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The Sheahan Diamond Literature Reference Compilation - Technical Articles based on Major Region - Botswana
The Sheahan Diamond Literature Reference Compilation is compiled by Patricia Sheahan who publishes on a monthly basis a list of new scientific articles related to diamonds as well as media coverage and corporate announcements called the Sheahan Diamond Literature Service that is distributed as a free pdf to a list of followers. Pat has kindly agreed to allow her work to be made available as an online digital resource at Kaiser Research Online so that a broader community interested in diamonds and related geology can benefit. The references are for personal use information purposes only; when available a link is provided to an online location where the full article can be accessed or purchased directly. Reproduction of this compilation in part or in whole without permission from the Sheahan Diamond Literature Service is strictly prohibited. Return to Diamond Region Index
Sheahan Diamond Literature Reference Compilation - Scientific Articles by Author for all years
Each article reference in the SDLRC is tagged with one or more key words assigned by Pat Sheahan to highlight the main topics of the article. In addition most references have been tagged with one or more region words. In an effort to make it easier for users to track down articles related to a specific region, KRO has extracted these region words and developed a list of major region words presented in the Major Region Index to which individual region words used in the article reference have been assigned. Each individual Region Report contains in chronological order all the references with a region word associated with the Major Region word. Depending on the total for each reference type - technical, media and corporate - the references will be either in their own technical, media or corporate Region Report, or combined in a single report. Where there is a significant number of technical references there will be a technical report dedicated to the technical articles while the media and corporate references are combined in a separate region report. References that were added in the most recent monthly update are highlighted in yellow within the Region Report. The Major Region words have been defined by a scale system of "general", "continent", "country", "state or province" and "regional". Major Region words at the smaller scales have been created only when there are enough references to make isolating them worthwhile. References not tagged with a Region are excluded, and articles with a region word not matched with a Major Region show up in the "Unknown" report.
Kimberlite - diamondiferous
Lamproite - diamondiferous
Lamprophyre - diamondiferous
Other - diamondiferous
Kimberlite - non diamondiferous
Lamproite - non diamondiferous
Lamprophyre - non diamondiferous
Other - non diamondiferous
Kimberlite - unknown
Lamproite - unknown
Lamprophyre - unknown
Other - unknown
Future Mine
Current Mine
Former Mine
Click on icon for details about each occurrence. Works best with Google Chrome.
CITATION: Faure, S, 2010, World Kimberlites CONSOREM Database (Version 3), Consortium de Recherche en Exploration Minérale CONSOREM, Université du Québec à Montréal, Numerical Database on consorem.ca. NOTE: This publicly available database results of a compilation of other public databases, scientific and governmental publications and maps, and various data from exploration companies reports or Web sites, If you notice errors, have additional kimberlite localizations that should be included in this database, or have any comments and suggestions, please contact the author specifying the ID of the kimberlite: [email protected]
The Aeromagnetic Delineation of the Distribution Patterns Of Karroo Volcanic in Botswana and Consequent Implications For the Tectonics of the Sub Continent.
Botswana Geological Survey, Bulletin. No. 22, PP. 93-140.
Osmimum, Strontium, neodymium and lead isotope systematics of Southern african peridotite xenoliths: implications for the chemical evolution of subcontinental mantle
Geochimica et Cosmochimica Acta, Vol. 53, pp. 1583-1595
International Geological Correlation Programme (IGCP)project outline Evolution of the Kibaran belt system in southwest Africa and comparison with equatorial..
Major and trace element and Sr Nd, Hf, and Pb isotope compositions of the Karoo large igneous province, Botswana and Zimbabwe: lithosphere vs mantle plume...
Archean to Proterzooic crustal evolution in the Central Zone of the Limpopo belt ( South Africa - Botswana ): constraints from combined U Pb and Lu Hf isotope analyses of zircon.
Archean to Proterzooic crustal evolution in the Central Zone of the Limpopo belt ( South Africa - Botswana ): constraints from combined U Pb and Lu Hf isotope analyses of zircon.
Sommer, H., Regenauer Lieb, K., Hauzenberger, C., Gasharova, B.
Rapid uplift of the Jwaneng kimberlite, south Botswana: caused by mantle metasomatism and documented by OH diffusion profiles in garnet from eclogitic xenoliths.
Growth of Bultfonteinite and hydrogarnet in metasomatized basalt xenoliths in the BK9 kimberlite, Orapa, Botswana: insights and hydrothermal metamorphism in kimberlite pipes.
GAC/MAC/AGU Meeting held May 23-27 Toronto, Abstract only
Emplacement temperatures of pyroclastic and colcaniclastic deposits in kimberlite pipes in southern Africa: new constraints from paleomagnetic measurements
GAC/MAC/AGU Meeting held May 23-27 Toronto, Abstract only
Lithospheric structure, evolution and diamond prospectivity of the Rehoboth Terrane and western Kaapvaal Craton, southern Africa: constraints from broadband
Buse, B., Schumacher, J.C., Sparks, R.S.J., Field, M.
Growth of bultfontenite and hydrogarnet in metasomatized basalt xenoliths in the B/K9 kimberlite, Damtshaa: insights into hydrothermal metamorphism pipe
Contributions to Mineralogy and Petrology, Vol. 160, 4, pp. 533-550.
Crustal structure of the Zimbabwe craton and the Limpopo belt of southern Africa: new constraints from seismic dat a and implications for its evolution.
South African Journal of Geology, Vol. 112, pp. 213-228.
Honda, M., Phillips, D., Harris, J.W., Matsumoto, T.
He, Ne and Ar in peridotitic and eclogitic paragenesis diamonds from the Jwaneng kimberlite, Botswana - implications for mantle evolution and diamond formation ages.
Earth and Planetary Science Letters, Vol. 301, 1-2, pp. 43-51.
A beautiful mine ( after the horrors of the 90's, when bling was equated with blood, De Beers brings new meaning to diamond clarity. Story based on Orapa
Lithospheric structures and Precambrian terrane boundaries in northeastern Botswana revealed through magnetotelluric profiling as part of southern African
Lithospheric structures and Precambrian terrane boundaries in northeastern Botswana revealed through magnetotelluric profiling as part of Southern Africa...
Journal of Geophysical Research, Vol. 116, B02401 21p.
The origin and evolution of the lithospheric mantle beneath the Makondi fold belt in Botswana: an extensive geochemical study of peridotite xenoliths from the Lethlakane diamond mine.
10th. International Kimberlite Conference Held Bangalore India Feb. 6-11, Poster abstract
Detailed protracted crystallization history of perovskite in Orapa kimberlite.
Proceedings of the 10th. International Kimberlite Conference, Vol. 1, Special Issue of the Journal of the Geological Society of India,, Vol. 1, pp. 211-224.
Geological mapping of the Francistown area in northeastern Botswana by surface temperature and spectral emissivity information derived from advanced spaceborn thermal emission and reflection radiometer (ASTER) thermal infrared data.
Gem Diamonds the owner of the highest average dollar-per-carat kimberlite diamond mine in the world continues to defy expectations with its exceptionally large and high-value stones from Botswan and Lesotho.
The geology and emplacement of the Jwaneng DK2 kimberlite, southern Botswana, based on a petrographic study of samples selected from all parts of the kimberlite.
GSSA Kimberley Diamond Symposium and Trade Show provisional programme, Sept. 12, title only
Abstract: The peridotite xenoliths of the Letlhakane kimberlite (Botswana), which intrude the Proterozoic Magondi Belt on the western margin of the Zimbabwe craton, represent highly depleted melting residues. These residues suffered subsequent variable metasomatic overprinting, evidenced by cryptic trace element enrichments in the spinel peridotites to modal addition of phlogopite, clinopyroxene and spinel within the garnet peridotites. In order to assess the robustness of the Re–Os chronometer in such highly metasomatised peridotites, detailed investigations of base metal sulphide (BMS) petrography and single-BMS grain 187Os/188Os analyses have been undertaken in three representative peridotites.
Geophysical Research Letters, Vol. 42, 20, pp. 8398-8405.
Africa, Botswana
Geophysics - gravity
Abstract: Rifting incorporates the fundamental processes concerning the breakup of continental lithosphere and plays a significant role in the formation and evolution of sedimentary basins. In order to decipher the characteristics of rifting at its earliest stage, we conduct the first teleseismic crustal study of one of the world's youngest continental rifts, the Okavango Rift Zone (ORZ), where the magma has not yet breached the surface. Results from receiver function stacking and gravity modeling indicate that the crust/mantle boundary beneath the ORZ is uplifted by 4-5 km, and the initiation of the ORZ is closely related to lithospheric stretching. Possible decompression melting of the subcrustal lithosphere occurs beneath the ORZ, as evidenced by a relatively low upper mantle density based on the gravity modeling.
Abstract: Geosoft is pleased to announce the launch of the Botswana Geoscience Portal, a partnership initiative with the Botswana Geoscience Institute and industry sponsors. Developed and hosted by Geosoft, the portal provides free access to multi-disciplinary datasets from Ngamiland, a district in the country's northwest. It is available online at: http://geoscienceportal.geosoft.com/Botswana/search. The geoscience portal aims to help Botswana attract new investment in resource exploration, improve transparency and stimulate collaboration between government, industry and the public to advance understanding of the economic and social needs of the North-West district. Tiyapo Hudson Ngwisanyi, Chief Executive Officer of the Botswana Geoscience Institute said: “Making geoscientific data more accessible and transparent is critical to furthering understanding of the North-West district, and encouraging new investment in resource exploration within Africa. The portal is a welcome development that will assist us in promoting ongoing, productive collaboration between government and industry.” “Geosoft is excited to be part of an initiative that demonstrates how government and industry can work together to encourage mineral exploration investment and thus downstream economic growth in the country,” said Tim Dobush, Chief Executive Officer of Geosoft. “We are continually engaging with government organizations like the Botswana Geoscience Institute and industry leaders to innovate, and maximize the value of geoscience data for resource discovery and to meet the social/economic needs of the broader public sector.” Data available on the Botswana Geoscience Portal includes airborne geophysics, ground geophysics and geochemistry. Future updates will provide access to borehole data, remote sensing, seismic surveys and information products including interpretations and 3D models.- See more at: http://www.geosoft.com/news/botswana-geoscience-portal-goes-live#sthash.CZGrHC4h.dpuf
Abstract: Diamonds and their inclusions are unique probes into the deep Earth, tracking the deep carbon cycle to >800?km. Understanding the mechanisms of carbon mobilization and freezing is a prerequisite for quantifying the fluxes of carbon in the deep Earth. Here we show direct evidence for the formation of diamond by redox reactions involving FeNi sulfides. Transmission Kikuchi Diffraction identifies an arrested redox reaction from pyrrhotite to magnetite included in diamond. The magnetite corona shows coherent epitaxy with relict pyrrhotite and diamond, indicating that diamond nucleated on magnetite. Furthermore, structures inherited from h-Fe3O4 define a phase transformation at depths of 320 -330?km, the base of the Kaapvaal lithosphere. The oxidation of pyrrhotite to magnetite is an important trigger of diamond precipitation in the upper mantle, explaining the presence of these phases in diamonds.
Canadian Institute of Mining and Metallurgy, Vol. 6, 3, 14p.
Africa, Botswana
Deposit - Orapa
Abstract: The degree of uncertainty associated with a natural diamond resource is important to quantify from the time of discovery through the production lifetime. Data collection occurs during the discovery, exploration, delineation, and production or recovery phases. Quantifying the relationship between data and uncertainty is an important component of project valuation. The value of data is measured as their potential to reduce uncertainty if they are collected. A method is developed using Monte Carlo simulation for predicting resource uncertainty and valuing data during critical phases of development, particularly discovery and exploration. The technique is applied to diamond pipe deposits.
The 4th Colloquium on Diamonds - source to use held Gabarone March 1-3, 2010, 8p.
Africa, Botswana
Deposit - AK6
Abstract: The AK6 kimberlite is situated 25 km south of the Debswana Orapa Mine in Botswana and was discovered by De Beers geologists in 1969 during the follow-up of geophysical targets in the Orapa area. The kimberlite was not extensively pursued at the time as the initial bulk sampling indicated it to be of limited size and low grade, factors largely contributed to by the basalt breccia capping. Completion of high resolution integrated geophysical techniques and drill bulk sampling to depth recovered 97 tons of kimberlite during 2003 and 2004, which led to the increased size and grade estimates. Bulk sampling by Large Diameter Drilling (LDD, 23 inch diameter) commenced in 2005; 13 holes were drilled to a cumulative depth of 3,699 m and 689 carats of diamonds were recovered. In July 2006 the De Beers Mineral Resource Classification Committee classified these Phase I LOO results at a High Inferred level with an average grade of 24 carats per hundred tonnes (cpht) at a bottom cut-off of +1 mm, and a modeled average diamond value of 150 dollars per carat. A second phase of LDO drilling was initiated in 2006, and bulk sampling by trenching commenced in 2007 in order to deliver a resource estimate at indicated level. An Indicated Resource of 11.1 million carats at an average grade of 22 cpht was declared for the deposit mining lease application lodged in 2007.
The 4th Colloquium on Diamonds - source to use held Gabarone March 1-3, 2010, 28p.
Africa, Botswana
Deposit - Orapa
Abstract: Commencing with the Pre-Feasibility Study (PFS) conclusions, the Orapa 3 process design evolved through a phase of value-engineering studies. An overall re-evaluation of the originally proposed process design was necessary both in order to address the interim increase in target throughput from 9.8 Mtpa to 12 Mtpa as well as to increase capital efficiency. In the interests of clarity, the PFS process design for Orapa 3 has been omitted from this paper, as it is no longer relevant. Recognition is however due to those engaged in earlier phases of the Orapa 3 project with respect to fundamental mass~balancing modelling; and ore and diamond characterisation, which fanned the basis for the process design that has evolved from feasibility study activities. The background context for Orapa 3 is of an operation expected to yield operating utilisation and revenue improvements relative to the Orapa 2 operation. Delivering these without undue penalties to capital and operating cost required a shift in thinking, trading excess installed capacity for flexible circuit configuration. The process design adopted is "layered", with the purpose of preserving Run Of Mine (ROM) throughput by reducing in-circuit arisings - particularly to the Dense Medium Separation (DMS) section - rather than simply installing additional DMS capacity on the expectation of low DMS availability. Elsewhere, the ability to monitor and maintain critical sizing activities - particularly desanding - without impact on overall plant throughput is intended to motivate operators to avoid the temptation to trade quality for quantity. At present, since an overall dynamic simulation of the Orapa 3 operation has still to be carried out, the design mass balance has been based on a relatively onerous combination of worst case feed type with 100% front-line process capacity in all plant sections. This means that, whilst the installed DMS capacity is based on routing 100% of sized scrubbing section product directly to the DMS, and with one DMS module always unavailable, the High Pressure Rolls Crushing (HPRC) capacity is based on allowing for 50% of this stream to be instead routed first to the HPRC section, at no more than 75% of maximum roll speed for the two units installed. This is an obvious "belt and braces" approach. Following the dynamic simulation exercise (currently in progress), it is likely that a less conservative approach will be taken. This will not affect the conceptual design of the process plant, being mostly an exercise in refining the number of DMS modules to be installed, and possibly reducing slightly the size of the HPRC roll units. Both of these will have positive capital and operating cost impacts. Page 215 The Southern African Institute of Mining and Metallurgy Diamonds - Source to Use 2010 G Popp/ewell andB Hae/else DMS capacity, despite being split into coarse and fiaes streams, consists of identical modules. Two of the nine modules are set-up to receive either coarse or fine feed, the only difference being that fines modules are rated at lower capacity than the same modules treating coarse feed. Final recovery section capacity is based on entirely wet primary diamond recovery technology. This greatly reduces both the cost of drying. a large amount of recovery section feed and the dust• management issues associated with dry recovery technology. In contrast to the Orapa 2 operations, a scavenginglauditgrease belt section is included as a diamond recovery "goal-keeper" and to provide a process assurance function.
The 4th Colloquium on Diamonds - source to use held Gabarone March 1-3, 2010, 10p.
Africa, Botswana
Deposit - Jwaneng
Abstract: Debswana's Jwaneng Mine (south-central Botswana) is the richest diamond mine• in the world and has been contributing substantial revenue to Botswana since the mine started operating in 1982. The resource consists of 3 separate volcanic pipes/vents namely North, South and Centre pipes (2 additional small kimberlite bodies have also been intersected within the mining pit) which erupted through Transvaal strata and the overlying Karoo sediments - 245 million years ago. Although earlier drilling and geophysical surveys suggest that the 3 pipes extend to depths greater than 1 km below the surface, the resource is only at an indicated level of confidence to a depth of 400m, and mining activities will start exploiting the inferred resource material below 400m in 2014.
The 4th Colloquium on Diamonds - source to use held Gabarone March 1-3, 2010, 18p.
Africa, Botswana
Deposit - Jwaneng
Abstract: Slope stability is a fundamental part of a successful mining operation. It impacts directly on the safety of personnel and the economics of the mine. The Jwaneng Mine in Botswana is planning a push back of 644m depth in the south east wall. Mining will commence in 2010 and be completed in 2024. This will put the mine in the deep pit category. The mine has invested in extensive geotechnical data gathering and design programs that started as far back as 2003 for the south east wall. The south east wail of Jwaneng Mine is characterized by foliation that dips adversely into the mining faces. The orienta1ion of the foliation is variable due to intense tectonic movements that have also caused the occurrence of faults that are sub-vertical. A considerable amount of information on the characteristics of structural patterns and the rock mass has been collected. This paper presents an overview of the feasibility level geotechnical design that is about to be concluded.
Abstract: A regional-scale geophysical inversion of magnetic field data in the Ngamiland region of northwestern Botswana is now available for download from the Botswana Geoscience Portal, a partnership initiative of the Botswana Geoscience Institute (BGI), industry sponsors and Geosoft. The earth modelling results represent Botswana’s latest push to provide geoscience data free of charge to mineral explorers, researchers and other stakeholders from around the world. They were generated by the Geosoft Professional Services Group using VOXI Earth Modelling, the company’s high performance inversion software. "The VOXI inversion results are outstanding, even more so because the area of interest is vast, comprising more than 35 million cells," said Motsamai Tarzan Kwadiba, Principal Geophysicist for the BGI. "The outcome provides a springboard for a variety of research opportunities such as seismotectonic studies for seismic hazard assessment and earthquake risk mitigation, area selection for earth resources exploration and management, and investigations of the anatomy and evolution of the Okavango rift zone." Since its launch in April 2016, over 1000 multi-disciplinary datasets have been downloaded from the Botswana Geoscience Portal. Stakeholders from more than 35 countries have visited the repository to access the 10 gigabytes of pre-competitive geoscience data. The new inversion results add clear 3D images of the shallow crust beneath the Okavango delta region, one of the world’s largest inland deltas. Often referred to as the ‘jewel’ of the Kalahari and Africa's last Eden, the 22000 square-kilometer Okavango delta itself is an alluvial fan contained within a seismically active graben structure at the south-western extremity of the East African Rift system.
Earth and Planetary Science Letters, Vol. 463, pp. 178-188.
Africa, Botswana
Deposit - Lethakane
Abstract: Monocrystalline diamonds commonly record complex internal structures reflecting episodic growth linked to changing carbon-bearing fluids in the mantle. Using diamonds to trace the evolution of the deep carbon cycle therefore requires dating of individual diamond growth zones. To this end Rb-Sr and Sm-Nd isotope data are presented from individual eclogitic silicate inclusions from the Orapa and Letlhakane diamond mines, Botswana. ?13C?13C values are reported from the host diamond growth zones. Heterogeneous 87Sr/86Sr ratios (0.7033-0.7097) suggest inclusion formation in multiple and distinct tectono-magmatic environments. Sm-Nd isochron ages were determined based on groups of inclusions with similar trace element chemistry, Sr isotope ratios, and nitrogen aggregation of the host diamond growth zone. Diamond growth events at 0.14±0.090.14±0.09, 0.25±0.040.25±0.04, 1.1±0.091.1±0.09, 1.70±0.341.70±0.34 and 2.33±0.022.33±0.02 Ga can be directly related to regional tectono-magmatic events. Individual diamonds record episodic growth with age differences of up to 2 Ga. Dated diamond zones have variable ?13C?13C values (?5.0 to ?33.6‰ vs PDB) and appear to imply changes in subducted material over time. The studied Botswanan diamonds are interpreted to have formed in different tectono-magmatic environments that involve mixing of carbon from three sources that represent: i) subducted biogenic sediments (lightest ?13C?13C, low 87Sr/86Sr); ii) subducted carbonate-rich sediments (heavy ?13C?13C, high 87Sr/86Sr) and iii) depleted upper mantle (heavy ?13C?13C, low 87Sr/86Sr). We infer that older diamonds from these two localities are more likely to have light ?13C?13C due to greater subduction of biogenic sediments that may be related to hotter and more reduced conditions in the Archaean before the Great Oxidation Event at 2.3 Ga. These findings imply a marked temporal change in the nature of subducted carbon beneath Botswana and warrant further study to establish if this is a global phenomenon.
European Geosciences Union General Assembly 2017, Vienna April 23-28, 1p. 5540 Abstract
Africa, Botswana
Deposit - Letlhakane
Abstract: The diamondiferous Letlhakane kimberlites are part of the Orapa kimberlite cluster (˜ 93.1 Ma) in north-eastern Botswana, located on the edge of the Zimbabwe Craton, close to the Proterozoic Magondi Mobile Belt. Here we report the first Re-Os ages of six individual eclogitic sulphide inclusions (3.0 to 35.7?g) from Letlhakane diamonds along with their rhenium, osmium, iridium and platinum concentrations, and carbon isotope, nitrogen content and N-aggregation data from the corresponding growth zones of the host diamonds. For the first time, Re-Os data will be compared to Sm-Nd ages of individual eclogitic silicate inclusions recovered from the same diamonds using a Triton Plus equipped with four 1013? amplifiers. The analysed inclusion set currently encompasses pairs of individual sulphides from two diamonds (LK040 sf4 & 5, LK113 sf1 & 2) and two sulphide inclusions from separate diamonds (LK048, LK362). Ongoing work will determine the Sm-Nd ages and element composition of multiple individual eclogitic garnets (LK113/LK362, n=4) and an eclogitic clinopyroxene (LK040) inclusion. TMA ages of the six sulphides range from 1.06 to 2.38 Ga (± 0.1 to 0.54 Ga) with Re and Os contents between 7 and 68 ppb and 0.03 and 0.3 ppb, respectively. The host diamond growth zones have low nitrogen abundances (21 to 43 ppm N) and high N-aggregation (53 to 90% IaB). Carbon isotope data suggests the involvement of crustal carbon (?13C between -19.3 to -22.7 ± 0.2 per mill) during diamond precipitation. Cathodoluminescence imaging of central plates from LK040 and LK113 displays homogenous internal structure with no distinct zonation. The two sulphide inclusions from LK040 define an 'isochron' of 0.92 ± 0.23 Ga (2SD) with initial 187Os/188Os = 1.31 ± 0.24. Sulphides from LK113 have clear imposed diamond morphology and indicate diamond formation at 0.93 ± 0.36 Ga (2SD) with initial 187Os/188Os = 0.69 ± 0.44. The variation in the initial 187Os/188Os does not justify including these inclusions (or any from other diamonds) on the same isochron and implies an extremely heterogeneous diamond crystallisation environment that incorporated recycled Os. C1-normalized osmium, iridium and platinum (PGE) compositions from the analysed sulphide inclusions display enrichment in Ir (3.4 to 33) and Pt (2.3 to 28.1) in comparison to eclogitic xenolith data from Orapa that are depleted relative to chondrite. The Re-Os isochrons determined in this study are within error of previously reported ages from the adjacent (˜40km) Orapa diamond mine (1.0 to 2.9 Ga) based on sulphide inclusions and a multi-point 990 ± 50 Ma (2SD) isochron for composite (n=730) silicate inclusions. Together with additional new Sm-Nd isochron age determinations from individual silicate inclusions from Letlhakane (2.3 ± 0.02 (n = 3); 1.0 ± 0.14 (n = 4) and 0.25 ± 0.04 Ga (n = 3), all 2SE) these data suggest a phase of Mesoproterozoic diamond formation as well as Neoarchean/Paleoproterozoic and Mesozoic diamond growth, in punctuated events spanning >2.0 Ga.
van den Heuvel, Q., Matveev, S., Drury, M., Gress, M., Chinn, I., Davies, G.
Genesis of diamond inclusions: an integrated cathodluminescence ( CL) and electron backscatter diffraction (EBSD) study on eclogitic and peridotitic inclusions and their diamond host.
European Geosciences Union General Assembly 2017, Vienna April 23-28, 1p. 6564 Abstract
Geochimica et Cosmochimica Acta, available in press 23p.
Africa, Botswana
deposit - Orapa
Abstract: Base metal sulphide (BMS) inclusions in diamonds provide a unique insight into the chalcophile and highly siderophile element composition of the mantle. Entombed within their diamond hosts, these provide a more robust (closed system) sample, from which to determine the trace element, Re-Os and S-isotopic compositions of the mantle than mantle xenoliths or orogenic peridotites, as they are shielded from alteration during ascent to the Earth’s crust and subsequent surface weathering. However, at temperatures below 1100 °C some BMS inclusions undergo subsolidus re-equilibration from an original monosulphide solid solution (Mss) and this causes fractionation of the major and trace elements within the inclusions. Thus to study the subjects noted above, current techniques require the entire BMS inclusion to be extracted for analyses. Unfortunately, ‘flaking’ of inclusions during break-out is a frequent occurrence and hence the risk of accidentally under-sampling a portion of the BMS inclusion is inherent in current practices. This loss may have significant implications for Re-Os isotope analyses where incomplete sampling of a Re-rich phase, such as chalcopyrite that typically occurs at the outer margins of BMS inclusions, may induce significant bias in the Re-Os and 187Os/188Os measurements and resulting model and isochron ages. We have developed a method for the homogenisation of BMS inclusions in diamond prior to their break-out from the host stone. Diamonds are heated to 1100 °C and then quenched to chemically homogenise any sulphide inclusions for both major and trace elements. Using X-ray Computed Microtomography (µCT) we determine the shape and spatial setting of multiple inclusions within a host stone and crucially show that the volume of a BMS inclusion is the same both before and after homogenisation. We show that the homogenisation process significantly reduces the inherent variability of in situ analysis when compared with unhomogenised BMS, thereby widening the scope for multiple methods for quantitative analysis, even on ‘flakes’ of single BMS inclusions. Finally we show that the trace elements present in peridotite (P-type) and eclogitic (E-type) BMS are distinct, with P-type diamonds having systematically higher total platinum-group element (particularly Os, Ir, Ru) and Te and As concentrations. These distinctions suggest that the PGE and semi-metal budgets of mantle-derived partial melts will be significantly dependent upon the type(s) and proportions of sulphides present in the mantle source.
Abstract: The Karowe mine, owned and operated by Lucara Diamond Corporation, located in the Republic of Botswana, achieved commercial diamond production in July 2012. The AK06 kimberlite discovered in 1969 is the ore source at Karowe. The AK06 kimberlite within the Orapa Kimberlite Field is a roughly north-south elongate kimberlite body with a near surface expression of approximately 3.3 ha and a maximum area of approximately 7 ha at approximately 120 m below surface. The body comprises three geologically distinct, coalescing pipes that taper with depth. These pipes are referred to as the North Lobe, Centre Lobe, and South Lobe. The AK6 kimberlite is an opaque-mineral-rich monticellite kimberlite, texturally classified primarily as fragmental volcaniclastic kimberlite with lesser macrocrystic hypabyssal facies kimberlite of the Group 1 variety. The nature of the kimberlite differs between each lobe with distinctions apparent in the textural characteristics. The South Lobe is considered to be distinctly different from the North and Centre Lobes that are similar to each other in terms of their geological characteristics. The North and Centre Lobes exhibit internal textural complexity whereas the bulk of the South Lobe is more massive and internally homogeneous. The South Lobe forms the majority of the resource and displays the coarsest diamond size distribution of the three lobes. In three years of production, Karowe has established a continuing production of high value diamonds including coloured diamonds. In March 2013 a 239 ct gem quality diamond was recovered which was the first in a continuing population of large high value Type IIa diamonds recovered from the Centre Lobe, and more importantly the South Lobe, of the Karowe mine. Large diamonds, 50 ct in size, are spatially distributed horizontally and vertically within the South Lobe. Since commissioning to mid-December 2015, approximately 1.5 Mct have been produced and specials (diamonds greater than 10.8 ct in weight) represent circa 4.6% by weight of all diamond production. Life of Mine average stone size for the specials is 29.6 ct/stone. In 2015, a plant optimization project was completed to modify the process plant to treat harder kimberlite at depth and improve the recovery of exceptional diamonds via bulk sorters for primary run of mine large diamond recovery. In November 2015, the Karowe mine recovered an 813 ct stone and the world’s second largest gem quality diamond in over 100 years weighing 1,111 ct
Slope stability challenges and solutions for mining kimberlite resources hosted in structurally complex country rock: dip slope mining at Jwaneng mine, Botswana.
Abstract: The diamondiferous Letlhakane kimberlites are part of the Orapa kimberlite cluster (˜ 93.1 Ma) in north-eastern Botswana, located on the edge of the Zimbabwe Craton, close to the Proterozoic Magondi Mobile Belt. Here we report the first Re-Os ages of six individual eclogitic sulphide inclusions (3.0 to 35.7?g) from Letlhakane diamonds along with their rhenium, osmium, iridium and platinum concentrations, and carbon isotope, nitrogen content and N-aggregation data from the corresponding growth zones of the host diamonds. For the first time, Re-Os data will be compared to Sm-Nd ages of individual eclogitic silicate inclusions recovered from the same diamonds using a Triton Plus equipped with four 1013? amplifiers. The analysed inclusion set currently encompasses pairs of individual sulphides from two diamonds (LK040 sf4 & 5, LK113 sf1 & 2) and two sulphide inclusions from separate diamonds (LK048, LK362). Ongoing work will determine the Sm-Nd ages and element composition of multiple individual eclogitic garnets (LK113/LK362, n=4) and an eclogitic clinopyroxene (LK040) inclusion. TMA ages of the six sulphides range from 1.06 to 2.38 Ga (± 0.1 to 0.54 Ga) with Re and Os contents between 7 and 68 ppb and 0.03 and 0.3 ppb, respectively. The host diamond growth zones have low nitrogen abundances (21 to 43 ppm N) and high N-aggregation (53 to 90% IaB). Carbon isotope data suggests the involvement of crustal carbon (?13C between -19.3 to -22.7 ± 0.2 per mill) during diamond precipitation. Cathodoluminescence imaging of central plates from LK040 and LK113 displays homogenous internal structure with no distinct zonation. The two sulphide inclusions from LK040 define an 'isochron' of 0.92 ± 0.23 Ga (2SD) with initial 187Os/188Os = 1.31 ± 0.24. Sulphides from LK113 have clear imposed diamond morphology and indicate diamond formation at 0.93 ± 0.36 Ga (2SD) with initial 187Os/188Os = 0.69 ± 0.44. The variation in the initial 187Os/188Os does not justify including these inclusions (or any from other diamonds) on the same isochron and implies an extremely heterogeneous diamond crystallisation environment that incorporated recycled Os. C1-normalized osmium, iridium and platinum (PGE) compositions from the analysed sulphide inclusions display enrichment in Ir (3.4 to 33) and Pt (2.3 to 28.1) in comparison to eclogitic xenolith data from Orapa that are depleted relative to chondrite. The Re-Os isochrons determined in this study are within error of previously reported ages from the adjacent (˜40km) Orapa diamond mine (1.0 to 2.9 Ga) based on sulphide inclusions and a multi-point 990 ± 50 Ma (2SD) isochron for composite (n=730) silicate inclusions. Together with additional new Sm-Nd isochron age determinations from individual silicate inclusions from Letlhakane (2.3 ± 0.02 (n = 3); 1.0 ± 0.14 (n = 4) and 0.25 ± 0.04 Ga (n = 3), all 2SE) these data suggest a phase of Mesoproterozoic diamond formation as well as Neoarchean/Paleoproterozoic and Mesozoic diamond growth, in punctuated events spanning >2.0 Ga.
Mineral inclusions in diamonds from Karowe mine, Botswana: examining the mantle sources of a diamond population containing exceptionally large crystals.
Geochimica et Cosmochimica Acta, Vol. 213, pp. 574-592.
Africa, Botswana
deposit - Orapa
Abstract: Major- and trace-element compositions of garnet and clinopyroxene, as well as 87Sr/86Sr in clinopyroxene and ?18O in garnet in eclogite and pyroxenite xenoliths from Orapa, at the western margin of the Zimbabwe craton (central Botswana), were investigated in order to trace their origin and evolution in the mantle lithosphere. Two groups of eclogites are distinguished with respect to 87Sr/86Sr: One with moderate ratios (0.7026-0.7046) and another with 87Sr/86Sr >0.7048 to 0.7091. In the former group, heavy ?18O attests to low-temperature alteration on the ocean floor, while 87Sr/86Sr correlates with indices of low-pressure igneous processes (Eu/Eu?, Mg#, Sr/Y). This suggests relatively undisturbed long-term ingrowth of 87Sr at near-igneous Rb/Sr after metamorphism, despite the exposed craton margin setting. The high-87Sr/86Sr group has mainly mantle-like ?18O and is suggested to have interacted with a small-volume melt derived from an aged phlogopite-rich metasome. The overlap of diamondiferous and graphite-bearing eclogites and pyroxenites over a pressure interval of ?3.2 to 4.9 GPa is interpreted as reflecting a mantle parcel beneath Orapa that has moved out of the diamond stability field, due to a change in geotherm and/or decompression. Diamondiferous eclogites record lower median 87Sr/86Sr (0.7039) than graphite-bearing samples (0.7064) and carbon-free samples (0.7051), suggesting that interaction with the - possibly oxidising - metasome-derived melt caused carbon removal in some eclogites, while catalysing the conversion of diamond to graphite in others. This highlights the role of small-volume melts in modulating the lithospheric carbon cycle. Compared to diamondiferous eclogites, eclogitic inclusions in diamonds are restricted to high FeO and low SiO2, CaO and Na2O contents, they record higher equilibrium temperatures and garnets have mostly mantle-like O isotopic composition. We suggest that this signature was imparted by a sublithospheric melt with contributions from a clinopyroxene-rich source, possibly related to the ca. 2.0 Ga Bushveld event.
South African Institute of Mining and Metallurgy, Vol. 116, 8, pp. 709-714.
Africa, Botswana
deposit - Karowe
Abstract: Historically, the recovery of large diamonds in conventional treatment plant flow sheets has been associated with dense media separation (DMS). This is attributed mainly to DMS's highly efficient and proven track record in the concentration and separation of ores with variable solids densities. In most instances, DMS has been utilized as a pre-concentration step ahead of any recovery plant, due to its ability and versatility in reducing feed within a specific size range to manageable volumes for downstream X-ray processing and subsequent diamond recovery. The benefit of using carbon-signature-based detection equipment for retrieving large stones upfront in the flow sheet not only equates to earlier recovery of diamonds from the system, but also lessens the exposure of diamond-bearing ore to additional materials handling, pumping, and/or crushing, which has been known to damage or even break diamonds and decrease revenue.
Geochimica et Cosmochinica Acta, Vol. 213, pp. 574-592.
Africa, Botswana
deposit - Orapa
Abstract: Major- and trace-element compositions of garnet and clinopyroxene, as well as 87Sr/86Sr in clinopyroxene and ?18O in garnet in eclogite and pyroxenite xenoliths from Orapa, at the western margin of the Zimbabwe craton (central Botswana), were investigated in order to trace their origin and evolution in the mantle lithosphere. Two groups of eclogites are distinguished with respect to 87Sr/86Sr: One with moderate ratios (0.7026-0.7046) and another with 87Sr/86Sr >0.7048 to 0.7091. In the former group, heavy ?18O attests to low-temperature alteration on the ocean floor, while 87Sr/86Sr correlates with indices of low-pressure igneous processes (Eu/Eu?, Mg#, Sr/Y). This suggests relatively undisturbed long-term ingrowth of 87Sr at near-igneous Rb/Sr after metamorphism, despite the exposed craton margin setting. The high-87Sr/86Sr group has mainly mantle-like ?18O and is suggested to have interacted with a small-volume melt derived from an aged phlogopite-rich metasome. The overlap of diamondiferous and graphite-bearing eclogites and pyroxenites over a pressure interval of ?3.2 to 4.9 GPa is interpreted as reflecting a mantle parcel beneath Orapa that has moved out of the diamond stability field, due to a change in geotherm and/or decompression. Diamondiferous eclogites record lower median 87Sr/86Sr (0.7039) than graphite-bearing samples (0.7064) and carbon-free samples (0.7051), suggesting that interaction with the - possibly oxidising - metasome-derived melt caused carbon removal in some eclogites, while catalysing the conversion of diamond to graphite in others. This highlights the role of small-volume melts in modulating the lithospheric carbon cycle. Compared to diamondiferous eclogites, eclogitic inclusions in diamonds are restricted to high FeO and low SiO2, CaO and Na2O contents, they record higher equilibrium temperatures and garnets have mostly mantle-like O isotopic composition. We suggest that this signature was imparted by a sublithospheric melt with contributions from a clinopyroxene-rich source, possibly related to the ca. 2.0 Ga Bushveld event.
Abstract: Kimberlite magmas, the primary source of diamonds, have many features indicative of explosive eruptions and high volatile contents. The main approaches used to establish exsolution of fluid during magma ascent include theoretical modeling and experimental estimates of volatile solubility in kimberlite-like melts. Both approaches are hampered by the poorly constrained composition of kimberlite melts. Resorption features on diamonds are very sensitive to the presence and composition of the kimberlite fluid as well as to temperature and pressure. Here, we use direct evidence from diamond resorption features as a new method for investigating the parameters of fluid exsolution. The method is based on experimental reproduction of diamond resorption in kimberlite melts with and without an exsolved fluid phase. We studied 802 diamonds from two kimberlites (BK1 and AK15) from the Orapa cluster, Botswana. Samples from the BK1 pipe include three lithologies: two coherent kimberlites (CK-A and CK-B) and a pyroclastic kimberlite (massive volcaniclastic kimberlite, MVK). The known depth of diamond samples in each kimberlite lithology allows us to demonstrate an increase in the intensity of kimberlite-induced resorption with depth of diamond recovery in the drill holes. Each kimberlite lithology has a different proportion of diamonds with kimberlite-induced resorption, which is unique in style in each lithology: glossy surfaces in MVK due to reaction with C-O-H fluid, rough corroded surfaces in CK-B due to reaction with volatile-undersaturated melt, and a combination of glossy surfaces with corroded features in CK-A due to an overprint of melt resorption after fluid resorption. Both diamond resorption and kimberlite textures in the BK1 kimberlite show evidence of fluid exsolution only in CK-A and MVK lithologies, but no fluid presence in CK-B. The observed diamond resorption features may be controlled by (1) a temporary separation of the rising magma column into a bubble-rich head and bubble-poor volatile-depleted tail and (2) fluid exsolution at depths greater than decompressional degassing. We discuss how the depth of fluid exsolution from kimberlite melt may affect the diamond grade and the resorption of diamond populations in a kimberlite.
Journal of African Earth Sciences, Vol. 137, pp. 9-21.
Africa, Botswana
deposit - Jwaneng
Abstract: Country rock at Jwaneng Diamond Mine provides a rare insight into the deformational history of the Transvaal Supergroup in southern Botswana. The ca. 235 Ma kimberlite diatremes intruded into late Archaean to Early Proterozoic, mixed, siliciclastic-carbonate sediments, that were subjected to at least three deformational events. The first deformational event (D1), caused by NW-SE directed compression, is responsible for NE-trending, open folds (F1) with associated diverging, fanning, axial planar cleavage. The second deformational event (D2) is probably progressive, involving a clockwise rotation of the principal stress to NE-SW trends. Early D2, which was N-S directed, involved left-lateral, oblique shearing along cleavage planes that developed around F1 folds, along with the development of antithetic structures. Progressive clockwise rotation of far-field forces saw the development of NW-trending folds (F2) and its associated, weak, axial planar cleavage. D3 is an extensional event in which normal faulting, along pre-existing cleavage planes, created a series of rhomboid-shaped, fault-bounded blocks. Normal faults, which bound these blocks, are the dominant structures at Jwaneng Mine. Combined with block rotation and NW-dipping bedding, a horst-like structure on the northwestern limb of a broad, gentle, NE-trending anticline is indicated. The early compressional and subsequent extensional events are consistent throughout the Jwaneng-Ramotswa-Lobatse-Thabazimbi area, suggesting that a large area records the same fault geometry and, consequently, deformational history. It is proposed that Jwaneng Mine is at or near the northernmost limit of the initial, northwards-directed compressional event.
Mineralogy and Petrology, in press available, 16p.
Africa, Botswana
diamond exploration
Abstract: Bechuanaland/Botswana has a long and colourful history in exploration and mining. Here these activities are subdivided into three phases: pre-historic, historic and modern. Quarrying stone in Botswana was ongoing 500,000 years ago during the Early Stone Age (ESA). Actual mining of stones probably only started during the Middle Stone Age (MSA) i.e. post 250,000 BP, and the first prehistoric hard rock mining of specularite and limonite, likely started during the Late Stone Age (LSA) 20,000 to 2,000 BP. In east Botswana iron and copper were mined from AD 800 onwards; the mining of gold started in the thirteenth century. Historic mining started with the re-discovery of gold close to Francistown in 1865 and lasted until the 1950s. Rumours of diamonds in Bechuanaland had already surfaced in the 1880s, and it was Ngamiland, in the northwest, that was first explored systematically for diamonds and gold between 1896 and 1899. A joint initiative between Anglo American and De Beers started serious prospecting parts of eastern Bechuanaland between 1932 and 1938; and in 1938 the first diamond finds in Bechuanaland were reported. Modern mining and exploration started with the signing of an agreement in 1959, allowing Consolidated African Selection Trust Ltd. (CAST) into the Bamangwato Tribal Reserve. CAST found a few diamonds in the Motloutse River, but concluded that these were reworked and dropped the exploration rights. De Beers believed that these diamonds had come from west of the Motloutse headwaters, across the watershed in the Kalahari. This ultimately led to the discovery of the Orapa kimberlite field in 1967, a year after Botswana became independent. This discovery triggered a major exploration boom across Botswana adding important diamond-bearing kimberlites such as at Letlhakane (1968), Jwaneng (1973), Gope (1981) and Lerala (1991).
Contrasting termite transported indicator mineral concentrations in the Kgalafadi of central district Botswana: Macrotermes micaelseni vs Hodotermes mossambicus.
Vancouver Kimberlite Cluster, March 9, 1p. Abstract
Mineralogy and Petrology, in press available, 11p.
Africa, Botswana
deposit - Orapa
Abstract: Spatially resolved analyses reveal considerable isotopic heterogeneity within and among diamonds ranging in size from 0.15 to 4.75 mm from the Orapa Mine, Botswana. The isotopic data are interpreted in conjunction with nitrogen aggregation state data and growth zone relationships from cathodoluminescence images. The integrated information confirms that a distinct diamond growth event (with low IaAB nitrogen aggregation states, moderately high nitrogen contents and ?13C and ?15N values compatible with average mantle values) is younger than the dominant population(s) of Type IaAB diamonds and cores of composite diamonds with more negative and positive ?13C and ?15N values, respectively. A significant proportion of the older diamond generation has high nitrogen contents, well outside the limit sector relationship, and these diamonds are likely to reflect derivation from subducted organic matter. Diamonds with low ?13C values combined with high nitrogen contents and positive ?15N values have not been previously widely recognised, even in studies of diamonds from Orapa. This may have been caused by prior analytical bias towards inclusion-bearing diamonds that are not necessarily representative of the entire range of diamond populations, and because of average measurements from heterogeneous diamonds measured by bulk combustion methods. Two distinct low nitrogen/Type II microdiamond populations were recognised that do not appear to continue into the macrodiamond sizes in the samples studied. Other populations, e.g. those containing residual singly-substituted nitrogen defects, range in size from small microdiamonds to large macrodiamonds. The total diamond content of the Orapa kimberlite thus reflects a complex assortment of multiple diamond populations.
Mineralogy and Petrology, June 14, DOI:10.1007/ s00710-018- 0593-8, 14p.
Africa, Botswana
deposit - Nxau
Abstract: The Nxau Nxau kimberlites in northwest Botswana belong to the Xaudum kimberlite province that also includes the Sikereti, Kaudom and Gura kimberlite clusters in north-east Namibia. The Nxau Nxau kimberlites lie on the southernmost extension of the Congo Craton, which incorporates part of the Damara Orogenic Belt on its margin. The Xaudum kimberlite province is geographically isolated from other known clusters but occurs within the limits of the NW-SE oriented, Karoo-aged Okavango Dyke Swarm and near NE-SW faults interpreted as the early stages of the East African Rift System. Petrographic, geochronological and isotopic studies were undertaken to characterise the nature of these kimberlites and the timing of their emplacement. The Nxau Nxau kimberlites exhibit groundmass textures, mineral phases and Sr-isotope compositions (87Sr/86Sri of 0.7036?±?0.0002; 2?) that are characteristic of archetypal (Group I) kimberlites. U-Pb perovskite, 40Ar/39Ar phlogopite and Rb-Sr phlogopite ages indicate that the kimberlites were emplaced in the Cretaceous, with perovskite from four samples yielding a preferred weighted average U-Pb age of 84?±?4 Ma (2?). This age is typical of many kimberlites in southern Africa, indicating that the Xaudum occurrences form part of this widespread Late Cretaceous kimberlite magmatic province. This time marks a significant period of tectonic stress reorganisation that could have provided the trigger for kimberlite magmatism. In this regard, the Nxau Nxau kimberlites may form part of a NE-SW oriented trend such as the Lucapa corridor, with implications for further undiscovered kimberlites along this corridor.
Abstract: The diamondiferous Jwaneng kimberlite cluster (~240 Ma) is located on the NW rim of the Archaean Kaapvaal Craton in central Botswana. Previous studies report eclogitic diamond formation in the late Archean (2.9 Ga) and in the Middle Proterozoic (1.5 Ga) involving different mantle and sedimentary components [1;2;3]. Here we report newly acquired Sm- Nd ages of individual eclogitic pyrope-almandine and omphacite inclusions along with their major element data and nitrogen data from the diamond hosts to re-examine Jwaneng’s diamond formation ages. The Sm-Nd isotope analyses were performed via TIMS using 1013? resistors [4]. An initial suite of three pyropealmandine and 14 omphacite inclusions yield 143Nd/144Nd from 0.51102±7 to 0.5155±5. 147Sm/144Nd vary from 0.024 to 0.469. Major element data defines two inclusion populations: (1) seven omphacites with high Mg#, high Cr# and one pyropealmandine with low-Ca define an isochron age of 1.93±0.16 Ga with ?Ndi= +3.5; (2) seven omphacites with low Mg#, low Cr# and two pyrope-almandines with low-Ca define an isochron age of 0.82±0.06 Ga with ?Ndi= +3.7. Nitrogen contents of corresponding diamond host growth zones in Group (1) are ? 50 at.ppm whereas Group (2) range between 50 to 700 at.ppm with N-aggregation > 70 %B. Additional data used to define “co-genetic” inclusion suites include Sr-isotopes and trace elements of the inclusions and carbon isotopes of the diamond hosts. Re-Os data of coexisting sulphide inclusions from the same silicate-bearing diamonds further validates the ages and indicates more periods of diamond formation at Jwaneng than previously assumed. The integrated data indicate the possibility of an extensive Paleoproterozoic diamond-forming event in southern Africa.
Mineralogy and Petrology, 10.1007/ s710-018-0592 -9, 10p.
Africa, Botswana
deposit - Orapa, Damtshaa, BK09, BK12,AK01
Abstract: Twenty eclogitic diamonds from Orapa Mine (Botswana) with an unusual yellow colour are characterised for their growth structure, N systematics, and C isotope composition, and the major element composition of their silicate inclusions. The diamonds show complex luminescence with green, blue and non-luminescent zones and occasional sector zonation. All parts of the diamonds have low total N concentrations (<50 at.ppm, with one exception of <125 at.ppm) and a limited range in C isotope composition (?5.7 to ?10.6‰). Fourier Transform Infrared spectra show bands at 1334, 1332, 1282, and 1240 cm?1 typical for Ib-IaA diamonds. Relict unaggregated N defects (Nso and Ns+) are present and the preservation is likely caused by the low N concentrations and possible low mantle residence temperatures rather than young diamond formation (inclusion ages of 140, 1096, 1699 Ma; Timmerman et al. Earth Planet Sc Lett 463:178-188, 2017). Garnet and clinopyroxene inclusions extracted from 14 diamonds have an eclogitic composition with relatively low Ca contents and based on all characteristics, these diamonds form a distinct population from Orapa.
Mineralogy and Petrology, 10.1007/s00710-018-0608-5 8p.
Africa, Botswana
indicator minerals
Abstract: The majority of the diamond mines in Botswana were discovered as a direct consequence of soil sampling for indicator minerals such as garnet and picroilmenite. Over the past 60 years the application of soil sampling for indicator minerals as a primary exploration tool has declined while aeromagnetic surveys have increased in popularity. The rate of kimberlite discovery in Botswana has declined significantly. The obvious magnetic kimberlites have been discovered. The future of new kimberlite discoveries is once again dependent on soil sampling for kimberlite indicator minerals. It is essential to have an in depth understanding of the transport mechanism of kimberlite indicator minerals from the kimberlite to the modern day surface of the Kalahari Formation, which is solely via termite bioturbation. Field observations indicate that the concentration of indicator minerals at surface is directly dependent on the physical characteristics and capabilities as well as behavioural patterns of the particular termite species dominant in the exploration area. The discovery of future diamond mines in Botswana will be closely associated with an in depth understanding of the relationship between size and concentration of kimberlite indicator minerals in surface soils and the seasonal behaviour, depth penetration capabilities, earthmoving efficiencies and mandible size of the dominant termite species within the exploration area. Large areas in Botswana, where kimberlite indicator minerals recovered from soil samples have been described as distal from source or background, will require re-evaluation. Without detailed termite studies the rate of discovery will continue to decline.
Mineralogy and Petrology, doi.org/10.1007/s00710-018-0604-9 12p.
Africa, Botswana
deposit - Karowe
Abstract: Mineral inclusions in diamonds play a critical role in constraining the relationship between diamonds and mantle lithologies. Here we report the first major and trace element study of mineral inclusions in diamonds from the Karowe Mine in north-east Botswana, along the western edge of the Zimbabwe Craton. From a total of 107 diamonds, 134 silicate, 15 oxide, and 22 sulphide inclusions were recovered. The results reveal that 53% of Karowe inclusion-bearing diamonds derived from eclogitic sources, 44% are peridotitic, 2% have a sublithospheric origin, and 1% are websteritic. The dominant eclogitic diamond substrates sampled at Karowe are compositionally heterogeneous, as reflected in wide ranges in the CaO contents (4-16 wt%) of garnets and the Mg# (69-92) and jadeite contents (14-48 mol%) of clinopyroxenes. Calculated bulk rock REEN patterns indicate that both shallow and deep levels of the subducted slab(s) were sampled, including cumulate-like protoliths. Peridotitic garnet compositions largely derive from harzburgite/dunite substrates (~90%), with almost half the garnets having CaO contents <1.8 wt%, consistent with pyroxene-free (dunitic) sources. The highly depleted character of the peridotitic diamond substrates is further documented by the high mean and median Mg# (93.1) of olivine inclusions. One low-Ca garnet records a very high Cr2O3 content (14.7 wt%), implying that highly depleted cratonic lithosphere at the time of diamond formation extended to at least 220 km depth. Inclusion geothermobarometry indicates that the formation of peridotitic diamonds occurred along a 39-40 mW/m2 model geotherm. A sublithospheric inclusion suite is established by three eclogitic garnets containing a majorite component, a feature so far unique within the Orapa cluster. These low- and high-Ca majoritic garnets follow pyroxenitic and eclogitic trends of majoritic substitution, respectively. The origin of the majorite-bearing diamonds is estimated to be between 330 to 420 km depth, straddling the asthenosphere-transition zone boundary. This new observation of superdeep mineral inclusions in Karowe diamonds is consistent with a sublithospheric origin for the exceptionally large diamonds from this mine.
Geochimica et Cosmochimica Acta, Vol. 213, 1, pp. 574-592.
Africa, Botswana
deposit - Orapa
Abstract: Major- and trace-element compositions of garnet and clinopyroxene, as well as 87Sr/86Sr in clinopyroxene and ?18O in garnet in eclogite and pyroxenite xenoliths from Orapa, at the western margin of the Zimbabwe craton (central Botswana), were investigated in order to trace their origin and evolution in the mantle lithosphere. Two groups of eclogites are distinguished with respect to 87Sr/86Sr: One with moderate ratios (0.7026-0.7046) and another with 87Sr/86Sr >0.7048 to 0.7091. In the former group, heavy ?18O attests to low-temperature alteration on the ocean floor, while 87Sr/86Sr correlates with indices of low-pressure igneous processes (Eu/Eu?, Mg#, Sr/Y). This suggests relatively undisturbed long-term ingrowth of 87Sr at near-igneous Rb/Sr after metamorphism, despite the exposed craton margin setting. The high-87Sr/86Sr group has mainly mantle-like ?18O and is suggested to have interacted with a small-volume melt derived from an aged phlogopite-rich metasome. The overlap of diamondiferous and graphite-bearing eclogites and pyroxenites over a pressure interval of ?3.2 to 4.9 GPa is interpreted as reflecting a mantle parcel beneath Orapa that has moved out of the diamond stability field, due to a change in geotherm and/or decompression. Diamondiferous eclogites record lower median 87Sr/86Sr (0.7039) than graphite-bearing samples (0.7064) and carbon-free samples (0.7051), suggesting that interaction with the - possibly oxidising - metasome-derived melt caused carbon removal in some eclogites, while catalysing the conversion of diamond to graphite in others. This highlights the role of small-volume melts in modulating the lithospheric carbon cycle. Compared to diamondiferous eclogites, eclogitic inclusions in diamonds are restricted to high FeO and low SiO2, CaO and Na2O contents, they record higher equilibrium temperatures and garnets have mostly mantle-like O isotopic composition. We suggest that this signature was imparted by a sublithospheric melt with contributions from a clinopyroxene-rich source, possibly related to the ca. 2.0 Ga Bushveld event.
Abstract: Roots of continental cratons keep a long record of multiple metasomatic events, but their trace is complicated due to the mixed signals left by these events in the composition of mantle silicate minerals. Simple composition helps diamonds to provide a more robust record of the latest metasomatic events which they witnessed. Growth and dissolution features on the diamond surface are sensitive to the composition of the reacting media. In this study we use mantle-derived resorption features on natural diamonds to examine the nature of metasomatic events in diamondiferous mantle lithologies. We use experiments at mantle conditions to examine how the composition of fluids and melts affect diamond resorption. We then compare these results to the features of natural diamonds to determine which of the tested compositions could have acted as metasomatic agents in Earth’s cratonic roots. Diamond dissolution experiments conducted at 6 GPa, 1200 - 1500oC using synthetic MgO-CaO-SiO2-CO2-H2O system examined the effect of CHO fluid, silica-saturated CHO fluid, aqueous and “dry” silica-carbonate and carbonate melts. Results show that the main control of diamond resorption morphology is the state of the reacting media: fluid vs. melt. We compared the experimental results to diamonds with mantle-derived resorption features from two kimberlites from the Orapa kimberlite cluster (Botswana). We identified twelve mantle-derived resorption types, none of which resembled the products of resorption in fluids. Most of the observed resorption types could be produced by dissolution in mantle melts with variable proportions of carbonate and silicate components and in the range of temperatures. The most abundant resorption type resembles the product of diamond dissolution in carbonate melts at temperatures above 1450oC. Our results suggest that fluid-metasomatism is not destructive for diamonds while melt-metasomatism is. The lower hydrous carbonated solidus of lherzolite compared to harzburgite can result in the shift the process from diamond growth in fluids to diamond dissolution in melts due to metasomatic transformation of harzburgite into lherzolite.
Africa, Zimbabwe. Australia, Canada, Northwest Territories, South Africa, Botswana
deposit - Murowa, Argyle, Diavik, Venetia, Orapa
Abstract: FTIR maps of diamond plates, cut through the centre of growth, contain abundant information about changing defect concentrations from core to rim. These data can, in principle, be interpreted in terms of the variation in conditions of diamond growth and the temperatures experienced by the diamond during the period of mantle residence between growth and exhumation. Many diamonds show multiple growth zones that can be observed by cathodoluminescence. Importantly, the combination of nitrogen concentration and nitrogen aggregation measured by FTIR can be used to determine whether the growth zones are of similar or very different ages (Kohn et al., 2016). In this study, we use automated fitting of several thousand individual spectra within each FTIR map to define a model temperature for each pixel using the Python program, QUIDDIT. We then use a two-stage aggregation model to constrain potential temperature-time histories for each diamond. To take full advantage of the temperature history recorded by zoned diamonds, radiometric ages of inclusions are required. If the growth ages of each zone and the date of exhumation are well-known, then a model temperature can be calculated for each zone. The combination of zone-specific ages and improved quality and processing of FTIR spectra is able to provide unique new insights into the thermal history of diamondbearing lithospheric mantle. For the first time we will be able to use the N defects in diamonds to work out whether a particular location in the lithosphere has heated or cooled over long periods of geological time. The implications for the mechanism of formation of lithosphere will be discussed. We will illustrate the approach using examples of zoned diamonds from Murowa (Zimbabwe), Argyle (Australia), Diavik (Canada), Venetia (South Africa) and Orapa (Botswana).
Abstract: Archean supracrustal rocks (i.e. chemical sediments and metavolcanics) preserve sulfur Mass Independent Fractionations (MIF) that originate from photochemical reactions occurring in atmosphere before the great oxygenation event, 2.45 Ga. Reduced and oxidized aerosols were produced by photochemistry and respectively carry 33S enrichment (?33S > 0‰) and depletion (?33S < 0‰). The relative abundance of the minor isotope of sulfur (36S) was also affected by MIF in such a way that compact negative correlation exists between ?33S and ?36S. For much of Archean sediments, ?36S /?33S? -1, while slight variation of this slope have been attributed to minor change in the chemical composition of the atmosphere affecting global MIF source mechanism. On another hand, 36S abundance is also affected by microbial cycling and in this specific case, ?36S /?33S? -7. Accordingly, ?33S-?36S co-variations can be used to discriminate distinct sedimentary pool. This contribution aims to test the robustness of MIF array of specific exospheric sulfur pools along their journey from the surface to the mantle. We examine the ?36S in addition to ?34S and ?33S signatures measured in-situ with secondary ion mass spectrometer, in sub lithospheric peridotitic and eclogitic sulfides from Kaapvaal (Jwaneng and Kimberley Pool) and Siberian craton (Mir and Udachnaya). Unlike peridotitic sulfides, eclogitic sulfides from both localities display significant MIF attesting from the presence of surficial sulfur in their source. More interestingly, the magnitude of the anomalies as well as ?36S/?33S ratio, differ from one locality to the other. Siberian eclogites match the composition of Eoarchean sulfate (?36S/?33S=-3 and ?33S<0‰). Sample from Jwaneng follow the MIF array previously reported in Archean chemical sediment (?36S/?33S=-1) while sulfide from Kimberley pool match the composition of some meso-Archean sediments in good agreement with isochron age reported in the literature for the sulfide from this locality. This study confirms that surficial sulfur has been efficiently transferred to the lithospheric mantle. More interestingly, it shows that peculiar sedimentary pools are still preserved in the cratonic keels.
Mineralogy and Petrology, doi.org/10.1007/s00710-018-0627-2 9p.
Africa, Botswana
deposit - Orapa
Abstract: This paper presents the results of an investigation into the structure of eolian kimberlite indicator minerals (KIMs) haloes present within Quaternary Kalahari Group sediments (up to 20 m thick) overlying the Late Cretaceous kimberlites in the Orapa field in North-East Botswana. A database of more than 8000 samples shows that kimberlites create a general mineralogical blanket of KIMs of various distances of transportation from primary sources in the Orapa area. Models of the reflection and dispersion patterns of KIMs derived from kimberlite pipes including AK10/ AK22/AK23 have been revealed based on 200 selected heavy mineral samples collected during diamond prospecting activities in Botswana from 2014 to 2017. Short distance eolian haloes situated close to kimberlite bodies cover gentle slopes within plains up to 500 × 1000 m in size. They have regularly have oval or conical shapes and are characterized by the presence mainly of unabraded or only slightly abraded KIMs. A sharp reduction of their concentration from hundreds and thousands of grains / 20 l immediately above kimberlites toto 10 grains/20 l at a distance of only 100-200 m from the pipes is a standard feature of these haloes. The variation of concentration, morphology and abrasion of specific KIMs with increasing distance from the primary sources has been investigated and presented herein. Sample volumes recommended for pipes present within a similar setting as those studied, with different depth of sedimentary cover are as follows: up to 10-20 m cover at 20-50 l, 20-30 m cover at 50-100 l and 30-80 m cover at 250 l. It is important to appreciate that the discovery of even single grains of unabraded or slightly abraded KIMs in eolian haloes are of high prospecting significance in this area. The results of the research can be applied to in diamond prospecting programs in various regions with similar environments.
Mineralogy and Petrology, doi.org/10.1007/s00710-018-0634-3 12p.
Africa, Botswana
deposit - Jwaneng
Abstract: To fully understand the implications of the compositional information recorded by inclusions in diamond it is vital to know if their growth was syn- or protogenetic and the extent to which they have equilibrated with diamond forming agents. The current paradigm is that the majority of inclusions in diamond are syngenetic but recently this assumption has been questioned. This study presents an integrated cathodoluminescence (CL) and electron backscatter diffraction (EBSD) study of 8 diamonds containing eclogitic inclusions: 19 pyrope-almandine garnets, 12 omphacitic clinopyroxenes, 4 sulphides, 1 coesite and 1 rutile from the Jwaneng diamond mine, Botswana. Diamond plates were sequentially polished to expose inclusions at different levels and CL imaging and EBSD were performed to constrain the relationship between diamond and inclusion growth. Despite complex growth and resorption, individual diamonds are single crystals with a homogeneous crystallographic orientation. All individual inclusions have homogeneous crystallographic orientation and no resolvable compositional zonation. The combined CL and EBSD data suggest that epitaxial inclusion-diamond growth is rare (none of 24 inclusions) and that the imposition of cubo-octahedral faces on inclusions does not necessarily result in epitaxy. Individual diamonds contain inclusions that record evidence of both syngentic and protogenetic relationships with the host diamond and in one case an inclusion appears syngenetic to the diamond core but protogenetic to the growth zone that surrounds 70% of the inclusion. These findings emphasise that inclusions in diamonds have multiple modes of origin and that in order to validate the significance of geochronological studies, further work is needed to establish that there is rapid chemical equilibration of protogenetic inclusions with diamond forming agents at mantle temperatures.
International Journal of Earth Sciences, Vol. 107, 7, pp. 2627-2633.
Africa, Botswana
kimberlites
Abstract: Glassy beads were found in the sand cover associated with known and suspected kimberlites on the Kalahari plateau, Botswana. Morphology and chemistry were examined by ESEM and EDAX. The polymetallic and quartzose "beads", here described for the first time and termed fulguroids, formed at very high temperatures, well in excess of those reached by the kimberlites. They solidified in free fall. We propose that they were melted in the atmosphere by lightning strikes on Kalahari overburden entrained when the kimberlites erupted.
Journal of African Earth Sciences, Vol. 137, pp. 9-21.
Africa, Botswana
deposit - Jwaneng
Abstract: Country rock at Jwaneng Diamond Mine provides a rare insight into the deformational history of the Transvaal Supergroup in southern Botswana. The ca. 235 Ma kimberlite diatremes intruded into late Archaean to Early Proterozoic, mixed, siliciclastic-carbonate sediments, that were subjected to at least three deformational events. The first deformational event (D1), caused by NW-SE directed compression, is responsible for NE-trending, open folds (F1) with associated diverging, fanning, axial planar cleavage. The second deformational event (D2) is probably progressive, involving a clockwise rotation of the principal stress to NE-SW trends. Early D2, which was N-S directed, involved left-lateral, oblique shearing along cleavage planes that developed around F1 folds, along with the development of antithetic structures. Progressive clockwise rotation of far-field forces saw the development of NW-trending folds (F2) and its associated, weak, axial planar cleavage. D3 is an extensional event in which normal faulting, along pre-existing cleavage planes, created a series of rhomboid-shaped, fault-bounded blocks. Normal faults, which bound these blocks, are the dominant structures at Jwaneng Mine. Combined with block rotation and NW-dipping bedding, a horst-like structure on the northwestern limb of a broad, gentle, NE-trending anticline is indicated. The early compressional and subsequent extensional events are consistent throughout the Jwaneng-Ramotswa-Lobatse-Thabazimbi area, suggesting that a large area records the same fault geometry and, consequently, deformational history. It is proposed that Jwaneng Mine is at or near the northernmost limit of the initial, northwards-directed compressional event.
Gems & Gemology, Sixth International Gemological Symposium Vol. 54, 3, 1p. Abstract p. 273-4.
Africa, Botswana
deposit - Karowe
Abstract: In November 2015, Lucara Diamond’s operation at the Karowe mine in Botswana gained notoriety due to the extraction of a series of large colorless diamonds, including the 1,109 ct Lesedi La Rona and the 812 ct Constellation. The Lesedi La Rona marks the largest gem diamond recovered since the Cullinan (3,106 ct) in 1905. The Constellation, considered to be the seventh-largest recorded diamond, attained the highest price ever paid for a rough, selling for $63.1 million ($77,649 per carat). Additionally, three other significant colorless diamonds were recovered during the same period, weighing 374, 296, and 183 ct. Due to the similarity in their external characteristics— which include cleavage faces—as well as their extraction locations and dates, it was suspected that these stones might have originated from a larger rough that had broken. Lucara demonstrated that the 374 ct diamond and the Lesedi La Rona fit together, yet a large cleavage plane is still unaccounted for. GIA was able to study several rough and/or faceted pieces of these five diamonds using a range of spectroscopic and imaging techniques to gain insight into the presence and distribution of point defects in these diamonds. Diamonds are commonly classified according to their nitrogen content measured by Fourier-transform infrared (FTIR) spectroscopy: Type I diamonds contain nitrogen in either isolated (Ib) or aggregated (IaAB) forms, while type II diamonds do not contain detectable nitrogen concentrations (IIa) but may contain boron (IIb). Analysis of faceted stones cut from the Lesedi La Rona indicates that the rough is a mixed-type diamond, containing both type IIa and pure type IaB regions. These types of diamonds, though exceedingly unusual, have been observed at GIA and reported by Delaunay and Fritsch (2017). The Constellation and the 374, 296, and 183 ct diamonds were determined to be type IaB, containing 20 ± 4 ppm B-aggregates (N4V), in agreement with the concentration for the type IaB pieces of the Lesedi La Rona. Pure type IaB diamonds such as these are actually quite rare, accounting for only 1.2% of a random suite of 5,060 large (>10 ct) D-to-Z diamonds submitted to GIA, whereas 24.6% were type II. Photoluminescence spectra further confirmed analogous defect content for the five large Karowe diamonds, with emissions from H4 (N4V2 0, 496 nm), H3 (NVN0, 503 nm), 505 nm, NV– (637 nm), and GR1 (V0, 741 nm) defects showing similar relative intensities and peak widths. Even for diamonds of the same type, parallel defect content and characteristics across such a variety of defects is unlikely for unrelated stones. The external morphologies of the diamonds showed primary octahedral, resorbed, and fractured faces, with the Constellation and the 296 ct diamond featuring fractures containing metallic inclusions and secondary iron oxide staining. Deep UV fluorescence (< 230 nm) imaging elucidated the internal growth structures of the samples. For the Constellation and the 374, 296, and 183 ct diamonds, at least two growth zones with differing blue fluorescence intensities were observed within single pieces. Combined with the spectroscopic data, these results provide compelling evidence that the Lesedi La Rona, the Constellation, and the 374, 296, and 183 ct diamonds from Karowe had comparable growth histories and likely originated from the same rough, with a combined weight of at least 2,774 ct.
Abstract: Diamonds originate deep in the Earth's mantle since billions of years ago. Through their long history diamonds accumulate information about the Earth's evolution, and preserve it owing to their extreme chemical and mechanical stability. The surface of natural diamonds shows a variety of growth and dissolution features, which reflect the diversity of conditions in the mantle and in kimberlite magma, providing an important clue for understanding the deep regions of subcratonic mantle. However, such studies are hampered by an absence of a systematic approach for studying diamond surface features and morphology. This review integrates studies of natural diamonds with the results of diamond dissolution experiments to explore the origin of the most typical resorption features of diamonds and the information they provide. It uses detailed studies of over ~ 3500 diamonds from eight kimberlite bodies in the Northwest Territories in Canada and Orapa kimberlite cluster in Botswana, and the data from diamond dissolution experiments covering a pressure range of between 0.1?MPa - 7.5?GPa, temperature range of between 900?°C - 1750?°C, and over 12 log units of oxygen fugacity values. Examining the effects of these parameters on diamond resorption morphology shows that the shape and size of the etch pits depends on the temperature and H2O:CO2 ratio in the fluid, whereas pressure affects the efficiency of diamond crystal shape transformation from octahedral into rounded resorbed forms. The effect of pressure on the physical properties of the reacting fluid / melt controls the character of diamond etching. A comparison between the experimentally-induced and naturally occurring diamond resorption demonstrates a clear difference between the features developed in kimberlite magma and features inherited from the mantle source. Kimberlite-induced resorption on diamonds shows a strong correlation with the geology and emplacement mode of the hosting kimberlite unit. Low-relief surfaces develop on diamonds from pyroclastic kimberlites in all kimberlite classes, whereas surface features on diamonds from coherent kimberlites differ between kimberlite localities and often show corrosive character. Diamond resorption morphology can offer a robust method to better understand emplacement processes in different kimberlite localities, which are a matter of significant debate. The proposed here classification scheme for diamond resorption features is based on the features observable under a stereomicroscope. It helps differentiating resorption produced in the mantle source from that in the kimberlite magma and assigning diamond resorption to a particular mode of kimberlite emplacement, or a mantle metasomatic event.
The Southern African Institute of Mining and Metallurgy, Vol. 119, pp. 155-164.
Africa, Botswana
deposit - Jwaneng
Abstract: Despite the pre-eminence of the Jwaneng Diamond Mine as the world's richest diamond mine, the discovery story has long been clouded in mystery. This is the 45-year old untold story of the Jwaneng discovery and contemporaneous Bechuanaland/Botswana political and socioeconomic history.
Abstract: Together with Mauritius, Botswana is often categorized as one of two growth miracles in sub-Saharan Africa. Due to its spectacular long-run economic performance and impressive social development, it has been termed both an economic success story and a developmental state. While there is uniqueness in the Botswana experience, several aspects of the country’s opportunities and challenges are of a more general nature. Throughout its history, Botswana has been both blessed and hindered by its natural resource abundance and dependency, which have influenced growth periods, opportunities for economic diversification, strategies for sustainable economic and social development, and the distribution of incomes and opportunities. Through a political economy framework, Hillbom and Bolt provide an updated understanding of an African success story, covering the period from the mid-19th century, when the Tswana groups settled, to the present day. Understanding the interaction over time between geography and factor endowments on the one hand, and the development of economic and political institutions on the other, offers principle lessons from Botswana’s experience to other natural resource rich developing countries.
Geochimica et Cosmochimica Acta, in press available 29p.
Africa, South Africa, Botswana
deposit - Koffiefontein, Letlhakane, Orapa, Finsch, De Beers Pool
Abstract: Ten individual gem-quality monocrystalline diamonds of known peridotite/eclogite paragenesis from Southern Africa (Koffiefontein, Letlhakane, Orapa) were studied for trace element concentrations and He and Ar abundances and isotopic compositions. In addition, two samples, consisting of pooled fragments of gem-quality peridotitic diamonds from Finsch and DeBeers Pool respectively, were analysed for noble gases. Previous studies (Richardson et al., 1984; Pearson et al., 1998; Gress et al., 2017; Timmerman et al., 2017) provided age constraints of 0.09, 1.0-1.1, 1.7, 2.3, and 3.2-3.4?Ga on mineral inclusions in the studied diamonds, allowing us to study trace elements and noble gases over 3 Gyr of geological time. Concentrations of trace elements in the diamonds are very low - a few hundred ppt to several tens of ppbs - and are likely dependent on the amount of sub-micron inclusions present. Trace element patterns and trace element/3He ratios of the studied monocrystalline diamonds are similar to those in fibrous diamonds, suggesting that trace elements and stable noble gas isotopes reside within the same locations in diamond and track the same processes that are reflected in the trace element patterns. We cannot discern any temporal differences in these geochemical tracers, suggesting that the processes generating them have been occurring over at least the past 2.3?Ga. 3He/4He ratios decrease and 4He and 40Ar* contents increase with increasing age of peridotitic and some eclogitic diamonds, showing the importance of in-situ radiogenic 4He and 40Ar ingrowth by the decay of U-Th-Sm and K respectively. For most gem-quality monocrystalline diamonds, uncertainties in the 3He/4He evolution of the continental lithospheric mantle combined with large analytical uncertainties and possible spatial variability in U-Th-Sm concentrations limit our ability to provide estimates of diamond formation ages using 4He ingrowth. However, the limited observed 4He ingrowth (low U?+?Th/3He) together with a R/Ra value of 5.3 for peridotitic diamond K306 is comparable to the present-day sub-continental lithospheric mantle value and supports the young diamond formation age found by Re-Os dating of sulphides in the same diamond by Pearson et al. (1998). After correction for in-situ radiogenic 4He produced since diamond formation a large variation in 3He/4He remains in ?1?Ga old eclogitic diamonds that is suggested to result from the variable influence of subducted altered oceanic crust that has low 3He/4He. Hence, the 3He/4He isotope tracer supports an origin of the diamond-forming fluids from recycled oceanic crust for eclogitic diamonds, as indicated by other geochemical proxies.
Abstract: The physical characteristics and impermeability of diamonds allow them to retain radiogenic 4He produced in-situ from radioactive decay of U, Th and Sm. This study investigates the U-Th/He systematics of fibrous diamonds and provides a first step in quantification of the uncertainties associated with determining the in-situ produced radiogenic 4He concentration. Factors determining the total amount of measured helium in a diamond are the initial trapped 4He, the in-situ produced radiogenic 4He, ?-implantation, ?-ejection, diffusion, and cosmogenic 3He production. Alpha implantation is negligible, and diffusion is slow, but the cosmogenic 3He component can be significant for alluvial diamonds as the recovery depth is unknown. Therefore, samples were grouped based on similar major and trace element compositions to determine possible genetically related samples. A correlation between the 4He and U-Th concentrations approximates the initial 4He concentration at the axis-intersect and age as the slope. In this study, the corrections were applied to eight fibrous cubic diamonds from the Democratic Republic of the Congo and two diamonds from the Jwaneng kimberlite in Botswana. A correlation exists between the 4He and U-Th concentrations of the group ZRC2, 3, and 6, and of the group CNG2, 3, and 4 and both correlations deviate significantly from a 71?Ma kimberlite eruption isochron. The U-Th/He dating method appears a promising new approach to date metasomatic fluid events that result in fibrous diamond formation and this is the first evidence that some fibrous diamonds can be formed 10s to 100s Myr before the kimberlite eruption.
Phd. Thesis University of Alberta, 147p. See note on front page - see U of A search strategy on cover page
Africa, Botswana
deposit - Karowe
Abstract: This study presents the first comprehensive data on the recently developed Karowe diamond mine from the Orapa kimberlite cluster, which hosts mines such as Orapa, Damtshaa, and Letlhakane. The objectives of the study were to establish the compositional characteristics of the lithospheric mantle beneath the Karowe mine at the time of kimberlite eruption by studying the major- and trace-element characteristics of 24 mantle xenoliths and 106 clinopyroxene xenocrysts. In addition, the possible diamond sources beneath Karowe were evaluated through examination of major- and trace-element compositions of mineral inclusions in 120 diamonds. Finally, the physical characteristics of the diamonds themselves as well as their total nitrogen contents and carbon isotope compositions were investigated.The mantle xenoliths are predominantly melt-depleted garnet-free spinel peridotites (n = 14), with a small proportion of pervasively refertilised garnet-spinel lherzolites (n = 4), and variably metasomatised garnet-bearing pyroxenites (n = 3). The remaining three xenoliths are a garnet lherzolite, an eclogite, and a megacrystic olivine. The mineralogical evidence indicates that all these come from relatively low-pressure regions of the mantle outside of the diamond stability field. The predominant spinel lherzolites are characterised by coarse-grained and granolublastic textures, exsolution lamellae in clinopyroxenes and orthopyroxenes, and low equilibration temperatures (630 to 800 oC). They have high Mg# in olivines (median: 92.1) and orthopyroxenes (median: 92.4) as well as variable Cr# in spinels (13 to 47; median: 37). Clinopyroxenes show variable LREEN enrichment (LaN/SmN=0.24 to 3.8) which is consistent with secondary re-enrichement processes. Trace element compositions of the garnets and clinopyroxenes in the garnet-bearing xenoliths indicate cryptic melt metasomatism as well as modal metasomatism associated with the introduction of phlogopite. Clinopyroxene-based geothermobarometry on clinopyroxene xenocrysts (25 out of the106) and one garnet lherzolite xenolith indicate a 39 to 40 mW/m2 model paleogeotherm, which overlaps at greater depths with two non-touching garnet-orthopyroxene inclusion pairs recovered from Karowe diamonds. These data imply that the lithospheric mantle beneath Karowe is 210 km thick with a diamond window of approximately 90 km thickness, which is consistent with other estimates of lithospheric depths in this region of the Zimbabwe Craton derived from petrology and geophysics. The major- and trace-element compositions of mineral inclusions in the diamonds indicate that 53 % are derived from eclogitic sources, 44 % are peridotitic, 2% have a sublithospheric origin, and 1 % are websteritic. The sublithospheric inclusion suite consists of three eclogitic garnets containing a majorite component (>6.12 to 6.46 apfu Si; with [O] = 24). This new observation of superdeep mineral inclusions in Karowe diamonds is unique within the Orapa cluster and may provide a key link to the presence of exceptionally large diamonds from this mine.From the present diamond suite, Karowe diamonds have variable morphologies with a dominance of octahedra (30 %), macles (20 %), and moderately resorbed morphologies (transitional between octahedra and dodecahedra; 18 %). The remaining 32 % are made up of 10 % rounded dodecahedra, 4 % cubo-octahedra, 2 % pseudo-hemimorphic and 16 % aggregated crystals. Overall, diamonds have FTIR nitrogen contents that range from below the limit of detection (?15 at.ppm) to 1217 at.ppm with variable nitrogen aggregation states (0 to 100 %B) and ?13C values from -34.5 to -2.0 ‰. Eclogitic diamonds contain 24 to 1217 at.ppm nitrogen with a median of 513 at.ppm and their carbon isotope compositions range between -21.5 and -2.5 ‰ with a median at -4.9 ‰. Peridotitic diamonds contain up to 937 at.ppm nitrogen with a median of 129 at.ppm. The majority of peridotitic diamonds fall into a typical mantle-like ?13C range (-8.6 to -2.0 ‰), with the exception of two diamonds that display unusual strongly 13C-depleted isotope compositions (-34.5 and -14.9 ‰). The mode in ?13C values for peridotitic diamonds (in class -4.0 to -3.5 ‰) is offset by about +1 ‰ relative to eclogitic diamonds (mode in class -5.0 to -4.5 ‰). These results could reflect derivation of mantle-like carbon from different sources through time for the two main parageneses or relate to the speciation of carbon fluids with constant ?13C (e.g., a minor increase in the CO2/CH4 ratio in the diamond-forming fluid from peridotitic to eclogitic diamonds).
Geochemical Perspectives Letters, Vol. 11, pp. 39-43. pdf
Africa, Botswana, South America, French Guiana
deposit - Dachine, Orapa
Abstract: Fluid inclusions trapped in fast-growing diamonds provide a unique opportunity to examine the origin of diamonds, and the conditions under which they formed. Eclogitic to websteritic diamondites from southern Africa show 13C-depletion and 15N-enrichment relative to mantle values (?13C = -4.3 to -22.2 ‰ and ?15N = -4.9 to +23.2 ‰). In contrast the 3He/4He of the trapped fluids have a strong mantle signature, one sample has the highest value so far recorded for African diamonds (8.5 ± 0.4 Ra). We find no evidence for deep mantle He in these diamondites, or indeed in any diamonds from southern Africa. A correlation between 3He/4He ratios and 3He concentration suggests that the low 3He/4He are largely the result of ingrowth of radiogenic 4He in the trapped fluids since diamond formation. The He-C-N isotope systematics can be best described by mixing between fluid released from subducted altered oceanic crust and mantle volatiles. The high 3He/4He of low ?13C diamondites reflects the high 3He concentration in the mantle fluids relative to the slab-derived fluids. The presence of post-crystallisation 4He in the fluids means that all 3He/4He are minima, which in turn implies that the slab-derived carbon has a sedimentary organic origin. In short, although carbon and nitrogen stable isotope data show strong evidence for crustal sources for diamond-formation, helium isotopes reveal an unambiguous mantle component hidden within a strongly 13C-depleted system.
Abstract: Botswana experienced a Mw 6.5 earthquake on 3rd April 2017, the second largest earthquake event in Botswana's recorded history. This earthquake occurred within the Limpopo-Shashe Belt, ~350 km southeast of the seismically active Okavango Rift Zone. The region has no historical record of large magnitude earthquakes or active faults. The occurrence of this earthquake was unexpected and underscores our limited understanding of the crustal configuration of Botswana and highlight that neotectonic activity is not only confined to the Okavango Rift Zone. To address this knowledge gap, we applied a regularized inversion algorithm to the Bouguer gravity data to construct a high-resolution crustal thickness map of Botswana. The produced crustal thickness map shows a thinner crust (35-40 km) underlying the Okavango Rift Zone and sedimentary basins, whereas thicker crust (41-46 km) underlies the cratonic regions and orogenic belts. Our results also show localized zone of relatively thinner crust (~40 km), one of which is located along the edge of the Kaapvaal Craton within the MW 6.5 Botswana earthquake region. Based on our result, we propose a mechanism of the Botswana Earthquake that integrates crustal thickness information with elevated heat flow as the result of the thermal fluid from East African Rift System, and extensional forces predicted by the local stress regime. The epicentral region is therefore suggested to be a possible area of tectonic reactivation, which is caused by multiple factors that could lead to future intraplate earthquakes in this region.
Botswana Journal of Earth Sciences, Vol. 7, pp. 43-57. pdf
Africa, Botswana
prospecting, markets
Abstract: In this paper I describe the different components that make up the Botswana Diamond Pipeline today, which means the supply chain of diamonds, that ranges from diamond prospecting to mining, to diamond processing and recovery, to rough diamond sorting, valuation, sales and marketing, to diamond polishing and cutting, and finally to diamond jewellery manufacturing and retail. In Botswana, we can now truly witness the journey of the diamond from “Rough to Finger” or from “Mine to Store” (Fig. 1). Today, Botswana is the world’s second largest producer of diamonds by value and volume after Russia, and there are currently twelve known kimberlite fields (Fig. 2) and eight operating diamond mines. Botswana’s diamonds are cut and polished into beautiful diamond jewellery locally and across the globe.
Botswana Journal of Earth Sciences, Vol. 7, pp. 13-28. pdf
Africa, Botswana
deposit - AK6
Abstract: The AK6 kimberlite in north-eastern Botswana, better known as Karowe, is today one of the world?s top diamond producers by value. Its potential, however, was not recognised when AK6 was first discovered some fifty years ago. This paper traces the history of Karowe from the discovery of AK6 through to evaluation and production, reflecting on the interplay of economic, technical and corporate elements and highlighting some of the lessons learnt along this journey. Karowe Mine has been operating since 2012 and is fully owned by Lucara Diamond Corporation. In 2015, Karowe yielded the second largest diamond ever found, the 1,109ct Lesedi La Rona (Fig. 1).
Abstract: Experiments on diamond crystallization in kimberlite melt were performed for 40 h at 6.3 GPa in the temperature range of 1300-1570 °C and at 7.5 GPa in the temperature range of 1450-1570 °C, using a multianvil high-pressure apparatus of split-sphere type. Group I kimberlite from the Udachnaya-East pipe and a synthetic multicomponent mixture modeling the average composition of group II kimberlites were used as starting materials. The experiments have shown that diamond growth on seed crystals in the kimberlite melt in equilibrium with olivine, pyroxene, and garnet starts from 1400 °C at 7.5 GPa and from 1520 °C at 6.3 GPa. Diamond nucleation requires higher temperature and pressure, 1570 °C and 7.5 GPa. The alkali-enriched and silicate-depleted derivates of kimberlite melts ensure the growth and nucleation of diamond at lower P and T values: 1400 °C at 7.5 GPa and 1520 °C at 6.3 GPa. The results obtained evidence that temperature, pressure, and the composition of crystallization medium are the main factors controlling diamond formation processes in the kimberlite melts and their derivates.
Botswana Journal of Earth Sciences, Vol. 7, pp. 29-34. pdf
Africa, Botswana
deposit - KX36
Abstract: The KX36 kimberlite pipe is situated in the southeastern part of Central Kalahari Game Reserve (CKGR), Botswana, approximately 60 km from the known Gope and Kikao kimberlite fields (see figure 1).The kimberlite is covered by 75m of Kalahari sand, has a surface area of 3.6 Ha at the base of the sand cover and was discovered by Petra Diamonds Botswana (Pty) Ltd in 2008. Application of modern geophysical techniques (Ultra hi-resolution low level flying Xcalibur magnetics) and improved sampling method led to the discovery of KX36.The kimberlite was emplaced into the Karoo Supergroup, which comprised the older sedimentary rocks (300 - 185 Ma) overlain by the flood basalts (185Ma). The Karoo Supergroup rocks are overlain by approximately 80m of Kalahari Group sediments.
Botswana Journal of Earth Sciences, Vol. 7, pp. 1-2. pdf
Africa, Botswana
deposit - Orapa
Abstract: I feel tremendously honoured and privileged to be invited to attend the 50thanniversary celebrations of the Orapa discovery. Thank you, Leon Daniels and Debswana. This will be a very emotional and exciting experience for me to return to Orapa after 50 years, where early in the morning of the 21st of April 1967 my team of twelve Motswana explorers and I stepped onto a low calcrete hill littered with kimberlitic indicator minerals. This was not entirely unexpected, as some months earlier Dr Gavin Lamont (the exploration manager) and Jim Gibson (the senior geologist) had detected such minerals during a road sampling survey into this isolated region south of the Makgadigadi Pans. However, what was unexpected was the enormous size of this kimberlite pipe that was destined to become the world-class Orapa diamond mine.
The Journal of the Southern African Insitute of Mining and Metallurgy, Vol. 119, Feb, 9p. Pdf
Africa, South Africa, Zimbabwe, Namibia, Angola, DRC, Lesotho, Botswana, eSwatini
production
Abstract: Southern Africa is generally thought to be well explored, with only limited potential for major new diamond discoveries. However, Chiadzwa in Zimbabwe and reports of a significant new kimberlite find in Angola are testimony to the dangers attached to an attitude that 'there is nothing left to find'.
Since the major discoveries in the central interior of South Africa in the 1870s, diamond exploration in the region has been led by market and political factors that influence the key exploration drivers of opportunity and value proposition. Unexpected new discoveries by new players always impact on existing producers and, from time to time, denial of opportunity through political or protectionist policies has inhibited investment in exploration. Entrepreneurial exploration appetite in southern Africa will be tempered by the potential value equation and security of investment. Overlaid on this, developments in diamond recovery technologies provide opportunity to reinvigorate current mines and old prospects previously considered too difficult or costly to exploit. Position on the cost curve will remain a key factor for survival in an increasingly competitive environment.
Botswana Journal of Earth Sciences, Vol. 7, pp. 35-41. pdf
Africa, Botswana
Deposit - Gope
Abstract: The Gope (Go25) kimberlite was discovered by Falconbridge Explorations Limited (Botswana) (FELB) in 1981, following a helicopter-supported sampling programme within Reconnaissance Permits RP8/79 and RP1/80, covering approximately 78 500 km2, centred on the Central Kalahari area of Botswana (Fig. 1). The majority of this area is covered by sands of the Kalahari Group, with thicknesses up to 100m. Unfortunately, most original company files, including mineral distribution maps and mineral analyses were not available to the author. This paper draws on the excellent summary of the discovery of the Gope (Go-25) kimberlite by Lee et al. (2009), together with the author’s personal recollections.
Botswana Journal of Earth Sciences, Vol. 7, pp. 3-12. pdf
Africa, Botswana
deposit - Jwaneng
Abstract: When Leon Daniels first contacted us, and others, about the Botswana Diamond Exploration Conference 2017, he wrote: ‘The future of diamond exploration lies in us "old-timers" who have retired or are about to retire to inspire the next generation to go out there and make the next discoveries so vitally important for Botswana.’ Sadly, in presenting on behalf of both Stuart and I, I had to own to being one of those old-timers!
Msc. Thesis VRIJE University Amsterdam, 166p. Academia available pdf
Africa, Botswana
deposit - Letlhakane
Abstract: The Letlhakane kimberlite pipes are emplaced in the Proterozoic Makondi Fold Belt, Botswana. They belong to a cluster of kimberlite diatremes that also includes the Orapa diamond mine, approximately 40 km to the northwest. In a previous geochemical study on Letlhakane xenoliths it was proposed that the Makondi Fold Belt is underlain by Archaean mantle that belongs to the Zimbabwe Craton. This implies the Letlhakane Kimberlites were sourced from the edge of Zimbabwe cratonic mantle and ascended through Proterozoic Makondi crust, explaining their rather anomalous tectonic setting. In this study we aim to verify the Archaean nature of the lithospheric mantle beneath Letlhakane and assess the origin and extent of metasomatic modifications in comparison to the Kaapvaal and Zimbabwe Cratons. We present an extensive petrological, geochemical and isotopic dataset on a selection of 38 peridotite xenoliths from Letlhakane in order to characterize the mantle that underlies northern Botswana. Whole rock and mineral major and trace elements were measured by electron microprobe (EMP), laser ablation ICPMS and XRF. Sm-Nd and Lu-Hf isotope analyses were performed on garnet, cpx and amphibole separates from 12 selected samples. The sample suite includes spinel harzburgites, spinel lherzolites, a spinel dunite, a wehrlite, a garnet websterite, garnet harzburgites, garnet lherzolites and amphibole bearing garnet lherzolites. The samples are categorized into four groups based on garnet chemistry and modal compositions: I) garnet free samples, II) garnet harzburgites, II) garnet lherzolites and IV) amphibole-bearing garnet lherzolites. Whole rock major elements and olivine magnesium numbers suggest that the SCLM experienced 20 to 60% melt depletion between 5 and 3 GPa. Reconstructed whole rock HREE concentrations and Lu-Yb systematics indicate that up to 20% melting occurred in the absence of garnet, leading to strong fractionation of HREE. The data suggest a shallow decompressional melting regime, consistent with Archaean cratonic genesis models. Preliminary Re-Os data suggest melt depletion occurred at ~2.7 Ga. All samples experienced various amounts of metasomatic re-enrichment expressed by high modal abundances of garnet, opx, clinopyroxene and amphibole. Silica enrichment occurred to a lesser extent than observed in the Kaapvaal, but the Letlhakane samples show significantly more opx-rich assemblages than reported for the Zimbabwe Craton. Sm-Nd and Lu-Hf isotope signatures of garnet harzburgites suggest LREE enrichment occurred around ~2.0 Ga, possibly related to major tectono-magmatic activity associated with accretion of the Makondi Fold Belt to the Zimbabwe Craton. Cpx from the garnet lherzolites show major isotopic interaction and re-equilibration with Group I Kimberlites, which probably crystallized from pre-cursor kimberlitic melts prior to the Letlhakane eruption at ~93 Ma. Trace elements and Nd-Hf istope systematics of the amphibole bearing samples suggest amphibole metasomatism occurred from a LREE, Na, Ka, Ca and Al enriched hydrous melt around 500 to 600 Ma, possibly associated with Pan-African magmatic activity in northern Botswana. The overall lack of negative Nb-Ta anomalies suggests that metasomatic melts were generated in a within-plate geodynamical environment, rather than a subduction related setting.
Geochimica et Cosmochimica Acta, 10.1016/j.gca.2020.10.010 35p. Pdf
Africa, Botswana
deposit - Jwaneng
Abstract: Constraining the formation age of individual diamonds from incorporated mineral inclusions and assessing the host diamonds’ geochemical characteristics allows determination of the complex history of diamond growth in the sub-continental lithospheric mantle (SCLM). It also provides the rare opportunity to study the evolution of the deep cycling of volatiles over time. To achieve these aims, Sm-Nd isotope systematics are presented for 36 eclogitic garnet and clinopyroxene inclusions from 16 diamonds from the Jwaneng mine, Botswana. The inclusions and host diamonds comprise at least two compositional suites that record different ‘mechanisms’ of diamond formation and define two isochrons, one Paleoproterozoic (1.8 Ga) and one Neoproterozoic (0.85 Ga). There are indications of at least three additional diamond-forming events whose ages currently cannot be well constrained. The Paleoproterozoic diamond suite formed by large-scale (> 100’s km), volatile-rich metasomatism related to formation and re-working of the Proto-Kalahari Craton. In contrast, the heterogeneous composition of the Neoproterozoic diamond suite indicates diamond formation on a small-scale, through local (< 10 km) equilibration of compositionally variable diamond-forming fluids in different eclogitic substrates during the progressive breakup of the Rodinia supercontinent. The results demonstrate that regional events appear to reflect the input of volatiles (i.e., carbon-bearing) derived from the asthenospheric mantle, whereas local diamond-forming events mainly promote the redistribution of volatiles within the SCLM. The occurrence of isotopically light carbon analysed in distinct growth zones from samples of this study (?13C < -21.1‰) provides further indication of a recycled origin for surface-derived carbon in some diamonds from Jwaneng. Determining Earth’s long-term deep carbon cycle using diamonds, however, requires an understanding of the nature and scale of specific diamond-forming events.
Geochimica et Cosmochimica Acta, Vol. 293, pp. 1-17. pdf
Africa, Botswana
deposit - Jwaneng
Abstract: Constraining the formation age of individual diamonds from incorporated mineral inclusions and assessing the host diamonds’ geochemical characteristics allows determination of the complex history of diamond growth in the sub-continental lithospheric mantle (SCLM). It also provides the rare opportunity to study the evolution of the deep cycling of volatiles over time. To achieve these aims, Sm-Nd isotope systematics are presented for 36 eclogitic garnet and clinopyroxene inclusions from 16 diamonds from the Jwaneng mine, Botswana. The inclusions and host diamonds comprise at least two compositional suites that record different ‘mechanisms’ of diamond formation and define two isochrons, one Paleoproterozoic (1.8?Ga) and one Neoproterozoic (0.85?Ga). There are indications of at least three additional diamond-forming events whose ages currently cannot be well constrained. The Paleoproterozoic diamond suite formed by large-scale (>100?s km), volatile-rich metasomatism related to formation and re-working of the Proto-Kalahari Craton. In contrast, the heterogeneous composition of the Neoproterozoic diamond suite indicates diamond formation on a small-scale, through local (<10?km) equilibration of compositionally variable diamond-forming fluids in different eclogitic substrates during the progressive breakup of the Rodinia supercontinent. The results demonstrate that regional events appear to reflect the input of volatiles (i.e., carbon-bearing) derived from the asthenospheric mantle, whereas local diamond-forming events mainly promote the redistribution of volatiles within the SCLM. The occurrence of isotopically light carbon analysed in distinct growth zones from samples of this study (?13C??21.1‰) provides further indication of a recycled origin for surface-derived carbon in some diamonds from Jwaneng. Determining Earth’s long-term deep carbon cycle using diamonds, however, requires an understanding of the nature and scale of specific diamond-forming events.
Abstract: Re-Os isotope systematics are reported from a suite of eclogitic and websteritic sulphide inclusions extracted from well-characterised diamond growth zones from the Orapa and Jwaneng kimberlite clusters. Re-Os ages (786 ± 250 Ma) are within uncertainty of previously determined Sm-Nd ages (853 ± 55 Ma), demonstrating isotopic equilibrium, at varying levels of completeness, across multiple isotopic systems in different minerals at the time of diamond formation and inclusion encapsulation. These data confirm the concept that inclusion isochron ages, when used with detailed textural/ growth zone control, reflect the timing of diamond crystallisation. Our data substantiate previous Re-Os and Sm-Nd inclusion ages of diamonds from Orapa and Jwaneng, indicating that major tectono-magmatic events formed discrete diamond populations of Paleo- (~ 2.0 to 1.7 Ga), Meso- (~ 1.2 to 1.1 Ga) and Neoproterozoic (~ 0.9 to 0.75 Ga) age. Some of these processes occurred simultaneously across the Kalahari Craton and can be traced over 100's of km illustrating the significance of diamond inclusions for monitoring continental tectonics. Inclusion ages indicating diamond formation that are younger than 300 Ma appear to be more common than previously recognised, consistent with evidence of relatively abundant, young, fluid-rich "fibrous" and polycrystalline diamonds at Jwaneng and Orapa. The increasingly widespread evidence for Mesozoic diamond-forming events in southern Africa and elsewhere appears closely linked with the kimberlite-related magmatism that affected these regions and subsequently transported diamonds to the surface. The inclusion isochron ages emphasise that diamond formation is a multi-stage and episodic process that can occur contemporaneously in disparate substrates and produce multiple diamond populations in the sub-continental lithospheric mantle.
Appendix to previous Lithos article in March 2021, 11p. Pdf
Africa, Botswana
deposit - Damtshaa, Orapa
Abstract: Re-Os isotope systematics are reported from a suite of eclogitic and websteritic sulphide inclusions extracted from well-characterised diamond growth zones from the Orapa and Jwaneng kimberlite clusters. Re-Os ages (786 ± 250 Ma) are within uncertainty of previously determined Sm-Nd ages (853 ± 55 Ma), demonstrating isotopic equilibrium, at varying levels of completeness, across multiple isotopic systems in different minerals at the time of diamond formation and inclusion encapsulation. These data confirm the concept that inclusion isochron ages, when used with detailed textural/ growth zone control, reflect the timing of diamond crystallisation. Our data substantiate previous Re-Os and Sm-Nd inclusion ages of diamonds from Orapa and Jwaneng, indicating that major tectono-magmatic events formed discrete diamond populations of Paleo- (~ 2.0 to 1.7 Ga), Meso- (~ 1.2 to 1.1 Ga) and Neoproterozoic (~ 0.9 to 0.75 Ga) age. Some of these processes occurred simultaneously across the Kalahari Craton and can be traced over 100's of km illustrating the significance of diamond inclusions for monitoring continental tectonics. Inclusion ages indicating diamond formation that are younger than 300 Ma appear to be more common than previously recognised, consistent with evidence of relatively abundant, young, fluid-rich “fibrous” and polycrystalline diamonds at Jwaneng and Orapa. The increasingly widespread evidence for Mesozoic diamond-forming events in southern Africa and elsewhere appears closely linked with the kimberlite-related magmatism that affected these regions and subsequently transported diamonds to the surface. The inclusion isochron ages emphasise that diamond formation is a multi-stage and episodic process that can occur contemporaneously in disparate substrates and produce multiple diamond populations in the sub-continental lithospheric mantle.
Abstract: The Orapa kimberlite field of Botswana is one of the world’s major diamond producing regions. Within this field, there are several small kimberlite pipes that have not been completely explored in terms of their lateral extent, depth, and diamond potential. Two such pipes, BK54 and BK55, were found during a ground gravity and magnetic survey, and subsequent drilling confirmed the presence of kimberlite material. To determine the physical properties of these pipes, their lateral extent, depth, and thickness were estimated using a gravity and magnetic analysis and 2.5D and 3D modeling. Tilt derivatives of the magnetic data indicated that BK54 has a northwest-trending elliptical shape and BK55 has a roughly circular shape. Residual gravity anomaly maps indicate that BK54 does not have a density anomaly whereas BK55 is associated with a gravity maximum. The 3D gravity and magnetic inversion modeling constrained by magnetic susceptibility measurements indicates that BK54 is smaller in volume than BK55 and that neither pipe is thicker than 125 m. The difference in shape and the lack of a gravity anomaly over BK54 implies a different formation mechanism for each kimberlite pipe. Although several mechanisms are suggested, BK54 may have formed by a more explosive eruption producing more tuffistic material in the crater and diatreme facies. The gravity and magnetic analysis also found that the kimberlite pipes, while small, are larger in extent than was determined by drilling and warrant additional drilling to determine their economic potential.
Abstract: Controversies surround the origin of kimberlite megacrysts, including whether and how they are genetically related to their host kimberlites, the relationship between the Cr-poor and Cr-rich suites and the dominant processes responsible for elemental and isotopic variations of megacrysts from a given kimberlite. We present new in-situ major and trace element and Sr isotopic results for clinoyroxene and garnet megacrysts from four southern African kimberlites: Colossus and Orapa (Group 1 kimberlites on the Zimbabwe craton), and Kalkput and Bellsbank (Group 2 kimberlites on the western Kaapvaal craton), that include both Cr-poor and Cr-rich megacryst varieties. Cr-poor megacrysts are present at Colossus, Orapa and Kalkput and the data exhibit tight, well-defined trends on major element diagrams as well as incompatible and rare earth element abundances similar to those previously reported for Cr-poor megacrysts. Cr-rich megacrysts, which are also present at Orapa and are the only variety present at Bellsbank, generally have higher Mg# values, lack well-defined major element trends and show stronger incompatible element enrichments as well as more radiogenic 87Sr/86Sri ratios than Cr-poor megacrysts from the same kimberlite group. Thermobarometry indicates that the Cr-poor megacrysts equilibrated at temperatures of ?1200 to 1450 °C and pressures of 4.5 to 7.5 GPa. Cr-rich megacrysts, in contrast, extend to temperatures and pressures as low as 700 °C and 3 GPa, respectively. This indicates that, in the studied suites, Cr-poor megacrysts equilibrated at high temperatures in the lower lithosphere (>135 km), whereas Cr-rich megacrysts typically equilibrated at lower temperatures and pressures. Within the Cr-poor megacrysts from Group 1 and Group 2 kimberlites, there is a clear correspondence between kimberlite group, diagnostic incompatible element ratios (e.g., Nb/La) and Sr isotope ratios that parallel the differences noted between whole-rock Group 1 and Group 2 kimberlites. In the case of Cr-poor megacrysts, similar calculated melt compositions in equilibrium with garnet and clinopyroxene from the same kimberlite were obtained using recent high-pressure mineral?carbonated melt partition coefficients. This suggests formation in conditions close to trace element equilibrium, and is consistent with crystallization from primitive melts with kimberlite-like trace element compositions. In the case of Cr-rich megacrysts, differences in the compositions of melts in equilibrium with clinopyroxene and garnet tend to be larger, and melts in equilibrium with Cr-rich clinopyroxene tend to show significantly greater incompatible element enrichments than those of estimated near-primary kimberlite melts. This could be due to the different behaviour of clinopyroxene and garnet during metasomatic melt-rock interaction, but the apparent disequilibrium between clinopyroxene and garnet could also be due to some of the Cr-rich megacrysts actually being peridotitic xenocrysts. We propose a model for the origin of southern African megacrysts in which carbonated protokimberlite melts formed stockwork-like bodies of variable size in the deep lithosphere (>130 km), which fed networks of melt-filled veins extending into the surrounding and overlying mantle. Crystallization of larger melt bodies resulted in megacryst assemblages dominated by Cr-poor megacrysts, and the incompatible element and isotopic characteristics of these dominantly reflect those of the protokimberlite melt. In contrast, crystallization of smaller melt bodies and their vein networks resulted in megacryst assemblages dominated by Cr-rich megacrysts, which formed as a result of extensive assimilation and metasomatic melt-rock interaction between protokimberlite and peridotite wallrock at low melt/rock ratios, particularly in the middle to shallow lithosphere where pre-existing potassic metasomatic heterogeneities are prevalent. The Cr-rich nature and enrichments in incompatible elements and radiogenic Sr in the Cr-rich megacrysts reflect extensive interaction of their parental magmas with this metasomatized peridotite.
Eclogitic geotherms of the Rio de la Plata craton archon-core. Estancia Trementina and Puentesino, DPTO. Of Concepcion - Parauay. Compared of two large diamond deposits Argyle ( lamproitic ) and Orapa ( kimberlitic).
Historia Natural, Vol. 11, 2, pp. 5-16. pdf
South America, Paraguay, Australia, Africa, Botswana
Abstract: Kimberlites are mantle-derived igneous rocks emplaced in the upper crust. Class 1 kimberlite are multi-phase bodies consisting of coherent kimberlite (CK) and different pyroclastic facies, including diatreme Kimberley-type pyroclastic kimberlite (KPK). The composition, crystallisation conditions and emplacement processes of these multiphase kimberlites are poorly understood, especially the formation of KPK. CK facies include hypabyssal kimberlite (HK) and ambiguous partially fragmented CK. Ilmenite macrocrysts from some Orapa kimberlites show reaction rims, the composition of which correlates with kimberlite facies. The goal of this study is to document the reaction products on ilmenite from different kimberlite facies and to use them to determine crystallisation temperature (T) and oxygen fugacity (fO2). Obtaining a better understanding of fO2 is important not only scientifically, but also for economic reasons, because highly oxidising conditions would have promoted resorption of diamonds in the kimberlite. This study used thin sections taken in well constrained depth intervals from drillholes in AK15 and BK1 kimberlites from the Orapa kimberlite cluster (Botswana). The AK15 intrusion consists of a single phase of CK facies. The BK1 pipe consists of two CK facies (CK-A and CK-B) and one KPK facies. CK-B is a HK and CK-A shows areas of partial fragmentation. Kimberlite textures were examined with a petrographic microscope. Ilmenite reaction rims were identified with SEM. EMP analyses were performed on perovskite, ilmenite and magnetite grains for T and fO2 calculation. We found that ilmenite macrocrysts in CK-A develop rims composed of magnetite and rutile. The reaction rims on ilmenite macrocrysts in KPK are highly variable and are distinguished by the presence of titanite. In CK-B, ilmenite macrocrysts are replaced by a symplectic intergrowth of magnetite and perovskite. In AK15, ilmenite macrocrysts consist of magnetite rims. fO2 estimated using ferric iron content in CaTiO3 perovskite varies from NNO -5.74 to -1.30 showing progressive oxidation upwards and within KPK facies. Such fO2 conditions require T during perovskite crystallisation between 560 and 700 °C. The observed textures suggest that BK1 ilmenite macrocrysts reacted with the melt to produce magnetite and perovskite rims followed by full ilmenite replacement by symplectic intergrowth of perovskite and magnetite in CK-B and replacement of perovskite with TiO2 oxide in CK-A. Development of titanite in KPK indicates assimilation of crustal xenoliths, while variability of reaction rims and fO2 estimates within the same sample confirm the high degree of material mixing in KPK. Similarities of ilmenite rims in CK-A and KPK indicate similarity in the process of their formation.
Abstract: The Zambezi rises with considerable modesty in north-west Zambia from a small spring on the gentle upland of the Southern Equatorial Divide - the watershed that separates the river from north-west-flowing tributaries of the Congo. The evolution of the Zambezi River has repeatedly modified the distribution of riverine plant and animal species. The hydrology of the Zambezi is further influenced by water exploitation by different users, along its main channel and tributaries. The dams have had severe ecological impacts on the major floodplains, as a result of the reduction of the supply of water and sediment. The major Early Cretaceous Zambezi-Limpopo River system entered the Mozambique coastal plain via a line of crustal weakness that was exploited by a major west-north-west trending dyke swarm. Drainage evolution of the Palaeo-Chambeshi system has been invoked as the primary cause of the recent evolution of the molerats.