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The Sheahan Diamond Literature Reference Compilation - Technical, Media and Corporate Articles based on Major Region - Colorado
The Sheahan Diamond Literature Reference Compilation is compiled by Patricia Sheahan who publishes on a monthly basis a list of new scientific articles related to diamonds as well as media coverage and corporate announcements called the Sheahan Diamond Literature Service that is distributed as a free pdf to a list of followers. Pat has kindly agreed to allow her work to be made available as an online digital resource at Kaiser Research Online so that a broader community interested in diamonds and related geology can benefit. The references are for personal use information purposes only; when available a link is provided to an online location where the full article can be accessed or purchased directly. Reproduction of this compilation in part or in whole without permission from the Sheahan Diamond Literature Service is strictly prohibited. Return to Diamond Region Index
Sheahan Diamond Literature Reference Compilation - Scientific Articles by Author for all years
Each article reference in the SDLRC is tagged with one or more key words assigned by Pat Sheahan to highlight the main topics of the article. In addition most references have been tagged with one or more region words. In an effort to make it easier for users to track down articles related to a specific region, KRO has extracted these region words and developed a list of major region words presented in the Major Region Index to which individual region words used in the article reference have been assigned. Each individual Region Report contains in chronological order all the references with a region word associated with the Major Region word. Depending on the total for each reference type - technical, media and corporate - the references will be either in their own technical, media or corporate Region Report, or combined in a single report. Where there is a significant number of technical references there will be a technical report dedicated to the technical articles while the media and corporate references are combined in a separate region report. References that were added in the most recent monthly update are highlighted in yellow within the Region Report. The Major Region words have been defined by a scale system of "general", "continent", "country", "state or province" and "regional". Major Region words at the smaller scales have been created only when there are enough references to make isolating them worthwhile. References not tagged with a Region are excluded, and articles with a region word not matched with a Major Region show up in the "Unknown" report.
Kimberlite - diamondiferous
Lamproite - diamondiferous
Lamprophyre - diamondiferous
Other - diamondiferous
Kimberlite - non diamondiferous
Lamproite - non diamondiferous
Lamprophyre - non diamondiferous
Other - non diamondiferous
Kimberlite - unknown
Lamproite - unknown
Lamprophyre - unknown
Other - unknown
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CITATION: Faure, S, 2010, World Kimberlites CONSOREM Database (Version 3), Consortium de Recherche en Exploration Minérale CONSOREM, Université du Québec à Montréal, Numerical Database on consorem.ca. NOTE: This publicly available database results of a compilation of other public databases, scientific and governmental publications and maps, and various data from exploration companies reports or Web sites, If you notice errors, have additional kimberlite localizations that should be included in this database, or have any comments and suggestions, please contact the author specifying the ID of the kimberlite: [email protected]
The Browns Peak Formation and its Relationship to the Late Tertiary Geologic History of the Elkhead Region, Northwestern Colorado and South Central Wyoming.
Ph.d. Thesis, University California At Berkeley, 175P.
Type A- Type C Eclogite Transition in a Xenolith from the Moses Rock Diatreme Further Evidence for the Presence of Metamorphosed Ophiolites Beneath the Colorado Plateau.
International Kimberlite Conference SECOND EXTENDED ABSTRACT VOLUME.,
Garnet Clinopyroxene-chlorite Eclogite Transition in a Xenolith from Moses Rock: Further Evidence for Metamorphosed Ophiolites Under the Colorado Plateau.
International Kimberlite Conference SECOND Proceedings, Vol. 2, PP. 357-365.
Relative Abundance, Compositions and P-t Histories of Ultramafic Xenoliths, Green Knobs, New Mexico and Implications For the Mantle Below the Colorado Plateau.
Geological Society of America (GSA), Vol.7, No. 7, P. 1275.
Detrital Minerals of Mantle Origin in the Green River Basin, Wyoming.
Society for Mining, Metallurgy and Exploration (SME)-American Institute of Mining, Metallurgical, and Petroleum Engineers (AIME)., SYMPOSIUM OUTLINE FALL MEETING DENVER OCTOBER 24TH. P. 13. (
Petrology of Alkaline Rocks in the Carbonatite Complex at Iron Hill, Powderhorn District, Gunnison County, Colorado - New Geochemical and isotopic Data.
Geological Society of America (GSA), Vol. 17, No. 3, FEBRUARY P. 149. (abstract.).
Fluorine and Chlorine Contents of Phlogopites Crystallized from ultrapotassic Rock Compositions in High Pressure Experiments- Implications for halogen Reservoirs in Source Regions.
American MINERALOGIST., Vol. 70, No. 5-6, PP. 529-536.
Canada, Ontario, United States, State Line, Wyoming, Leucite Hills, Uganda
Phanerozoic igneous rocks, including kimberlites of the United States craton west of the Blue Ridge Mountains and east of the Rocky Mountains and their associated
7th. IAGOD Symposium abstract volume, Held August 18-22, Lulea Sweden, pp. 407-408. (abstract.)
Colorado, New Mexico, Wyoming, Montana, South Dakota
Hydrated pyroxenite xenoliths from Navajo diatremes, ColoradoPlateau:pressure temperature estimates and metasomatic reactions in the mantle wedge above t
Geological Society of America, Vol. 19, No. 7 annual meeting abstracts, p.835. abstrac
Origins of bimodal leucogranite-lamprophyre suites, Climax and Red Mountain porphyry molydenum systems, Colorado: petrologic and strontium isotopicevidence
Colorado School of Mines Quarterly, Vol. 83, No. 2, Summer pp. 1-24
Eclogite facies ultramafic xenoliths from Colorado plateau diatremebreccias: comparison with eclogites in crustal environments, evaluation of thesubduction
Eclogites and eclogite-facies rocks, D.C. Smith ed., Elsevier, Dev. in, Chapter 7, pp. 387-450
Seismic identification of basement reflectors: the Bagdad reflection sequence in the Basin and Range Province- Colorado Plateau transition zone, Arizona
Preliminary aeromagnetic, gravity and generalized geologic maps of the United States Geological Survey (USGS) Basin and Range-Colorado plateau transition zone study area in southwestUtah, Nevada
United States Geological Survey (USGS) Open File, No. 89-0432, 16p. 3 oversize sheets 1: 250, 000
The Cretaceous/Tertiary boundary interval, Raton Basin, Colorado and New Mexico and its content of shock metamorphosed minerals evidence relevant K/Tboundary
Geological Society of America, Paper No. 249, 104p. $ 30.00 United States
Baldridge, W.S., Perry, F.V., Vaniman, D.T., et al.
Middle to late Cenozoic magmatism of the southeastern Colorado Plateau And central Rio Grande rift ( New Mexico and Arizona): a model for continentalrifting
Tectonophysics, Vol. 197, No. 2-4, November pp. 327-354
The continental crustal age distribution: methods of determining mantle seperation ages from samarium-neodymium (Sm-Nd) isotopic dat a and application to the southwest UnitedStates
Journal of Geophysical Research, Pt. B., Vol. 96, No. B2, February 10, pp. 2071-2088
Distribution of fluorine between minerals and glass in lamproites, lamprophyres and kamafugites: implications for the role of F in deep mantle derived magmas
Proceedings of Fifth International Kimberlite Conference held Araxa June 1991, Servico Geologico do Brasil (CPRM) Special, pp. 79-81
Early to mid-Tertiary inverted metamorphic gradient under the ColoradoPlateau: evidence from eclogite xenoliths in ultramafic microbreccias, Navajo volcanic field
Journal of Geophysical Research, Vol. Paper # 91JB00284
An analytical method for hydrogeochemical surveys: inductively coupled plasma atomic emission spectrometry after using enrichment coprecipitation with cobalt and amM.
Journal of Geochemical Exploration, Vol. 41, No. 3, November pp. 349-362
Intrusion of horizontal dikes -tectonic significance of middle Proterozoic diabase sheets Wide spread in the Upper crust of the southwestern United States
Journal of Geophysical Research, Vol. 96, No. B7, July 10, pp. 12, 461-12, 478
Alkaline hybrid mafic magmas of the Yampa area, northwest Colorado, and their relationship to the Yellowstone mantle plume and lithospheric mantle domains
Contributions to Mineralogy and Petrology, Vol. 107, No. 3, pp. 310-327
Dia Met's diamond recovery pilot plant in Colorado
The Canadian Mining and Metallurgical Bulletin (CIM Bulletin) ., Session on Diamonds at The Canadian Institute of Mining, Metallurgy and Petroleum (CIM) Annual Meeting April, Vol. 84, No. 947, March p. 99. Abstract
Overt and cryptic strongly potassic mafic liquids in the Neogene magmatism of the n.part of the Rio Grande Rift, USA: a lithospheric drip feed into asthenospheric so
Proceedings of Fifth International Kimberlite Conference held Araxa June 1991, Servico Geologico do Brasil (CPRM) Special, pp. 420-422
Application of simple paramagnetic susceptibility to rapid discrimination of ilmenite compositions in exploration for kimberlite in the Colorado-WyomingProvince, United States
Proceedings of Fifth International Kimberlite Conference held Araxa June 1991, Servico Geologico do Brasil (CPRM) Special, pp. 443-445
New age determinations of central Colorado Plateau laccoliths, Utah:recognizing disturbed K-Ar systematics and re-evaluating tectonomagmaticrelationships.
Geological Society of America Bulletin, Vol. 194, No. 12, December pp. 1547-1560.
Hafnium isotope composition of late Cenozoic basaltic rocks from northwestern Colorado, United States (US): new constraints on mantle enrichment processes.
Earth and Planetary Science Letters, Vol. 119, No. 4, October pp. 495-510.
Restoration of Laramide right lateral strike slip in northern New Mexico by using Proterozoic piercing points: tectonic implications from theProterozoic...
neodymium and Strontium isotope chronostratigraphy of Colorado Plateau lithosphere: implications for magmatic and tectonic underplating of the continental crust.
Earth and Planetary Science Letters, Vol. 116, No. 1/4, April pp. 23-44.
Diamonds, kimberlites and lamproites in the Wyoming Craton, Western USA
Society for Mining, Metallurgy and Exploration (SME)/American Institute of Mining, Metallurgical, and Petroleum Engineers (AIME) PHoenix, Arizona, March 14th., p. 49. Abstract
Contrasting lower crustal evolution across an Archean Proterozoic suture: physical, chemical and geochronologic studies of lower crustal xenoliths in southern Wyoming
Geological Society of America Annual Meeting Oct. 27-30, Abstract p. 252.
Upper mantle tomographic VP and VS images of the Middle Rocky Mountains in Wyoming, Colorado and New Mexico: evidence for a thick heterogeneous chemical lithosphere
Geological Society of America Annual Meeting Oct. 27-30, Abstract p. 473.
Contrasting lower crustal evolution across an Archean Proterozoic suture: physical, chemical and geochronologic studies of lower crustal xenoliths in southern Wyoming and northern Colorado.
American Geophysical Union, Geophysical Monograph, No. 154, pp. 139-162.
Upper mantle tomographic Vp and Vs images of the Rocky Mountains in Wyoming, Colorado, New Mexico: evidence for a thick heterogeneous chemical lithosphere.
American Geophysical Union, Geophysical Monograph, No. 154, pp. 329-346.
U Pb Hf isotopic analysis of zircon in lower crustal xenoliths from the Navajo volcanic field: 1.4 Ga mafic magmatism and metamorphism beneath Colorado Plateau.
Contributions to Mineralogy and Petrology, Vol. 151, 3, pp. 313-330.
Proterozoic evolution of the western margin of the Wyoming Craton: implications for the tectonic and magmatic evolution of the northern Rocky Mountains.
Canadian Journal of Earth Sciences, Vol. 43, 10, pp. 1601-1619,
Using xenoliths to explore variations in upper mantle composition and the relation of composition to seismic velocity structure beneath the Colorado Plateau.
Geological Society of America Annual Meeting 2007, Denver Oct. 28, 1p. Abstract
Geochemistry of crustal xenoliths from the Hatcher Mesa lamproite, Wyoming, USA: insights into the composition of the deep crust and upper mantle beneath the Wyoming craton.
Zheng-Xue, A.L., Lee, C-T.A., Peslier, A.H., Lenardic, A., Mackwell, S.J.
Water contents in mantle xenoliths from the Colorado Plateau and vicinity: implications for mantle rheology and hydration induced thinning of continental lithosph.
Antigorite peridotite, metaserpentinite, and other inclusions within diatremes on the Colorado Plateau, SW USA: implications for the mantle wedge during low angle
V(S) and density structure beneath the Colorado Plateau constrained by gravity anomalies and joint inversions of receiver function and phase velocity data.
Journal of Geophysical Research, Vol. 117, B2, B02313.
Sommer, H., Regenauer-Lieb, K., Gasharova, B., Jung, H.
The formation of volcanic centers at the Colorado Plateau as a result of the passage of aqueous fluid through the oceanic lithospher and the subcontinental mantle" new implications for the planetary water cycle in the western United States.
Journal of Geodynamics, Vol. 61, Oct. pp. 154-171.
Wyoming craton mantle lithosphere: reconstructions based on xenocrysts from Sloan and Kelsey Lake kimberlites.
Proceedings of the 10th. International Kimberlite Conference, Vol. 1, Special Issue of the Journal of the Geological Society of India,, Vol. 1, pp. 13-27.
Heat flow dat a in the Four Corners area suggest Neogene crustal warming resulting from partial lithosphere replacement in the Colorado Plateau interior, southwest USA.
Geological Society of America Bulletin, Vol. 126, pp. 1084-1092.
Geochemistry, Geophysics, Geosystems: G3, Vol. 16, 2, pp. 366-379.
United States, Colorado Plateau
Convection
Abstract: Although volcanism in the southwestern United States has been studied extensively, its origin remains controversial. Various mechanisms such as mantle plumes, upwelling in response to slab sinking, and small-scale convective processes have been proposed, but have not been evaluated within the context of rapidly shearing asthenosphere that is thought to underlie this region. Using geodynamic models that include this shear, we here explore spatiotemporal patterns of mantle melting and volcanism near the Colorado Plateau. We show that the presence of viscosity heterogeneity within an environment of asthenospheric shearing can give rise to decompression melting along the margins of the Colorado Plateau. Our models indicate that eastward shear flow can advect pockets of anomalously low viscosity toward the edges of thickened lithosphere beneath the plateau, where they can induce decompression melting in two ways. First, the arrival of the pockets critically changes the effective viscosity near the plateau to trigger small-scale edge-driven convection. Second, they can excite shear-driven upwelling (SDU), in which horizontal shear flow becomes redirected upward as it is focused within the low-viscosity pocket. We find that a combination of “triggered” edge-driven convection and SDU can explain volcanism along the margins of the Colorado Plateau, its encroachment toward the plateau's southwestern edge, and the association of volcanism with slow seismic anomalies in the asthenosphere. Geographic patterns of intraplate volcanism in regions of vigorous asthenospheric shearing may thus directly mirror viscosity heterogeneity of the sublithospheric mantle.
The effects of melt depletion and metasomatism on highly siderophile and strongly chalcophile elements: S-Se-Te-Re-PGE systematics of peridotite xenoliths from Kilbourne Hole, New Mexico.
Geochimica et Cosmochimica Acta, Vol. 166, pp. 210-233.
Schulze, D.J., Davis, D.W., Helmstaedt, H., Joy, B.
Timing of the Cenozoic " Great Hydration" event beneath the Colorado Plateau: Th-Pb dating of monazite in Navajo volcanic field metamorphic eclogite xenoliths.
Geology, Vol. 43, pp. 727-730.
United States, Colorado Plateau
Diatremes - Moses Rock, Mule's Ear, Garnet Ridge, Cane Valley, Red Mesa, Buell Park, Green Knobs
Kilian, T.M., Bleeker, W., Chamberlain. K., Evans, D.A.D., Cousens, B.
Paleomagnetism, geochronology and geochemistry of the Paleoproterozoic Rabbit Creek and Powder River dyke swarms: implications for Wyoming in supercraton Superia.
Geological Society of London Special Publication Supercontinent Cycles through Earth History., Vol. 424, pp. 15-45.
Abstract: Structural, anisotropy of magnetic susceptibility (AMS), and paleomagnetic data record patterns of layer-parallel shortening (LPS), vertical-axis rotation, and regional fault-fold evolution across the Sweetwater Arch, a major west to WNW trending, basement-cored Laramide uplift in Wyoming. The southern arch flank is bounded by a WNW striking reverse fault zone that imbricated basement and cover rocks, the northern flank is bounded by a west striking fault zone with a component of strike-slip and NW trending en echelon folds, and the eastern plunge transitions into an area of multiple-trending faults and folds. Synorogenic strata record major arch uplift from Maastrichtian to Early Eocene time, followed by arch collapse. LPS, with development of systematic minor fault sets and AMS lineations, preceded large-scale folding. LPS directions, estimated from both minor fault and AMS data, were oriented WSW along the northern flank, subparallel to Laramide regional shortening, but were refracted to the SSW along the southern flank, and to the west along the eastern arch plunge. Additional minor faults developed along steep fold limbs during continued shortening, with directions remaining SSW along the southern flank but becoming more variable along the eastern plunge where an increasingly heterogeneous stress field developed as additional faults were activated along basement heterogeneities. Vertical-axis rotation was limited along the arch flanks, whereas the eastern plunge underwent counterclockwise rotation. Deflections in shortening directions were partly related to basement heterogeneities, including weak supracrustal belts on the arch flanks, a strong granitic core, and local reactivation of Precambrian shear zones.
Abstract: Rare earth mineralization in the Bear Lodge alkaline complex (BLAC) is mainly associated with an anastomosing network of carbonatite dikes and veins, and their oxidized equivalents. Bear Lodge carbonatites are LREE-dominant, with some peripheral zones enriched in HREEs. We describe the unique chemistry and mineralogy one such peripheral zone, the Cole HFSE(+HREE) Occurrence (CHO), located ~2 km from the main carbonatite intrusions. The CHO consists of anatase, xenotime-(Y), brockite, fluorite, zircon, and K-feldspar, and contains up to 44.88% TiO2, 3.12% Nb2O5, 6.52% Y2O3, 0.80% Dy2O3, 2.63% ThO2, 6.0% P2O5, and 3.73% F. Electron microprobe analyses of xenotime-(Y) overgrowths on zircon show that oscillatory zoning is a result of variable Th and Ca content. Cheralite-type substitution, whereby Th and Ca are incorporated at the expense of REEs, is predominant over the more commonly observed thorite-type substitution in xenotime-(Y). Th/Ca-rich domains are highly beam sensitive and accompanied by high-F concentrations and low-microprobe oxide totals, suggesting cheralite-type substitution is more easily accommodated in fluorinated and hydrated/hydroxylated xenotime-(Y). Analyses of xenotime-(Y) and brockite show evidence of Embedded Image substitution for Embedded Image with patches of an undefined Ca-Th-Y-Ln phosphovanadate solid-solution composition within brockite clusters. Fluorite from the CHO is HREE-enriched with an average Y/Ho ratio of 33.2, while other generations of fluorite throughout the BLAC are LREE-enriched with Y/Ho ratios of 58.6-102.5. HFSE(+HREE) mineralization occurs at the interface between alkaline silicate intrusions and the first outward occurrence of calcareous Paleozoic sedimentary rocks, which may be local sources of P, Ti, V, Zr, and Y. U-Pb zircon ages determined by LA-ICP-MS reveal two definitive 207Pb/206Pb populations at 2.60-2.75 and 1.83-1.88 Ga, consistent with derivation from adjacent sandstones and Archean granite. Therefore, Zr and Hf are concentrated by a physical process independent of the Ti/Nb-enriched fluid composition responsible for anatase crystallization. The CHO exemplifies the extreme fluid compositions possible after protracted LREE-rich crystal fractionation and subsequent fluid exsolution in carbonatite-fluid systems. We suggest that the anatase+xenotime-(Y)+brockite+fluorite assemblage precipitated from highly fractionated, low-temperature (<200 °C), F-rich fluids temporally related to carbonatite emplacement, but after significant fractionation of ancylite and Ca-REE fluorocarbonates. Low-temperature aqueous conditions are supported by the presence of fine-grained anatase as the sole Ti-oxide mineral, concentrically banded botryoidal fluorite textures, and presumed hydration of phosphate minerals. Fluid interaction with Ca-rich lithologies is known to initiate fluorite crystallization which may cause destabilization of (HREE,Ti,Nb)-fluoride complexes and precipitation of REE+Th phosphates and Nb-anatase, a model valuable to the exploration for economic concentrations of HREEs, Ti, and Nb.
Progress in Earth and Planetary Science, Vol. 3, 20, 17p.
United States, Colorado Plateau
Metasomatism
Abstract: This is the first report on amphibole exsolution in pyrope from the Colorado Plateau. Pyrope crystals delivered from mantle depths underneath the Colorado Plateau by kimberlitic volcanism at 30 Ma were collected at Garnet Ridge, northern Arizona. The garnet grains analyzed in this study occur as discrete crystals (without adjacent rock matrix) and are classified into two major groups, Cr-rich pyrope and Cr-poor pyrope. The Cr-poor pyrope group is divided into four subgroups based on exsolved phases: amphibole lamella type, ilmenite lamella type, dense lamellae type, and clinopyroxene/amphibole lamellae type. Exsolved amphibole occurs in amphibole lamella type, dense lamellae type, and clinopyroxene/amphibole lamellae type of Cr-poor pyrope. The amphibole crystals tend to have preferred orientations in their garnet hosts and occur as monomineralic hexagonal or rhombic prisms and tablets, and as multimineralic needles or blades with other exsolved phases. Exsolved amphibole has pargasitic compositions (Na2O up to 1.6 apfu based on 23 oxygen). Garnet host crystals that have undergone amphibole exsolution have low OH contents (2-42 ppmw H2O) compared to garnets that do not have amphibole lamellae (up to 115 ppmw H2O). The low OH contents of garnets hosting amphibole lamellae suggest loss of OH from garnet during amphibole exsolution. Amphibole exsolution from pyrope resulted from breakdown of a precursor “hydrous Na-garnet” composition (Mg,Na+ x)3(Al2???x, Mgx)2Si3O12???2x(OH)2x. Exsolution of amphibole and other phases probably occurred during exhumation to depths shallower than 100 km prior to volcanic eruption. Based on the abundance and composition of exsolved clinopyroxene and amphibole lamellae in one garnet, hydrous Na-garnet had excess silicon (Si3.017 apfu, 12 oxygen normalization, vs. X3Y2Si3O12 for typical garnet). Comparison with experimental data suggests crystallization at pressures near 6-8 GPa. Garnet crystals that host exsolved amphibole have compositions (Pyp49-76, 3-10 wt% CaO, and up to 0.6 wt% Cr2O3) similar to garnets reported from pyroxenites, and have pyrope-almandine-grossular compositional ranges that overlap with the Cr-rich pyrope (typical lherzolitic garnet). Hydrous Na-garnet was likely formed by metasomatic reactions between Cr-rich pyrope and Na-rich aqueous fluid in the deep upper mantle. The most likely source of metasomatic Na-rich fluid is ancient oceanic crust that was subducted before subduction of the Farallon Plate beneath the Colorado Plateau.
Abstract: 186Os/188Os variations in mantle peridotites provide constraints on the long-term Pt/Os evolution of the depleted mantle and the Pt/Os ratio of the primitive upper mantle (PUM). We report new 186Os/188Os data for mantle peridotites from continental (Rio Grande Rift and Colorado Plateau) and oceanic (Lena Trough and Hawaiian Islands) settings that span a wide range in fertility (Al2O3 ? 0.67-4.42 wt.%) and 187Os/188Os ratios (0.1138-0.1305). Although peridotite 186Os/188Os values span only a narrow range (from 0.1198345 to 0.1198384), 186Os/188Os broadly correlates with indices of melt depletion including bulk rock Al2O3, spinel Cr#, and clinopyroxene Cr#, consistent with Pt depletion in residual peridotites. PUM 186Os/188Os is estimated to be 0.1198378 ± 23 (2 SD) based on extrapolation of 186Os/188Os-fertility trends, which is very slightly lower than H-chondrites [? 0.1198398 ± 16 (2 SD); Brandon et al., 2006]. This value is consistent with a PUM Pt/Os of 1.7 ± 0.2, similar to average Pt/Os ratios of fertile continental peridotites. The inferred PUM Pt/Os is slightly lower than but within error of Pt/Os values measured in several classes of chondrites [Carbonaceous ? 1.8 ± 0.2, Ordinary ? 1.9 ± 0.1, and Enstatite ? 1.9 ± 0.1 (Brandon et al., 2006)] indicating that PUM Pt/Os is broadly chondritic. In contrast, estimates for PUM Ru/Ir and Pd/Ir (cf. Becker et al., 2006) are suprachondritic. The addition of a chondritic late veneer alone cannot create a combination of chondritic and suprachondritic HSE ratios for the PUM. Instead, minor core segregation occurring concurrently with the addition of a late veneer may explain the observed mantle HSE abundances and ratios. Combined 186Os/188Os-187Os/188Os isotopic and Pt/Os and Re/Os variability in peridotites suggest an average mantle homogenization timescale of ~ 1.2 Ga. In contrast, combined Hf-Nd isotopic and Lu/Hf and Sm/Nd variability in peridotites indicate much shorter homogenization timescales (< 0.4 Ga), potentially reflecting enhanced homogenization by melt-rock interaction to which the Pt-Os and Re-Os systems are relatively immune. The mechanical mixing timescale inferred from Os isotopes is consistent with timescales predicted for whole mantle convection.
Abstract: Paleoproterozoic suture zones mark the formation of supercontinent Nuna and provide a record of North America's assembly. Conspicuously young ages (ca. 1.715 Ga) associated with deformation in southeast Wyoming craton argue for a more protracted consolidation of Laurentia, long after peak metamorphism in the Trans-Hudson orogen. Using paleomagnetic data from the newly dated 1899 ± 5 Ma Sourdough mafic dike swarm (Wyoming craton), we compare the relative positions of Wyoming, Superior, and Slave cratons before, during, and after peak metamorphism in the Trans-Hudson orogen. With these constraints, we refine a collisional model for Laurentia that incorporates Wyoming craton after Superior and Slave cratons united, redefining the Paleoproterozoic sutures that bind southern Laurentia.
Abstract: Cratons are old and strong continental cores where the lithosphere is thick and remains largely undeformed for 2-3 b.y. Unlike typical cratons, the Wyoming craton underwent pervasive deformation ca. 80-55 Ma during the Laramide orogeny in the west-central United States, and has been subsequently encroached upon by the Yellowstone hotspot since 2.0 Ma. However, the mechanism for the deformation and the craton-hotspot interaction are not well understood. We present here a three-dimensional shear wave velocity model beneath the Wyoming craton constrained from Rayleigh wave data, which reveal new details about the cratonic lithosphere. The average lithosphere thickness beneath the craton is ?150 km, significantly thinner than a normal cratonic root (>200 km). Continuous low velocities are observed beneath the Yellowstone hotspot and the Cheyenne belt. A low-velocity column is also present in the central-eastern craton at depths of 115-250 km. These low velocities can be explained by hot temperature and partial melting, implying mantle upwelling. A high-velocity anomaly with a dripping shape in central Wyoming extends to 200-250 km depth, indicating mantle downwelling and lithosphere erosion. Our model provides the first seismic evidence for complex small-scale mantle convection beneath the Wyoming craton. The convection probably developed during the subduction of the Farallon plate and has been reinforced by the Yellowstone hotspot. We propose that the combination of flat-slab subduction, small-scale convection, and hotspot activity can lead to massive destruction of a cratonic lithosphere.
Abstract: Asthenosphere beneath the relatively thin lithosphere of the Basin and Range province appears to be juxtaposed in step-like fashion against the Colorado Plateau's thick lithospheric keel. Primary to near-primary basalts are found above this edge, in the San Francisco-Morman Mountain volcanic fields, north central Arizona, western USA. We show that at least two distinct peridotite-dominated mantle end-members contributed to the origin of the basalts. One has paired Nd and Hf isotopic characteristics that cluster near the mantle array and trace element patterns as expected for melts generated in the asthenosphere, possibly in the presence of garnet. The second has isotopic compositions displaced above the ?Hf - ?Nd mantle array which, together with its particular trace element characteristics, indicate contributions from hydrogenous sediments and/or melt (carbonatite or silicate)-related metasomatism. Melt equilibration temperatures obtained from Si- and Mg-thermobarometry are mostly 1340-1425°C and account for the effects of water (assumed to be 2 wt.%) and estimated CO2 (variable). Melt equilibration depths cluster at the inferred location of the lithosphere-asthenosphere boundary at ?70-75 km beneath the southwestern margin of the Colorado Plateau but scatter to somewhat greater values (?100 km). Melt generation may have initiated in or below the garnet-spinel facies transition zone by edge-driven convection and continued as mantle and/or melts upwelled, assimilating and sometimes equilibrating with shallower contaminated mantle, until melts were finally extracted.
Abstract: Casper College undergraduate students investigated the feasibility of finding hidden kimberlite pipes by means of geological mapping, geophysics, and stream sediment sampling. The Precambrian Laramie Mountains of southeastern Wyoming, locally known as the Iron Mountain Kimberlite district, was chosen based on previous work conducted by the Wyoming State Geological Survey (WSGS), geology of the region, and known kimberlite pipes. Data was collected using micro gravimeter - Scintrex CG-5, magnetometer - G-858 MagMapper, and electrical resistivity - SuperSting R8/IP/SP. Target one was chosen while pre-mapping the area and a topographic bowl like depression was identified. Micro gravimeter data was collected on a 56m transect at 8m intervals. Magnetometer data was collected in an area of 122m by 92m running in a 8m parallel array. Electrical resistivity was collected along a 56m transect at 8m intervals. Target two was chosen because the WSGS identified a regional magnetic anomaly and follow-up research was needed. Microgravimeter data was collected on a 56m transect at 8m intervals. Magnetometer data was collected from an area of 122m by 92m running in an 8m parallel array. Electrical resistivity was collected along a 56m transect at 8m intervals. Two drill site locations were selected based on the geophysical results to prove kimberlite is present at depth. Sediment samples were taken along Middle Sybille Creek and yielded a variety of pink to very deep red and purple colored garnets which have been sent in for EPMA (electron probe micro analyses) testing to determine the garnet-spinel compositions. Once complete the geochemical analyses will help determine if either target has a greater potential to be a diamondiferous kimberlite pipe.
Abstract: Zoned crystals of carbocernaite occur in hydrothermally reworked burbankite-fluorapatite-bearing calcite carbonatite at Bear Lodge, Wyoming. The mineral is paragenetically associated with pyrite, strontianite, barite, ancylite-(Ce), and late-stage calcite, and is interpreted to have precipitated from sulfate-bearing fluids derived from an external source and enriched in Na, Ca, Sr, Ba, and rare-earth elements (REE) through dissolution of the primary calcite and burbankite. The crystals of carbocernaite show a complex juxtaposition of core-rim, sectoral, and oscillatory zoning patterns arising from significant variations in the content of all major cations, which can be expressed by the empirical formula (Ca0.43–0.91Sr0.40–0.69REE0.18–0.59Na0.18–0.53Ba0–0.08)?1.96–2.00(CO3)2. Interelement correlations indicate that the examined crystals can be viewed as a solid solution between two hypothetical end-members, CaSr(CO3)2 and NaREE(CO3)2, with the most Na-REE-rich areas in pyramidal (morphologically speaking) growth sectors representing a probable new mineral species. Although the Bear Lodge carbocernaite is consistently enriched in light REE relative to heavy REE and Y (chondrite-normalized La/Er = 500–4200), the pyramidal sectors exhibit a greater degree of fractionation between these two groups of elements relative to their associated prismatic sectors. A sample approaching the solid-solution midline [(Ca0.57Na0.42)?0.99(Sr0.50REE0.47Ba0.01)?0.98(CO3)2] was studied by single-crystal X-ray diffraction and shown to have a monoclinic symmetry [space group P11m, a = 6.434(4), b = 7.266(5), c = 5.220(3) Å, ? = 89.979(17)°, Z = 2] as opposed to the orthorhombic symmetry (space group Pb21m) proposed in earlier studies. The symmetry reduction is due to partial cation order in sevenfold-coordinated sites occupied predominantly by Ca and Na, and in tenfold-coordinated sites hosting Sr, REE, and Ba. The ordering also causes splitting of carbonate vibrational modes at 690–740 and 1080–1100 cm?1 in Raman spectra. Using Raman micro-spectroscopy, carbocernaite can be readily distinguished from burbankite- and ancylite-group carbonates characterized by similar energy-dispersive spectra.
Abstract: Plutons associated with a 1.4 Ga magmatic event intrude across southwestern Laurentia. The tectonic setting of this major magmatic province is poorly understood. Proposed melting models include anorogenic heating from the mantle, continental arc or transpressive orogeny, and anatexis from radiogenic heat buildup in thickened crust. Re-Os analyses of refractory mantle xenoliths from the Navajo volcanic field (NVF; central Colorado Plateau) yield Re depletion ages of 2.1–1.7 Ga, consistent with the age of the overlying Yavapai and Mazatzal crust. However, new Sm-Nd isotope data from clinopyroxene in peridotite xenoliths from NVF diatremes show a subset of xenoliths that plot on a ca. 1.4 Ga isochron, which likely reflects mantle melt production and isotopic resetting at 1.4 Ga. This suggests that Paleoproterozoic subcontinental lithospheric mantle was involved in the 1.4 Ga magmatic event. Our constraints support a subduction model for the generation of the 1.4 Ga granites but are inconsistent with rifting and anorogenic anatexis models, both of which would require removal of ancient lithosphere.
Canada, Northwest Territories, Quebec, United States, Colorado
deposit, A54, Lynx, Kelsey Lake
Abstract: Eighteen diamond samples from the A154 South kimberlite pipe (Diavik Mine), Slave Craton, Northwest Territories (Canada); sixteen diamond samples from the Lynx kimberlite dyke, Superior Craton, Quebec (Canada) and twelve diamond samples from the Kelsey Lake kimberlite pipe, Wyoming Craton, Colorado (USA), were cut through the core-zones, polished, imaged by cathodoluminescence (CL), and analyzed by secondary ion mass spectrometry (SIMS) for carbon isotope composition and nitrogen abundance. Twenty Kelsey Lake diamond plates, including the twelve crystals analyzed by SIMS, were analyzed by Fourier transform infrared spectrometry (FTIR) for nitrogen concentration and aggregation state. Diamond samples from Diavik and Kelsey Lake have average ?13CPDB and nitrogen contents (atomic ppm) similar to those found by earlier studies: averaging between ? 3.9‰ and 486 ppm, and ? 7‰ and 308 ppm, respectively. Samples from the Lynx dyke, investigated for the first time, are substantially different, having ?13C = ?1.2‰ and nitrogen content = 32 ppm (averages). All three localities have examples of significant variations in nitrogen content (> 100 ppm) within single stones. Carbon isotope variation within individual stones is relatively minor (< 2‰). In terms of nitrogen aggregation, samples from the Kelsey Lake kimberlite are dominated by zones of Type IaA, but mixed-type and Type IaB (less common) stones also occur. For the majority of samples, overall intra-diamond zonations of nitrogen abundances and carbon isotope ratios are not in agreement with modeled trends for single-event Rayleigh fractionation of diamond from fluid under nitrogen-compatible conditions at 1100 °C. The involvement of fluids from subducted crustal reservoirs with exceptionally light, and in the case of Lynx samples, exceptionally heavy ?13CPDB values is necessary to explain the observed growth histories of all the samples studied here.
Geochimica et Cosmochinica Acta, Vol. 213, pp. 346-374.
United States, Colorado
volatiles
Abstract: The Colorado Plateau hosts several large accumulations of naturally occurring, non-hydrocarbon gases, including CO2, N2, and the noble gases, making it a good field location to study the fluxes of these gases within the crust and to the atmosphere. In this study, we present a compilation of 1252 published gas-composition measurements. The data reveal at least three natural gas associations in the field area, which are dominated by hydrocarbons, CO2, and N2 + He + Ar, respectively. Most gas accumulations of the region exhibit compositions that are intermediate between the three end members. The first non-hydrocarbon gas association is characterized by very high-purity CO2, in excess of 75 mol% (hereafter, %). Many of these high-purity CO2 fields have recently been well described and interpreted as magmatic in origin. The second non-hydrocarbon gas association is less well described on the Colorado Plateau. It exhibits He concentrations on the order of 1-10%, and centered log ratio biplots show that He occurs proportionally to both N2 and Ar. Overall ratios of N2 to He to Ar are ?100:10:1 and correlation in concentrations of these gases suggests that they have been sourced from the same reservoir and/or by a common process. To complement the analysis of the gas-composition data, stable isotope and noble-gas isotope measurements are compiled or newly reported from 11 representative fields (previously published data from 4 fields and new data from 7 fields). Gas sampled from the Harley Dome gas field in Utah contains nearly pure N2 + He + Ar. The various compositional and stable and noble gas isotopic data for this gas indicate that noble gas molecule/isotope ratios are near crustal radiogenic production values and also suggest a crustal N2 source. Across the field area, most of the high-purity N2 + He + Ar gas accumulations are associated with the mapped surface trace of structures or sutures in the Precambrian basement and are often accumulated in lower parts of the overlying Phanerozoic sedimentary cover. The high-purity gas association mostly occurs in areas interior to the plateau that are characterized by a narrow range of elevated, moderate heat flow values (53-74 mW/m2) in the ancient (1.8-1.6 Ga) basement terranes of the region. Collectively, the geochemical and geological data suggest that (1) the N2 + He + Ar gas association is sourced from a crustal reservoir, (2) the gas association migrates preferentially along structures in the Precambrian basement, and (3) the sourcing process relates to heating of the crust. Prospecting for noble-gas accumulations may target areas with elevated Cenozoic heat flow, ancient crust, and deep crustal structures that focus gas migration. High-purity CO2 gas may also migrate through regional basement structures, however, there is not always a clear spatial association. Rather, CO2 accumulations are more clearly associated with zones of high heat flow (>63 mW/m2) that sit above hot upper mantle and are proximal to Cenozoic volcanic rocks near the plateau margins. These observations are consistent with previous interpretations of a magmatic gas source, which were based on geochemical measurements.
Abstract: Subducting serpentinized lithosphere has distinct ?D and ?18O values compared to normal mantle. Slab-derived fluids that infiltrate the mantle wedge can alter its oxygen and hydrogen isotope composition, raising or lowering the ?18O and ?D values depending on the nature of the subducted components. Hydrous minerals in peridotite xenoliths from the Colorado Plateau (southwestern USA) have ?D values (up to ?33‰) much higher than average mantle (?80‰), but similar to ?D values of olivine-hosted melt inclusions within arc basalts, suggesting a slab-derived fluid source. Oxygen isotope ratios of olivine from these xenoliths are similar to average mantle, yet display a strong negative correlation with clinopyroxene Ce/Sm, a proxy of metasomatism. This correlation is most simply explained by metasomatism from fluids derived from the serpentinized portion of the Farallon slab. Although ?18O values of mantle minerals span a narrow range, integration of stable isotope data with other geochemical tracers can provide new constraints on modern and ancient subduction-related processes, potentially providing a method for probing Archean lithospheric mantle for evidence of early subduction.
Earth Planetary Science Letters, Vol. 492, pp. 197-205.
United States, Colorado
mantle - discontinuity
Abstract: We analyze teleseismic P-to-S conversions for high-resolution imaging of the mantle transition zone beneath the Colorado Rocky Mountains using data from a dense PASSCAL seismic broadband deployment. A total of 6,021 P-to-S converted receiver functions are constructed using a multi-channel minimum-phase deconvolution method and migrated using the common converted point technique with the 3-D teleseismic P- and S-wave tomography models of Schmandt and Humphreys (2010). The image finds that the average depths of the 410-km discontinuity (the 410) and 660-km discontinuity (the 660) at and respectively. The peak-to-peak topography of both discontinuities is 33 km and 27 km respectively. Additionally, prominent negative polarity phases are imaged both above and below the 410. To quantify the mean properties of the low-velocity layers about 410 km, we utilize double gradient layer models parameterization to fit the mean receiver function waveform. This waveform fitting is accomplished as a grid-search using anelastic synthetic seismograms. The best-fitting model reveals that the olivine-wadsleyite phase transformation width is 21 km, which is significantly larger than anhydrous mineral physics prediction (4-10 km) (Smyth and Frost, 2002). The findings of a wide olivine-wadsleyite phase transformation and the negative polarity phases above and below the 410, suggest that the mantle, at least in the 350-450 km depth range, is significantly hydrated. Furthermore, a conspicuous negative polarity phase below the 660 is imaged in high velocity region, we speculate the low velocity layer is due to dehydration flux melting in an area of convective downwelling. Our interpretation of these results, in tandem with the tomographic image of a Farallon slab segment at 800 km beneath the region (Schmandt and Humphreys, 2010), is that hydrous and upwelling mantle contributes to the high-standing Colorado Rocky Mountains.
Earth and Planetary Science Letters, Vol. 492, pp. 197-205.
United States, Colorado
geophysics - seismic
Abstract: We analyze teleseismic P-to-S conversions for high-resolution imaging of the mantle transition zone beneath the Colorado Rocky Mountains using data from a dense PASSCAL seismic broadband deployment. A total of 6,021 P-to-S converted receiver functions are constructed using a multi-channel minimum-phase deconvolution method and migrated using the common converted point technique with the 3-D teleseismic P- and S-wave tomography models of Schmandt and Humphreys (2010). The image finds that the average depths of the 410-km discontinuity (the 410) and 660-km discontinuity (the 660) at and respectively. The peak-to-peak topography of both discontinuities is 33 km and 27 km respectively. Additionally, prominent negative polarity phases are imaged both above and below the 410. To quantify the mean properties of the low-velocity layers about 410 km, we utilize double gradient layer models parameterization to fit the mean receiver function waveform. This waveform fitting is accomplished as a grid-search using anelastic synthetic seismograms. The best-fitting model reveals that the olivine-wadsleyite phase transformation width is 21 km, which is significantly larger than anhydrous mineral physics prediction (4-10 km) (Smyth and Frost, 2002). The findings of a wide olivine-wadsleyite phase transformation and the negative polarity phases above and below the 410, suggest that the mantle, at least in the 350-450 km depth range, is significantly hydrated. Furthermore, a conspicuous negative polarity phase below the 660 is imaged in high velocity region, we speculate the low velocity layer is due to dehydration flux melting in an area of convective downwelling. Our interpretation of these results, in tandem with the tomographic image of a Farallon slab segment at 800 km beneath the region (Schmandt and Humphreys, 2010), is that hydrous and upwelling mantle contributes to the high-standing Colorado Rocky Mountains.
Earth and Planetary Science Letters, Vol. 499, pp. 219-229.
United States, Colorado Plateau
metasomatism
Abstract: In magmatic settings, water behaves as an incompatible species and should be depleted during melting and enriched during metasomatism. Previous studies have identified correlations between nominally anhydrous mineral (NAM) water content ([H2O]) and indices of metasomatism or melt extraction, seemingly confirming this behavior in the mantle. However in detail, these correlations are ambiguous and do not reflect robust controls on NAM [H2O]. We measured orthopyroxene (opx) and clinopyroxene (cpx) [H2O] in variably hydrated and metasomatized peridotite xenoliths from the Navajo volcanic field (NVF) that sample the Colorado Plateau subcontinental lithospheric mantle (SCLM), an endmember of SCLM hydration and metasomatism. These xenoliths span a wide range of pyroxene [H2O] (opx from 50 to 588 ppm wt. H2O; cpx from 38 to 581 ppm wt. H2O), but NAM [H2O] does not correlate with either indices of melt depletion or metasomatism. Growth of hydrous minerals suggests higher water activity than in anhydrous peridotites, and therefore hydrous-mineral-bearing xenoliths and anhydrous xenoliths should have different NAM [H2O] and water activities. However, when the two groups are compared no significant differences can be found in either NAM [H2O] or water activity. We propose that the high diffusivity of hydrogen in the mantle allows for equilibration of water activity in the mantle over sub-kilometer length scales over geologic time. Such diffusive equilibration reduces water activity variability and results in the blurring and destruction of correlations between NAM [H2O] and indices of metasomatism or melt extraction. As a result of diffusive equilibration of water, there is a large difference in the variability of concentration between NAM [H2O] (spanning ?2 orders of magnitude) and similarly incompatible elements such as Ce in the same peridotites (spanning ?4 orders of magnitude). This difference in behavior explains why H2O/Ce ratios in mantle peridotites are highly variable relative to those of basalts.
Abstract: Airborne Visible/Infrared Imaging Spectrometer (AVIRIS) and commercially-available HyMap hyperspectral data were used to study the occurrence and mineralogical characteristics of limberlite diatremes in the State-Line district of Colorado/Wyoming. A mosaic of five flightlines of AVIRIS data acquired during 1996 with 20-m resolution is being used to locate and characterize the kimberlite diatremes. Higher spatial resolution data (1.6 m AVIRIS and 4m HyMap acquired in 1998 and 1999, respectively) are being used to map additional detail. Poor exposures, vegetation cover, and weathering, however, make identification of characteristic kimberlite minerals difficult except where exposed by mining. Minerals identified in the district using the hyperspectral data include calcite, dolomite, illite/muscovite, and serpentine (principally antigorite), however, most spectral signatures are dominated by both green and dry vegetation. The goal of this work is to determine methods for characterizing subtle mineralogic changes associated with kimberlites as a guide to exploration in a variety of geologic terrains.
Lithos, doi.org/10.101016/j. lithos.2020.105460, 55p. Pdf
United States, Colorado
subduction
Abstract: The zonation of trace elements in Cr-pyrope has been analyzed to investigate histories recorded by garnet in cool mantle and implications for processes in the mantle wedge during low-angle subduction. The garnets are from the Navajo Volcanic Field (NVF) of the Colorado Plateau in the southwestern United States. Their host rocks were emplaced between 30 and 24 Ma, not long after low-angle subduction of the Farallon plate and the Laramide orogeny. Twenty-seven of the 31 garnets are discrete fragments from diatremes of serpentinized ultramafic microbreccia (SUM). Many Ni and Mn values in those grains yield temperatures in and below the range 800 °C to 600 °C, consistent with inclusions of chlorite and other hydrous minerals. Gradients of Na, Ti, Mn, Ni, Y, REE, and other elements are common in the discrete grains. Diffusion calculations constrain possible histories of a garnet with growth zonation of Y and REE and retrograde zonation of Mn and Ni. The garnet must have formed and resided at temperatures below about 900 °C, and that zonation is unlikely to have been preserved from the Proterozoic. The Mn gradient is consistent with cooling during the time period of low-angle Farallon subduction. Many of the discrete garnets grew from sources metasomatically enriched in Li, Na, Ti, and Zr, and they have distinctive high Li/Na. The high Li/Na is a likely consequence of Li metasomatism in the mantle wedge. Nb values in the Cr-pyrope fragments from northern SUM diatremes are lower than those of most garnets from kimberlites, but the low values are similar to and lower than those of pyrope in peridotite emplaced in orogenic belts; those northern diatremes also host lawsonite eclogite and garnetite. Most but not all relatively Cr-rich discrete garnets (4 to 8 wt% Cr2O3) record enrichment in LREE but little enrichment in Ti and Zr; LREE enrichment by an aqueous fluid is consistent with chlorite inclusions in two of these garnets. Oriented lamellae of rutile and other phases are common, and one texture may record fluid interactions associated with interface-coupled dissolution-reprecipitation. Garnets from the four minette-hosted peridotites record markedly hotter temperatures than do the SUM-hosted grains, and they lack the high Li/Na and low Nb. Gradients of trace elements in minette-hosted garnets record metasomatism shortly before crustal emplacement, but that metasomatism resulted in a decrease of Nb and had little effect on Li/Na. The minette-hosted garnet peridotites may represent mantle residual from Proterozoic accretion of the Colorado Plateau. In contrast, at least some of the SUM-hosted garnets probably grew in rock eroded from the forearc wedge by low-angle subduction and emplaced below the NVF.
Proceedinds of the National Academy of Sciences, Vol. 117, 19, 9p. Pdf
United States, Colorado
geothermometry
Abstract: The Great Unconformity marks a major gap in the continental geological record, separating Precambrian basement from Phanerozoic sedimentary rocks. However, the timing, magnitude, spatial heterogeneity, and causes of the erosional event(s) and/or depositional hiatus that lead to its development are unknown. We present field relationships from the 1.07-Ga Pikes Peak batholith in Colorado that constrain the position of Cryogenian and Cambrian paleosurfaces below the Great Unconformity. Tavakaiv sandstone injectites with an age of ?676 ± 26 Ma cut Pikes Peak granite. Injection of quartzose sediment in bulbous bodies indicates near-surface conditions during emplacement. Fractured, weathered wall rock around Tavakaiv bodies and intensely altered basement fragments within unweathered injectites imply still earlier regolith development. These observations provide evidence that the granite was exhumed and resided at the surface prior to sand injection, likely before the 717-Ma Sturtian glaciation for the climate appropriate for regolith formation over an extensive region of the paleolandscape. The 510-Ma Sawatch sandstone directly overlies Tavakaiv-injected Pikes granite and drapes over core stones in Pikes regolith, consistent with limited erosion between 717 and 510 Ma. Zircon (U-Th)/He dates for basement below the Great Unconformity are 975 to 46 Ma and are consistent with exhumation by 717 Ma. Our results provide evidence that most erosion below the Great Unconformity in Colorado occurred before the first Neoproterozoic Snowball Earth and therefore cannot be a product of glacial erosion. We propose that multiple Great Unconformities developed diachronously and represent regional tectonic features rather than a synchronous global phenomenon.
Journal of Petrology, in press available, 52p. Pdf
United States, Colorado Plateau
eclogite
Abstract: The Colorado Plateau has undergone as much as 1.8?km of uplift over the past 80?Ma, but never underwent the pervasive deformation common in the neighboring tectonic provinces of the western USA. To understand the source, timing and distribution of mantle hydration, and its role in plateau uplift, garnets from four eclogite xenoliths of the Moses Rock diatreme (Navajo Volcanic Field, Utah, USA) were analyzed in situ for ?18O by secondary ion mass spectrometry. These garnets have the largest reported intra-crystalline oxygen isotope zoning to date in mantle-derived xenoliths with core-to-rim variations of as much as 3‰. All samples have core ?18O values greater than that of the pristine mantle (?5.3‰, mantle garnet as derived from mantle zircon; Valley et al., 1998; Page et al., 2007) consistent with an altered upper oceanic crust protolith. Oxygen isotope ratios decrease from core to rim recording interaction with a low-?18O fluid at high temperature, likely derived from serpentinite in the foundering Farallon slab. All zoned samples converge at a ?18O value of ?6‰, regardless of core composition, suggesting that fluid infiltration was widely distributed. Constraints on the timing of this fluid influx, relative to diatreme emplacement, can be gained from diffusion modeling of major element zoning in garnet. Modeling using best-estimates of peak metamorphic conditions (620ºC, 3.7?GPa) yield durations of?
