plagioclase-free parageneses, and consist of abundant K-feldspar, phlogopite, diopsidic clinopyroxene and highly forsteritic olivine. Leucite is generally absent and it is rarely found only in the groudmasses of Spanish lamproites. Mediterranean lamproites and associated rocks share an extreme enrichment in many incompatible trace elements and depletion in High Field Strength Elements and high, and positively correlated Th/La and Sm/La ratios. They have radiogenic Sr and unradiogenic Nd isotope compositions, high 207Pb over 206Pb and high time integrated 232Th/238U. Their composition requires an originally depleted lithospheric mantle source metasomatised by at least two different agents: i) a high Th/La and Sm/La (i.e., SALATHO) component deriving from lawsonite-bearing, ancient crustal domains likely hosted in mélanges formed during the diachronous collision of the northward drifting continental slivers from Gondwana; ii) a K-rich component derived from a recent subduction and recycling of siliciclastic sediments. These metasomatic melts produced a lithospheric mantle source characterised by network of felsic and phlogopite-rich veins, respectively. Geothermal readjustment during post-collisional events induced progressive melting of the different types of veins and the surrounding peridotite generating the entire compositional spectrum of the observed magmas. In this complex scenario, orogenic Mediterranean lamproites represent rocks that characterise areas that were affected by multiple Wilson cycles, as observed in the the Alpine-Himalayan realm.
